Diastereoselective lithiation and substitution of (S)-N-benzylprolinol and rac-N-benzylpiperidine-2-methanol via the carbamate esters: Kinetic resolution by means of (-)-sparteine-mediated deprotonation

Synthesis

Volumn , Issue 11, 1999, Pages 1915-1924

  Weber, B ^a   Schwerdtfeger, J ^a   Frohlich R ^a   Gohrt A ^b   Hoppe, D ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b BAYER AG   (Germany)

Author keywords

( ) sparteine; Carbanions; Diastereoselective deprotonation; Kinetic resolution; Lithiation; Mosher esters; amino alcohols; amino oxy carbanions

Indexed keywords

BENZYL DERIVATIVE; CARBAMIC ACID ESTER; METHANOL; PIPERIDINE DERIVATIVE; SPARTEINE;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 0032706528     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-3612     Document Type: Article

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