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Comprehensive Supramolecular Chemistry, vol 2. Edited by Atwood JL, Davies JED, Macnicol DD, Vögtle F. Oxford: Pergamon Press; 1996.
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Comprehensive Supramolecular Chemistry
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Hydrogen bonding control of molecular self assembly: Recent advances in design, synthesis, and analysis
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Edited by Atwood JL, Davies JED, Macnicol DD, Vögtle F. Oxford: Pergamon
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Fredericks, J.R.1
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Molecular recognition: Connection and disconnection of hydrogen bonds, a case study with dimeric and highly associated monocarboxylic acids with simple receptors
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X-Ray structure of the 1:1 complex of a tripodal receptor and cis-cyclohexane-1,3,5-tricarboxylic acid
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Efficient recognition of chiral carbamoyl-α-hydroxyacids with a cleft-type receptor
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Discovery of sequence-selective peptide binding by synthetic receptors using encoded combinatorial libraries
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Still WC: Discovery of sequence-selective peptide binding by synthetic receptors using encoded combinatorial libraries. Accounts Chem Res 1996, 29:155-163. This paper provides an excellent review of recent advances in the use of encoded combinatorial libraries in molecular recognition. Particular use is made of the split bead strategy to screen both libraries of substrates for binding to a given receptor and libraries of receptors for binding to a target substrate.
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Accounts Chem Res
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3-symmetrical receptors. J Chem Soc Chem Commun 1996, 2255-2256. In an elegant and simple design the authors exploit a three-fold symmetrical receptor to create a large, hydrophobic, and chiral recognition site.
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J Chem Soc Chem Commun
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Pieters, R.J.1
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Modified synthesis and binding properties of a peptide receptor
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Intermolecular stabilisation of the β-sheet conformation in dipeptides
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Schrader T, Kirsten C: Intermolecular stabilisation of the β-sheet conformation in dipeptides. J Chem Soc Chem Commun 1996, 2089-2090.
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Molecular imprinting utilizing an amide functional group for hydrogen bonding leading to highly efficient polymers
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Yu C, Mosbach K: Molecular imprinting utilizing an amide functional group for hydrogen bonding leading to highly efficient polymers. J Org Chem 1997, 62:4057-4064.
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Kempe M: Antibody-mimicking polymers as chiral stationary phases in HPLC. Anal Chem 1996, 68:1948-1953.
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Nowick J, Smith EM, Pairish M: Artificial β-sheets. Chem Soc Reviews 1996, 25:401-415. This paper reviews work (primarily from the Nowick lab) on the design of β-sheet mimetic structures. Several strategies are employed, including the use of oligourea templates and rigid extended peptidomimetics to enforce β-sheet structure.
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Chem Soc Reviews
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Rebek J Jr: Molecular recognition and assembly. Acta Chem Scand 1996, 50:707-716.
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Entropically driven binding in a self-assembling molecular capsule
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Kang J, Rebek J Jr: Entropically driven binding in a self-assembling molecular capsule. Nature 1996, 382:239-241. This paper (and those following) describes a highly original approach to artificial receptor design based on self-assembly from multiple components. Glycouril subunits are the centerpiece of a strategy in which two components dimerize by complementary hydrogen bonding to form a large, spherical cavity.
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Nature
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Meissner R, Garcias X, Mecozzi S, Rebek J Jr: Synthesis and assembly of new molecular hosts: solvation and the energetics of encapsulation. J Am Chem Soc 1997, 119:77-85.
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Reversible encapsulation of disc-shaped guests by a synthetic, self-assembled host
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Grotzfeld RM, Branda N, Rebek J Jr: Reversible encapsulation of disc-shaped guests by a synthetic, self-assembled host. Science 1996, 271:487-489.
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Acceleration of a Diels-Alder reaction by a self-assembled molecular capsule
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Kennan AJ, Whitlock HW: Host-catalyzed isoxazole ring opening: a rationally designed artificial enzyme. J Am Chem Soc. 1996, 118:3027-3028. This paper extends the seminal work from Whitlock and Whitlock (1990; [35]) on synthetic cyclophane receptors. In this example, a pyridine-functionalized cyclophane shows significant rate acceleration in a decarboxylation reaction.
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Kennan, A.J.1
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Design, synthesis, and evaluation of bile acid-based molecular tweezers
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Davis AP, Menzer S, Walsh JJ, Williams DJ: Steroid-based receptors with tunable cavities; a series of polyhydroxylated macrocycles of varying size and flexibility. J Chem Soc Chem Commun 1996, 453-455. This is an interesting extension of a strategy pioneered by Bonar-Law et al. (1990; [36]) on the use of rigid steroid subunits as rigid, hydrogen bonding components in molecular recognition.
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J Chem Soc Chem Commun
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