Dynamical exchange behavior in organic monolayers studied by STM analysis of labeled mixtures

Langmuir

Volumn 15, Issue 20, 1999, Pages 6884-6889

  Stevens, F ^a   Beebe Jr , T P ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ELECTRONIC PROPERTIES; GRAPHITE; MIXTURES; SCANNING TUNNELING MICROSCOPY;

ORGANIC MONOLAYERS;

MONOLAYERS;

EID: 0032642039     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la980416e     Document Type: Article

References (33)

1. Venkataraman, B.; Breen, J. J.; Flynn, G. W. J. Phys. Chem. 1995, 99, 6608-6619.
2. Poulin, J.-C. Microsc. Microanal. Microstruct. 1994, 5, 351-358.
3. Hibino, M.; Sumi, A.; Hatta, I. Thin Solid Films 1996, 281-282, 594-597.
4. Kadotani, T.; Taki, S.; Kai, S. Jpn. J. Appl. Phys. 1997, 36, 4440-4445.
5. Kadotani, T.; Taki, S.; Okabe, H.; Kai, S. Jpn. J. Appl. Phys. 1996, 35, L1345-L1347.
6. Iwakabe, Y.; Hara, M.; Kondo, K.; Oh-hara, S.; Mukoh, A.; Sasabe, H. Jpn. J. Appl. Phys. 1992, 31, L1771-L1774.
7. Stevens, F.; Dyer, D. J.; Walba, D. M. Langmuir 1996, 12, 436-440.
8. Vanoppen, P.; Grim, P. C. M.; Rücker, M.; De Feyter, S.; Moessner, G.; Valiyaveettil, S.; Müllen, K.; De Schryver, F. C. J. Phys. Chem. 1996, 100, 19636-19641.
9. Eichhorst-Gerner, K.; Stabel, A.; Moessner, G.; Declerq, D.; Valiyaveettil, S.; Enkelmann, V.; Müllen, K.; Rabe, J. P. Angew. Chem., Int. Ed. Eng. 1996, 35, 1492-1495.
10. Grim, P. C. M.; Vanoppen, P.; Rücker, M.; De Feyter, S.; Valiyaveettil, S.; Moessner, G.; Müllen, K.; De Schryver, F. C. J. Vac. Sci. Technol., B 1997, 15, 1419-1424.
11. Hipps, K. W.; Lu, X.; Wang, X. D.; Mazur, U. J. Phys. Chem. 1996, 100, 11207-11210.
12. Lu, X.; Hipps, K. W.; Wang, X. D.; Mazur, U. J. Am. Chem. Soc. 1996, 118, 7197-7202.
13. Strohmaier, R.; Ludwig, C.; Petersen, J.; Gompf, B.; Eisenmenger, W. J. Vac. Sci. Technol. B 1996, 14, 1079-1082.
14. Tao, N. J. Phys. Rev. Lett. 1996, 76, 4066-4069.
15. Zeglinski, D. M.; Ogletree, D. F.; Beebe Jr., T. P.; Hwang, R. Q.; Somorjai, G. A.; Salmeron, M. B. Rev. Sci. Instrum. 1990, 61, 3769-3774.
16. Hibino, M.; Sumi, A.; Hatta, I. Jpn. J. Appl. Phys. 1995, 34, 610-614.
17. Canet, D.; Guillain, F.; Sanson, A. J. Trace and Microprobe Techniques 1995, 13, 361-362.
18. Hatta, I.; Nishino, J.; Sumi, A.; Hibino, M. Jpn. J. Appl. Phys. 1995, 34, 3930-3936.
19. Stevens, F.; Buchner, D.; Beebe Jr., T. P. J. Phys. Chem. B 1997, 101, 6491-6496.
20. Cyr, D. M.; Venkataraman, B.; Flynn, G. W. Chem. Mater. 1996, 8, 1600-1615.
21. Venkataraman, B.; Flynn, G. W.; Wilbur, J. L.; Folkers, J. P.; Whitesides, G. M. J. Phys. Chem. 1995, 99, 8684-8689.
22. Gunning, A. P.; Kirby, A. R.; Mallard, X.; Morris, V. J. J. Chem. Soc.. Faraday Trans. 1994, 90, 2551-2554.
23. Claypool, C. L.; Faglioni, F.; Goddard III, W. A.; Gray, H. B.; Lewis, N. S.; Marcus, R. A. J. Phys. Chem. B 1997, 101, 5978-5995.
24. Giancarlo, L.; Cyr, D.; Muyskens, K.; Flynn, G. W. Langmuir 1998, 14, 1465-1471.
25. Rabe, J. P.; Buchholz, S.; Askadskaya, L. Synth. Met. 1993, 54, 339-349.
26. It is possible that disulfides are also present in the monolayer. However, disulfides would cause additional "bright spots" and would increase the observed [thiol]/[alcohol] ratio. Since this ratio is low, there must be few, if any, disulfides in the monolayer. GC analysis did not indicate the presence of this impurity.
27. Joesten, M. D.; Schaad, L. J. Hydrogen Bonding; Marcel Dekker: New York, 1974; pp 278, 283.
28. Wenzler, L. A.; Moyes, G. L.; Raiker, G. N.; Hansen, R. L.; Harris, J. M.; Beebe Jr., T. P. Langmuir 1997, 13, 3761-3768.
29. Cyr, D. M.; Venkataraman, B.; Flynn, G. W. J. Phys. Chem. 1996, 100, 13747-13759.
30. Faglioni, F.; Claypool, C. L.; Lewis, N. S.; Goddard III, W. A. J. Phys. Chem. B 1997, 101, 5996-6020.
31. Stevens, F.; Dyer, D. J.; Müller, U.; Walba, D. M. Langmuir 1996, 12, 2, 5625-5629.
32. Masel, R. I. Principles of Adsorption and Reaction on Solid Surfaces; Wiley: New York, 1996; p 804.
33. Because both a molecule of alcohol and a molecule of thiol are involved in any single measurable exchange event, the determined rate is a composite of both molecules. Individual exchange rates could not be calculated.