Alternating copolymers of functional alkenes with carbon monoxide

Macromolecules

Volumn 29, Issue 18, 1996, Pages 5852-5858

  Kacker, Smita ^a   Jiang, Zhaozhong ^a   Sen, Ayusman ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CARBOXYLIC ACIDS; CATALYSTS; COPOLYMERIZATION; MONOMERS; OLEFINS;

ALKENOLS; INTRACHAIN REACTIONS; ISOTACTIC SEQUENCES; PENDANT HYDROXYL GROUP; POLYCYCLIC REPEATING UNITS;

COPOLYMERS;

EID: 0030211805     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma960255q     Document Type: Article

References (34)

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24. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
25. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
26. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
27. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
28. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
29. Previous reports of the synthesis chiral, isotactic α-alkene-CO copolymers: (a) Jiang, Z.; Sen, A. J. Am. Chem. Soc. 1995, 117, 4455. (b) Jiang, Z.; Adams, S. E.; Sen, A. Macromolecules 1994, 27, 2694. (c) Nozaki, K.; Sato, N.; Takaya, H. J. Am. Chem. Soc. 1995, 117, 9911. (d) Bronco, S.; Consiglio, G.; Hutter, R.; Batistini, A; Suter, U. W. Macromolecules 1994, 27, 4436. (e) Barasacchi, M.; Batistini, A.; Consiglio, G.; Suter, U. W. Macromolecules 1992, 25, 3604. (f) Brookhart, M.; Wagner, M. I.; Balavoine, G. G. A.; Haddou, H. A. J. Am. Chem. Soc. 1994, 116, 3641. (g) Wong, P. K. Eur. Pat. Appl. EP 384, 517, 1990.
30. This catalyst has been shown to form chiral, isotactic copolymers from nonfunctional aliphatic α-alkenes and CO with >90% enantioselectivity; see ref 9a.
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