Tris(tert-butoxy)siloxy complexes as single-source precursors to homogeneous zirconia- and hafnia-silica materials. An alternative to the sol-gel method

Journal of the American Chemical Society

Volumn 119, Issue 41, 1997, Pages 9745-9756

  Terry, Karl W ^a   Lugmair, Claus G ^b   Tilley, T Don ^c  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b Lawrence Berkeley Laboratory ^*  (France)

^c LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SILICONE DERIVATIVE; SILOXANE; ZIRCONIUM DERIVATIVE;

ARTICLE; DIFFERENTIAL SCANNING CALORIMETRY; GEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARTICLE SIZE; SYNTHESIS;

EID: 0030719459     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja971405v     Document Type: Article

References (156)

1. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
2. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
3. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
4. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
5. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
6. (a) Ultrastructure Processing of Ceramics, Glasses, and Composites; Hench, L. L., Ulrich, D. R., Eds.; Wiley: New York, 1984. (b) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich; D. R., Eds.; Wiley: New York, 1992. Better Ceramics Through Chemistry W; Cheetham, A. K., Brinker, C. J., Mecartney, M. L., Sanchez, C., Eds.; Materials Research Society Symposium Proceedings Vol. 360; Materials Research Society: Pittsburgh, 1994, and previous volumes in this series, Materials Chemistry - An Emerging Discipline; Interrante, L. V., Casper, L. A., Ellis, A. B., Eds.; Advances in Chemistry Series 245; American Chemical Society: Washington, DC, 1992. (e) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558.
7. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
8. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
9. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
10. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
11. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
12. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
13. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
14. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
15. Selected references on the single source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings Vol. 32; North-Holland: New York, 1984, p 152. Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169. (f) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1. (g) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663. (h) Bradley, D. C. Polyhedron 1994, 13, 1111. Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205.
16. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
17. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
18. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
19. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
20. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
21. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
22. (a) Brinker, C. J., Scherer, G. W. Sol-Gel Science; Academic Press: Boston, 1990. (b) Sol-Gel Technology for Thin Films, Fibers, Preforms, Electronics, and Specialty Shapes; Klein, L. C., Ed.; Noyes: Park Ridge, NJ, 1988. Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421. Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16. (e) Brinker, C. J. J. Non-Cryst. Solids 1988, 100, 31. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165.
23. (a) Schubert, U. J. Chem. Soc., Dalton Trans. 1996, 3343. (b) Schubert, U.; Hüsing, N.; Lorenz, A. Chem. Mater. 1995, 7, 2010. Schmidt, H.; Scholze, H.; Kaiser, A. J. Non-Cryst. Solids 1982, 48, 65.
24. (a) Schubert, U. J. Chem. Soc., Dalton Trans. 1996, 3343. (b) Schubert, U.; Hüsing, N.; Lorenz, A. Chem. Mater. 1995, 7, 2010. Schmidt, H.; Scholze, H.; Kaiser, A. J. Non-Cryst. Solids 1982, 48, 65.
25. (a) Schubert, U. J. Chem. Soc., Dalton Trans. 1996, 3343. (b) Schubert, U.; Hüsing, N.; Lorenz, A. Chem. Mater. 1995, 7, 2010. Schmidt, H.; Scholze, H.; Kaiser, A. J. Non-Cryst. Solids 1982, 48, 65.
26. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
27. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
28. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
29. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
30. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
31. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
32. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001. (b) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290. Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Inorg. Chem. 1993, 32, 5402 Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274. (e) Lugmair, C. G.; Tilley, T. D.; Rheingold, A. L. Chem. Mater. 1997, 9, 339. (f) Su, K.; Tilley, T. D. Chem. Mater. 1997, 9, 588. (g) Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
33. Narula, C. K.; Varshney, A.; Riaz, U. Chem. Vap. Deposition 1996, 2, 13.
34. Jansen, M.; Guenther, E. Chem. Mater. 1995, 7, 2110.
35. Andrianainarivelo, M.; Corriu, R.; Leclerq, D.; Mutin, P. H.; Vioux, A. J. Mater. Chem. 1996, 6, 1665.
36. (a) Simhan, R. G. J. Non-Cryst. Solids 1983, 54, 335. (b) Yoldas, B. E. J. Non-Cryst. Solids 1980, 38-39, 81. Paul, A. J. Mater. Sci. 1977, 12, 2246.
37. (a) Simhan, R. G. J. Non-Cryst. Solids 1983, 54, 335. (b) Yoldas, B. E. J. Non-Cryst. Solids 1980, 38-39, 81. Paul, A. J. Mater. Sci. 1977, 12, 2246.
38. (a) Simhan, R. G. J. Non-Cryst. Solids 1983, 54, 335. (b) Yoldas, B. E. J. Non-Cryst. Solids 1980, 38-39, 81. Paul, A. J. Mater. Sci. 1977, 12, 2246.
39. (a) Soled, S.; McVicker, G. B. Catal. Today 1992, 14, 189. (b) Niwa, M.; Katada, N.; Murakami, Y. J. Catal. 1992, 134, 340. Bosman, H. J. M.; Kruissink, E. C.; van der Spoel, J.; van den Brink, F. J. Catal. 1994, 148, 660. Sohn, J. R.; Jang, H. J. J. Mol. Catal. 1991, 64, 349.
40. (a) Soled, S.; McVicker, G. B. Catal. Today 1992, 14, 189. (b) Niwa, M.; Katada, N.; Murakami, Y. J. Catal. 1992, 134, 340. Bosman, H. J. M.; Kruissink, E. C.; van der Spoel, J.; van den Brink, F. J. Catal. 1994, 148, 660. Sohn, J. R.; Jang, H. J. J. Mol. Catal. 1991, 64, 349.
41. (a) Soled, S.; McVicker, G. B. Catal. Today 1992, 14, 189. (b) Niwa, M.; Katada, N.; Murakami, Y. J. Catal. 1992, 134, 340. Bosman, H. J. M.; Kruissink, E. C.; van der Spoel, J.; van den Brink, F. J. Catal. 1994, 148, 660. Sohn, J. R.; Jang, H. J. J. Mol. Catal. 1991, 64, 349.
42. (a) Soled, S.; McVicker, G. B. Catal. Today 1992, 14, 189. (b) Niwa, M.; Katada, N.; Murakami, Y. J. Catal. 1992, 134, 340. Bosman, H. J. M.; Kruissink, E. C.; van der Spoel, J.; van den Brink, F. J. Catal. 1994, 148, 660. Sohn, J. R.; Jang, H. J. J. Mol. Catal. 1991, 64, 349.
43. (a) Miller, J. B.; Rankin, S. E.; Ko, E. I. J. Catal. 1994, 148, 673. (b) Miller, J. B.; Ko, E. I. J. Catal. 1996, 159, 58.
44. (a) Miller, J. B.; Rankin, S. E.; Ko, E. I. J. Catal. 1994, 148, 673. (b) Miller, J. B.; Ko, E. I. J. Catal. 1996, 159, 58.
45. Guizard, C.; Cygankiewicz, N.; Larbot, A.; Cot, L. J. Non-Cryst, Solids 1986, 82, 86.
46. (a) Abe, Y.; Sugimoto, N.; Nagao, Y.; Misono, T. J. Non-Cryst. Solids 1989, 108, 150. (b) Nagarajan, V. S.; Rao, K. J. J. Mater. Sci. 1989, 24, 2140. Nogami, M.; Tomozawa, M. J. Am. Ceram. Soc. 1986, 69, 99. Nogami, M.; Nagasaka, K. J. Non-Cryst. Solids 1989, 109, 79.
47. (a) Abe, Y.; Sugimoto, N.; Nagao, Y.; Misono, T. J. Non-Cryst. Solids 1989, 108, 150. (b) Nagarajan, V. S.; Rao, K. J. J. Mater. Sci. 1989, 24, 2140. Nogami, M.; Tomozawa, M. J. Am. Ceram. Soc. 1986, 69, 99. Nogami, M.; Nagasaka, K. J. Non-Cryst. Solids 1989, 109, 79.
48. (a) Abe, Y.; Sugimoto, N.; Nagao, Y.; Misono, T. J. Non-Cryst. Solids 1989, 108, 150. (b) Nagarajan, V. S.; Rao, K. J. J. Mater. Sci. 1989, 24, 2140. Nogami, M.; Tomozawa, M. J. Am. Ceram. Soc. 1986, 69, 99. Nogami, M.; Nagasaka, K. J. Non-Cryst. Solids 1989, 109, 79.
49. (a) Abe, Y.; Sugimoto, N.; Nagao, Y.; Misono, T. J. Non-Cryst. Solids 1989, 108, 150. (b) Nagarajan, V. S.; Rao, K. J. J. Mater. Sci. 1989, 24, 2140. Nogami, M.; Tomozawa, M. J. Am. Ceram. Soc. 1986, 69, 99. Nogami, M.; Nagasaka, K. J. Non-Cryst. Solids 1989, 109, 79.
50. (a) Tanabe, K.; Sumiyoshi, T.; Shibata, K.; Kiyoura, T.; Kitagawa, J. Bull. Chem. Soc. Jpn. 1974, 47, 1064. (b) Miller, J. B.; Johnston, S. T.; Ko, E. I. J. Catal. 1994, 150, 311.
51. (a) Tanabe, K.; Sumiyoshi, T.; Shibata, K.; Kiyoura, T.; Kitagawa, J. Bull. Chem. Soc. Jpn. 1974, 47, 1064. (b) Miller, J. B.; Johnston, S. T.; Ko, E. I. J. Catal. 1994, 150, 311.
52. (a) Miller, J. B.; Ko, E. I. J. Catal. 1995, 153, 194. (b) Monros, G.; Marti, M. C.; Carda, J.; Tena, M. A.; Escribano, P.; Anglada, M. J. Mater. Sci. 1993, 28, 5852. Nogami, M. J. Non-Cryst. Solids 1985, 69, 415.
53. (a) Miller, J. B.; Ko, E. I. J. Catal. 1995, 153, 194. (b) Monros, G.; Marti, M. C.; Carda, J.; Tena, M. A.; Escribano, P.; Anglada, M. J. Mater. Sci. 1993, 28, 5852. Nogami, M. J. Non-Cryst. Solids 1985, 69, 415.
54. (a) Miller, J. B.; Ko, E. I. J. Catal. 1995, 153, 194. (b) Monros, G.; Marti, M. C.; Carda, J.; Tena, M. A.; Escribano, P.; Anglada, M. J. Mater. Sci. 1993, 28, 5852. Nogami, M. J. Non-Cryst. Solids 1985, 69, 415.
55. (a) Toba, M.; Mizukami, F.; Niwa, S.; Sano, T.; Maeda, K.; Annila, A.; Komppa, V. J. Mol. Catal. 1994, 94, 85. (b) Salvado, I. M. M.; Serna, C. J.; Navarro, J. M. F. J. Non-Cryst. Solids 1988, 100, 330.
56. (a) Toba, M.; Mizukami, F.; Niwa, S.; Sano, T.; Maeda, K.; Annila, A.; Komppa, V. J. Mol. Catal. 1994, 94, 85. (b) Salvado, I. M. M.; Serna, C. J.; Navarro, J. M. F. J. Non-Cryst. Solids 1988, 100, 330.
57. Abe, Y.; Kijima, I. Bull. Chem. Soc. Jpn. 1969, 42, 1118.
58. Bradley, D. C.; Thomas, I. M. J. Chem. Soc. 1960, 3857.
59. Hrncir, D. C.; Skiles, G. D. J. Mater. Res. 1988, 3, 410.
60. (a) Babaian, E. A.; Hrncir, D. C.; Bott, S. G.; Atwood, J. L. Inorg. Chem. 1986, 25, 4818. (b) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341.
61. (a) Babaian, E. A.; Hrncir, D. C.; Bott, S. G.; Atwood, J. L. Inorg. Chem. 1986, 25, 4818. (b) Thewalt, U.; Lasser, W. J. Organomet. Chem. 1984, 276, 341.
62. Fink, W. H.; Power, P. P.; Allen, T. L. Inorg. Chem. 1997, 36, 1431.
63. Scherrer, P. Nachr, Ges. Wiss. Göttingen 1918, 96.
64. (a) Toraya, H.; Yoshimura, M.; Sõmiya, S. J. Am. Ceram. Soc. 1984, 67, C-119. (b) Ward, D. A.; Ko, E. I. Chem. Mater. 1993, 5, 956.
65. (a) Toraya, H.; Yoshimura, M.; Sõmiya, S. J. Am. Ceram. Soc. 1984, 67, C-119. (b) Ward, D. A.; Ko, E. I. Chem. Mater. 1993, 5, 956.
66. McDevitt, N. T.; Baun, W. L. Spectrochim. Acta 1964, 20, 799
67. Liu, H.; Feng, L.; Zhang, X.; Xue, Q. J. Phys. Chem. 1995, 99, 332.
68. Wies, Gh.; Meise-Gresch, K.; Müller-Warmuth, W.; Beier, W.; Göktas, A. A.; Frischat, G. H. Phys. Chem. Glasses 1990, 31, 138.
69. Seyferth, D.; Wiseman, G. H.; Schwark, J. M.; Yu, Y.-F.; Poutasse, C. A. In Inorganic and Organometallic Polymers; Zeldin, M., Wynne, K. J., Allcock, H. R., Eds.; ACS Symposium Series 360; American Chemical Society: Washington, DC, 1988; p 143.
70. Artaki, I.; Zerda, T. W.; Jonas, J. J. Non-Cryst, Solids 1986, 81, 381.
71. (a) Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquérol, J.; Siemieniewska, T. Pure Appl. Chem. 1985, 57, 603. (b) Reference 3a, Chapter 9.
72. (29) (a) Sing, K. S. W.; Everett, D. H.; Haul, R. A. W.; Moscou, L.; Pierotti, R. A.; Rouquérol, J.; Siemieniewska, T. Pure Appl. Chem. 1985, 57, 603. (b) Reference 3a, Chapter 9.
73. Osendi, M. I.; Moya, J. S.; Serna, C. J.; Soria, J. J. Am. Ceram. Soc. 1985, 68, 135.
74. (a) Garvie, R. C. J. Phys. Chem. 1965, 69, 1238. (b) Garvie, R. C. Phys. Chem. 1978, 82, 218.
75. (a) Garvie, R. C. J. Phys. Chem. 1965, 69, 1238. (b) Garvie, R. C. Phys. Chem. 1978, 82, 218.
76. Nagarajan, V. S.; Rao, K. J. J. Mater. Sci. 1989, 24, 2140.
77. (a) Lange, F. F. J. Mater. Sci. 1982, 17, 225. (b) Lange, F. F. J. Mater. Sci. 1982, 17, 235.
78. (33) (a) Lange, F. F. J. Mater. Sci. 1982, 17, 225. (b) Lange, F. F. J. Mater. Sci. 1982, 17, 235.
79. Heuer, A. H.; Claussen, N.; Kriven, W. M.; Rühle, M. J. Am. Ceram. Soc. 1982, 65, 642.
80. Skandan, G.; Hahn, H.; Roddy, M.; Cannon, W. R. J. Am. Ceram. Soc. 1994, 77, 1706.
81. (a) Kamiya, K.; Mabe, S.; Yoko, T.; Tanaka, K. J. Ceram. Soc. Jpn. Inter. Ed. 1989, 97, 227. (b) Nogami, M.; Nagasaka, K.; Kadono, K.; Kishimoto, T. J. Non-Cryst. Solids 1988, 100, 298. Low, I. M.; McPherson, R. J. Mater. Sci. 1989, 24, 1648.
82. (a) Kamiya, K.; Mabe, S.; Yoko, T.; Tanaka, K. J. Ceram. Soc. Jpn. Inter. Ed. 1989, 97, 227. (b) Nogami, M.; Nagasaka, K.; Kadono, K.; Kishimoto, T. J. Non-Cryst. Solids 1988, 100, 298. Low, I. M.; McPherson, R. J. Mater. Sci. 1989, 24, 1648.
83. (a) Kamiya, K.; Mabe, S.; Yoko, T.; Tanaka, K. J. Ceram. Soc. Jpn. Inter. Ed. 1989, 97, 227. (b) Nogami, M.; Nagasaka, K.; Kadono, K.; Kishimoto, T. J. Non-Cryst. Solids 1988, 100, 298. Low, I. M.; McPherson, R. J. Mater. Sci. 1989, 24, 1648.
84. Kanno, Y. J. Mater. Sci. 1989, 24, 2415.
85. Heuer, A. H.; Ruhle, M. In Adavnces in Ceramics, Science and Technology of Zirconia; Claussen, N., Ruhle, M., Heuer, A. H., Eds.; The American Ceramic Society: Columbus, OH, 1984; Vol. 12, p 1.
86. Li, X.; Johnson, P. F. In Better Ceramics Through Chemistry; Zelinski, B. J. J., Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Mater. Res. Soc. Symp. Proc. Vol. 180; Materials Research Society: Pittsburgh, 1990; p 355.
87. (a) Torralvo, M. J.; Alario, M. A.; Soria, J. J. Catal 1984, 86, 473. (b) Sun, Y.; Sermon, P. A. J. Mater. Chem. 1996, 6, 1019.
88. (a) Torralvo, M. J.; Alario, M. A.; Soria, J. J. Catal 1984, 86, 473. (b) Sun, Y.; Sermon, P. A. J. Mater. Chem. 1996, 6, 1019.
89. (a) Noller, H.; Andréu, P.; Hunger, M. Angew. Chem., Int. Ed. Engl. 1971, 10, 172. (b) Knözinger, H. Angew. Chem., Int. Ed. Engl. 1968, 7, 791.
90. (a) Noller, H.; Andréu, P.; Hunger, M. Angew. Chem., Int. Ed. Engl. 1971, 10, 172. (b) Knözinger, H. Angew. Chem., Int. Ed. Engl. 1968, 7, 791.
91. (a) Bradley, D. C. Chem. Rev. 1989, 89, 1317. (b) Bradley, D. C.; Faktor, M. M. Trans. Faraday Soc. 1959, 55, 2117.
92. (a) Bradley, D. C. Chem. Rev. 1989, 89, 1317. (b) Bradley, D. C.; Faktor, M. M. Trans. Faraday Soc. 1959, 55, 2117.
93. Baxter, D. V.; Chisholm, M. H.; DiStasi, V. F.; Klang, J. A. Chem. Mater. 1991, 3, 221.
94. (a) Stecher, H. A.; Sen, A.; Rheingold, A. L. Inorg. Chem. 1989, 28, 3280. (b) Nandi, M.; Rhubright, D.; Sen, A. Inorg. Chem. 1990, 29, 3065.
95. (a) Stecher, H. A.; Sen, A.; Rheingold, A. L. Inorg. Chem. 1989, 28, 3280. (b) Nandi, M.; Rhubright, D.; Sen, A. Inorg. Chem. 1990, 29, 3065.
96. (a) Budzichowski, T. A.; Chisholm, M. H.; Streib, W. E. J. Am. Chem. Soc. 1994, 116, 389. (b) Jeffries, P. M.; Dubois, L. H.; Girolami, G. S. Chem. Mater. 1992, 4, 1169.
97. (a) Budzichowski, T. A.; Chisholm, M. H.; Streib, W. E. J. Am. Chem. Soc. 1994, 116, 389. (b) Jeffries, P. M.; Dubois, L. H.; Girolami, G. S. Chem. Mater. 1992, 4, 1169.
98. (a) Signer, R. Leibigs Ann. Chem. 1930, 478, 246. (b) Zoellner, R. W. J. Chem. Educ. 1990, 67, 714.
99. (a) Signer, R. Leibigs Ann. Chem. 1930, 478, 246. (b) Zoellner, R. W. J. Chem. Educ. 1990, 67, 714.
100. Bradley, D. C.; Thomas, I. M. J. Chem. Soc. 1960, 3857.
101. 9757 Paramagnetic Laurent Le Pape, Bernard Lamotte, Jean-Marie Mouesca, and Gérard Rius 2 Contribution from the Département de Recherche Fondamentale sur la Matière Condensée, SCIB/SCPM, C.EA/Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France 1 Presently at C.E.A./Grenoble, DRFMC/SCIB, laboratoire de Chimie de Coordination, Unité de Recherche Associée au CNRS No. 1194. 17 rue des Martyrs, 38054 Grenoble Cedex 9, France 2 Presently at the Université de la Rochelle, Pôle Science et Technologie/LEMMA, Avenue Marillac, 17042 La Rochelle, France
102. Armstrong, F. A.; George, S. J.; Cammack, R.; Hatchikian, E. C.; Thomson. A. J. Biochem. J. 1989, 264, 265.
103. George, S. J.; Armstrong, F. A.; Hatchikian, E. C.; Thomson, A. J. Biochem. J. 1989, 264, 275.
104. Conover, R. C.; Kowal, A. T.; Fu, W.; Park, J.-B.; Aono, S.; Adams, M. W. W.; Johnson, M. K. J. Biol. Chem. 1990, 265, 8533.
105. Werst, M. M.; Kennedy, M. C.; Houseman, A. L. P.; Beinert, H.; Hoffman, B. M. Biochemistry 1990, 29, 10533.
106. Beinert, H.; Kennedy, M. C. Eur. J. Biochem. 1989, 186, 5.
107. Gloux, J.; Gloux, P.; Lamotte, B.; Rius, G. Phys. Rev. Lett. 1985, 54, 599.
108. Gloux, J.; Gloux, P.; Hendriks, H.; Rius, G. J. Am. Chem. Soc. 1987, 109, 3220.
109. Rius, G.; Lamotte, B. J. Am. Chem. Soc. 1989, 111, 2464.
110. Mouesca, J.-M.; Rius, G.; Lamotte, B. J. Am. Chem. Soc. 1993, 115, 4714.
111. Gloux, J.; Gloux, P.; Lamotte, B.; Mouesca, J.-M.; Rius, G. J. Am. Chem. Soc. 1994, 116, 1953.
112. Gloux, J.; Gloux, P. J. Am. Chem. Soc. 1995, 117, 7513.
113. Noodleman, L.; Chen, J. L.; Case, D. A.; Giori, C.; Rius, G.; Mouesca, J.-M.; Lamotte, B. In Nuclear Magnetic Resonance of Paramagnetic Macromolecules; La Mar, G. N., Ed.; Kluwer Academic Publishers: The Netherlands, 1995; pp 339-367.
114. Johnson, R. E.; Papaefthymiou, G. C.; Frankel, R. B.; Holm, R. H. J. Am. Chem. Soc. 1983, 105, 7280.
115. Christou, G.; Garner, C. D. J. Chem. Soc., Dalton Trans. 1979, 1093.
116. Le Pape, L.; Excoffon, P.; Lamotte, B.; Laugier, J.; Rius, G. New J. Chem. 1997, 21, 231-235.
117. Belinskii, M. Chem. Phys. 1993, 172, 189.
118. Gibson, J. F.; Hall, D. O.; Thornley, J. H. M.; Whatley, F. R. Proc. Natl. Acad. Sci. U.S.A., 1966, 56, 987.
119. Middleton, P.; Dickson, D. P. E.; Johnson, C. E.; Rush, J. D. Eur. J. Biochem. 1978, 88, 135.
120. Banci, L.; Bertini, I.; Briganti, F.; Luchinat, C.; Scozzafava, A.; Oliver, M. V. Inorg, Chem. 1991, 30, 4517.
121. Bertini, I.; Campos, A. P.; Luchinat, C.; Teixeira, M. J. Inorg. Biochem. 1993, 52, 227.
122. Mouesca, J.-M.; Noodleman, L.; Case, D. A.; Lamotte, B. Inorg. Chem. 1995, 34, 4347.
123. Aizman, A.; Case, D. A. J. Am. Chem. Soc. 1982, 104, 3269.
124. Geurts, P. J. M.; Bouten, P. C. P.; Avoird, A. v. d. J. Chem. Phys. 1980, 73, 1306.
125. Noodleman, L.; Baerends, E. J. J. Am. Chem. Soc. 1984, 106, 2316.
126. Schultz, C.; Debrunner, P. G. J. Phys. Colloq. 1976, 37, 153.
127. Moura, I.; Huynh, B. H.; Hausinger, R. P.; LeGall, J.; Xavier, A. V.; Münck, E. J. Biol. Chem. 1980, 255, 2493.
128. Papaefthymiou, V.; Girerd, J.-J.; Moura, I.; Moura, J. J. G.; Münck, E. J. Am. Chem. Soc. 1987, 109, 4703.
129. Noodleman, L.; Norman, J. G.; Osborne, J. H.; Aizman, A.; Case, D. A. J. Am. Chem. Soc. 1985, 107, 3418.
130. Noodleman, L.; Case, D. A.; Baerends, E. J. In Density Functional Methods in Chemistry; Labanowski, J. K., Andzelm, J. W., Eds.; Springer-Verlag: New-York, 1991; pp 109-123.
131. Noodleman, L. Inorg. Chem. 1991, 30, 246.
132. Norman, J. G.; Jackets, S. C. J. Am. Chem. Soc. 1975, 97, 3833.
133. Norman, J. G.; Ryan, P. B.; Noodleman, L. J. Am. Chem. Soc. 1980. 102, 4279.
134. Noodleman, L.; Peng, C. Y.; Case, D. A.; Mouesca, J.-M. Coord. Chem. Rev. 1995, 144, 199.
135. Butcher, K. D.; Didziulis, S. V.; Briat, B.; Solomon, E. I. J. Am. Chem. Soc. 1990, 112, 2231.
136. Butcher, K. D.; Gebhard, M. S.; Solomon, E. I. Inorg. Chem. 1990, 29, 2067.
137. Gebhard, M. S.; Deaton, J. C.; Koch, S. A.; Millar, M.; Solomon, E. I. J. Am. Chem. Soc. 1990, 112, 2217.
138. Gebhard, M. S.; Koch, S. A.; Millar, M.; Devlin, F. J.; Stephens, P. J.; Solomon, E. I. J. Am. Chem. Soc. 1991, 113, 1640.
139. Burdett, J. K. Molecular Shapes. Theoretical Models of Inorganic Stereochemistry; Wiley: New York, 1980.
140. Gerloch, M.; Slade, R. C. Ligand-Field Parameters; University Press: Cambridge, U.K., 1973.
141. Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
142. Baerends, E. J.; Ros, P. Chem. Phys. 1973, 2, 52.
143. Baerends, E. J.; Ellis, D. E.; Ros, P. J. Comput. Phys. 1992, 99, 84.
144. Vosko, S. H.; Wilk, L.; Nusair, M. Can. J. Phys. 1980, 58, 1200.
145. Becke, A. D. Phys. Rev. 1988, A38, 3098.
146. Perdew, J. P. Phys. Rev. 1986, B33, 8822.
147. Bertrand, P.; Gayda, J.-P. Biochim. Biophys. Acta 1979, 579, 107.
148. Trogler, W. C. J. Chem. Educ. 1980, 57, 424.
149. Noodleman, L. Inorg. Chem. 1991, 30, 256.
150. Guigliarelli, B.; Guillausier, J.; More, C.; Sétif, P.; Bottin, H.; Bertrand, P. J. Biol. Chem. 1993, 268, 900-908.
151. Kamlowski, A.; Est, A. v. d.; Fromme, P.; Stehlik, D. Biochim. Biophys. Acta 1997. in press.
152. Kamlowski, A.; Est, A. v. d.; Fromme, P.; Krauss, N.; Schubert, W.-D.; Klukas, O.; Stehlik, D. Biochim. Biophys. Acta 1997, in press.
153. Calzolai, L.; Gorst, C. M.; Zhao, Z.-H.; Teng, Q.; Adams, M. W. W.; LaMar, G. N. Biochemistry 1995, 34, 11373-11384.
154. Telser, J.; Emptage, M. H.; Merkle, H.; Kennedy, M. C.; Beinert, H.; Hoffman, B. M. J. Biol. Chem. 1986, 261, 4840-4846.
155. Kent, T. A.; Emptage, M. H.; Merkle, H.; Kennedy, M. C.; Beinert, H.; Münck, E. J. Biol. Chem. 1985, 260, 6871-6881.
156. Crozet, M. Thesis, University Joseph Fourier, Grenoble I, 1995.