An unusual transformation from a tetranuclear Fe4S4 cluster into a dinuclear sulfide-free Fe2 cluster

New Journal of Chemistry

Volumn 21, Issue 2, 1997, Pages 231-235

  Le Pape, Laurent ^a   Excoffon, Pierre ^a   Lamotte, Bernard ^a   Laugier, Jean ^a   Rius, Gérard ^a,b  

^a CEA GRENOBLE   (France)

^b UNIVERSITÉ DE LA ROCHELLE   (France)

Author keywords

Cluster transformation; Crystal growth; Iron sulfur cluster; Metalloprotein; X ray structure

Indexed keywords

EID: 1842327269     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (23)

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18. 3CN used for the solutions and for synthesis was dried by CaH2 and distilled twice (the second time inside the glovebox) under argon atmosphere.
19. The pyrex tubes were perfectly airtight, being closed by greased Schlenk-type threaded ground glass joints equipped with an o-ring.
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22. Anal calc: C, 55.3; H, 6.45; N, 3.23; O, 7.4; S, 14.8; Fe, 12.9. Found: C, 55.5; H, 6.33; N, 3.48; O, 8.78; S, 15.8; Fe, 12.3.
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