Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks

Nature

Volumn 396, Issue 6707, 1998, Pages 152-155

  Yang, Peidong ^a   Zhao, Dongyuan ^a   Margolese, David I ^a   Chmelka, Bradley F ^a,b   Stucky, Galen D ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SILICON DIOXIDE;

ARTICLE; CHEMICAL ANALYSIS; COMPLEX FORMATION; COVALENT BOND; CRYSTAL STRUCTURE; MOLECULAR INTERACTION; ORGANIC CHEMISTRY; PRIORITY JOURNAL; SPECIES DIFFERENCE; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

EID: 0032511881     PISSN: 00280836     EISSN: None     Source Type: Journal    
DOI: 10.1038/24132     Document Type: Article

References (26)

1. Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C. & Beck, J. S. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710-712 (1992).
2. Huo, Q. et al. Generalized synthesis of periodic surfactant/inorganic composite materials. Nature 368, 317-321 (1994).
3. Huo, Q. et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays. Chem. Mater. 6, 1176-1191 (1994).
4. Tanev, P. T. & Pinnavaia, T. J. A neutral templating route to mesoporous molecular sieves. Science 267, 865-868 (1995).
5. Antonelli, D. M. & Ying, J. Y. Synthesis and characterization of hexagonal packed mesoporous tantalum oxide molecular sieves. Chem. Mater. 8, 874-881 (1996).
6. Förster, S. & Antonietti, M. Amphiphilic block copolymers in structure-controlled nanomaterial hybrids. Adv. Mater. 10, 195-217 (1998).
7. Templin, M. et al. Organically modified aluminosilicate mesostructures from block copolymer phases. Science 278, 1795-1798 (1997).
8. Zhao, D. et al. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 279, 548-552 (1998).
9. Tian, Z. et al. Manganese oxide mesoporous structures: mixed-valent semiconducting catalysts. Science 276, 926-930 (1997).
10. Bagshaw, S. A. & Pinnavaia, T. J. Mesoporous alumina molecular sieves. Angew. Chem. Int. Edn Engl. 35, 1102-1105 (1996).
11. 2 by a modified sol-gel method. Angew. Chem. Int. Edn Engl. 34, 2014-2017 (1995).
12. Ciesla, U., Schacht, S., Stucky, G. D., Unger, K. K. & Schüth, F. Formation of a porous zirconium oxo phosphate with a high surface area by a surfactant-assisted synthesis. Angew. Chem. Int. Edn Engl. 35, 541-543 (1996).
13. Liu, P., Liu, J. & Sayari, A. Preparation of porous hafnium oxide in the presence of a cationic surfactant. Chem. Commun. 557-578 (1997).
14. Attard, G. S. et al. Mesoporous platinum films from lyotropic liquid crystalline phases. Science 278, 838-840 (1997).
15. 2. Chem. Commun. 1685-1686 (1996).
16. Braun, P. V., Osenar, P. & Stupp, S. I. Semiconducting superlattices templated by molecular assemblies. Nature 380, 325-328 (1996).
17. Sayari, A. & Liu, P. Non-silica mesostructured materials: recent progress. Microporous Mater. 12, 149-177 (1997).
18. Stucky, G. D. et al. in The Robert A. Welch Foundation 40th Conference on Chemical Research: Chemistry on the Nanometer Scale 101-112 (Houston, Texas, 1996).
19. Monnier, A. et al. Cooperative formation of inorganic-organic interfaces in the synthesis of silicate mesostructures. Science 261, 1299-1302 (1993).
20. Beck, J. S. et al. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 114, 10834-10843 (1992).
21. Huang, Y., McCarthy, T. J. & Sachtler, W. M. Preparation and catalytic testing of mesoporous sulfated zirconium dioxide with partially tetragonal wall structure. Appl. Catal. A 148, 135-154 (1996).
22. Gregg, S. J. & Sing, K. S. W. Adsorption, Surface Area and Porosity (Academic, London, 1982).
23. Bailey, F. E. Jr & Koleske, J. V. Alkylene Oxides and their Polymers (Marcel Dekker, New York, 1990).
24. Zhao, D. et al. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J. Am. Chem. Soc. 120, 6024-6036 (1998).
25. Yang, P. et al. Triblock-copolymer-directed syntheses of large-pore mesoporous silica fibers. Chem. Mater. 10, 2033-2036 (1998).
26. Vioux, A. Nonhydrolytic sol-gel routes to oxides. Chem. Mater. 9, 2292-2299 (1997).