Controlled radical polymerization of methyl methacrylate initiated by an alkyl halide in the presence of the Wilkinson catalyst

Macromolecules

Volumn 31, Issue 2, 1998, Pages 542-544

  Moineau, G ^a   Granel, C ^a   Dubois, Ph ^a   Jerome R ^a   Teyssie Ph ^a  

^a UNIVERSITY OF LIÈGE   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; FREE RADICAL POLYMERIZATION; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; SIZE EXCLUSION CHROMATOGRAPHY; SOLVENTS; SYNTHESIS (CHEMICAL); WATER;

TETRAHYDROFURAN; WILKINSON CATALYST;

POLYMETHYL METHACRYLATES;

EID: 0031674539     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma971123f     Document Type: Article

References (16)

1. Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
2. (b) Ando, T.; Kato, M.; Kamigaito, M.; Sawamoto, M. Macromolecules 1996, 29, 1070.
3. Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
4. (b) Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901.
5. Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
6. Kameda, N.; Itagaki, N. Bull. Chem. Soc. Jpn. 1973, 46, 2597.
7. (b) Kameda, N.; Ishii, E. Makromol. Chem. 1983, 184, 1901.
8. (c) Kameda, N.; Ishii, E. Nippon Kagaku Kaishi 1983, 8, 1196.
9. (d) Kameda, N.; Hattori, M. Kobunshi Ronbunshu 1984, 41 (11), 679.
10. (e) Kameda, N.; Hattori, M. Kobunshi Ronbunshu 1985, 42 (8), 485.
11. Percec, V.; Barboiu, B.; Neumann, A.; Ronda, J. C.; Zhao, M. Macromolecules 1996, 29, 3665.
12. Hutchinson, R. A.; Aronson, M. T.; Richards, J. R. Macromolecules 1993, 26, 6410.
13. Osborn, J. A.; Wilkinson, G. Inorg. Synth. 1990, 28, 77.
14. Haddleton et al. have shown that these two criteria are not enough to confirm a radical pathway: Haddleton, D. M.; Crossman, M. C.; Hunt, K. H.; Topping, C.; Waterson, C.; Suddaby, K. G. Macromolecules 1997, 30, 3992.
15. 1H NMR, 9.6%.
16. Moineau, G.; Dubois, P.; Teyssié, P.; Jérôme, R.; Senninger, T. French Patent, Pending, 1996.