A stable methyl phosphane oxide/lithium amide complex: A structural and MO calculational investigation of the mechanism of proton abstraction by alkali metal reagents

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 17, 1996, Pages 1942-1944

  Armstrong, David R ^b   Davidson, Matthew G ^a   Davies, Robert P ^a   Mitchell, Helen J ^a   Oakley, Rachel M ^a   Raithby, Paul R ^a   Snaith, Ronald ^a   Warren, Stuart ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF STRATHCLYDE   (United Kingdom)

Author keywords

ab initio calculations; Amides; Lithium compounds; Phosphorus compounds; Solid state structures

Indexed keywords

EID: 0029952802     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199619421     Document Type: Article

References (11)

1. a) B. J. Wakefield, Organolithium Methods, Academic Press, New York, 1988; b) M. Fieser, Reagents for Organic Synthesis, Vol. 15, Wiley-Interscience, New York, 1990;
2. a) B. J. Wakefield, Organolithium Methods, Academic Press, New York, 1988; b) M. Fieser, Reagents for Organic Synthesis, Vol. 15, Wiley-Interscience, New York, 1990;
3. L. Brandsma, Preparative Polar Organometallic Chemistry, Vol 2, Springer, Berlin, 1990; d) P. G. Williard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, New York, 1991.
4. L. Brandsma, Preparative Polar Organometallic Chemistry, Vol 2, Springer, Berlin, 1990; d) P. G. Williard in Comprehensive Organic Synthesis, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, New York, 1991.
5. a) K. Gregory, P. von R. Schleyer, R. Snaith, Adv. Inorg. Chem. 1991, 37, 47-142; b) A. Sekigushi, Y. Sugai, K. Ebata, C. Kabuto, H. Sakurai, J. Am. Chem. Soc. 1993, 115, 1144-1146.
6. a) K. Gregory, P. von R. Schleyer, R. Snaith, Adv. Inorg. Chem. 1991, 37, 47-142; b) A. Sekigushi, Y. Sugai, K. Ebata, C. Kabuto, H. Sakurai, J. Am. Chem. Soc. 1993, 115, 1144-1146.
7. a) A. D. Buss, S. Warren, J. Chem. Soc. Perkin Trans, 1 1985, 2307-2325; b) A. D. Buss, N. Greeves, R. Mason, S. Warren, ibid. 1987, 2569-2577; c) J. Clayden, S. Warren, Angew. Chem. 1996, 108, 261-291; Angew. Chem. Int. Ed. Engl. 1996, 35, 241-270; d) D. R. Armstrong, D. Barr, M. G. Davidson, G. Hutton, P. O'Brien, R. Snaith, S. Warren, Tetrahedron Lett. 1996, submitted.
8. a) A. D. Buss, S. Warren, J. Chem. Soc. Perkin Trans, 1 1985, 2307-2325; b) A. D. Buss, N. Greeves, R. Mason, S. Warren, ibid. 1987, 2569-2577; c) J. Clayden, S. Warren, Angew. Chem. 1996, 108, 261-291; Angew. Chem. Int. Ed. Engl. 1996, 35, 241-270; d) D. R. Armstrong, D. Barr, M. G. Davidson, G. Hutton, P. O'Brien, R. Snaith, S. Warren, Tetrahedron Lett. 1996, submitted.
9. a) A. D. Buss, S. Warren, J. Chem. Soc. Perkin Trans, 1 1985, 2307-2325; b) A. D. Buss, N. Greeves, R. Mason, S. Warren, ibid. 1987, 2569-2577; c) J. Clayden, S. Warren, Angew. Chem. 1996, 108, 261-291; Angew. Chem. Int. Ed. Engl. 1996, 35, 241-270; d) D. R. Armstrong, D. Barr, M. G. Davidson, G. Hutton, P. O'Brien, R. Snaith, S. Warren, Tetrahedron Lett. 1996, submitted.
10. a) A. D. Buss, S. Warren, J. Chem. Soc. Perkin Trans, 1 1985, 2307-2325; b) A. D. Buss, N. Greeves, R. Mason, S. Warren, ibid. 1987, 2569-2577; c) J. Clayden, S. Warren, Angew. Chem. 1996, 108, 261-291; Angew. Chem. Int. Ed. Engl. 1996, 35, 241-270; d) D. R. Armstrong, D. Barr, M. G. Davidson, G. Hutton, P. O'Brien, R. Snaith, S. Warren, Tetrahedron Lett. 1996, submitted.
11. a) A. D. Buss, S. Warren, J. Chem. Soc. Perkin Trans, 1 1985, 2307-2325; b) A. D. Buss, N. Greeves, R. Mason, S. Warren, ibid. 1987, 2569-2577; c) J. Clayden, S. Warren, Angew. Chem. 1996, 108, 261-291; Angew. Chem. Int. Ed. Engl. 1996, 35, 241-270; d) D. R. Armstrong, D. Barr, M. G. Davidson, G. Hutton, P. O'Brien, R. Snaith, S. Warren, Tetrahedron Lett. 1996, submitted.