Molecular Routes to Metal Oxides and Metal Silicates. Synthesis and Thermal Decomposition Studies of Eclipsed Mo2[O2Si(OtBu)2]3 and W2(NHMe2)2[O2Si(O tBu)2]2[OSi(OH)(OtBu) 2]2

Chemistry of Materials

Volumn 9, Issue 2, 1997, Pages 588-595

  Su, Kai ^b   Tilley, T Don ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000676338     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm960413s     Document Type: Article

References (46)

1. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
2. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
3. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
4. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
5. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
6. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
7. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
8. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
9. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
10. For example see: (a) Ultrastructure Processing of Advanced Materials; Uhlmann, D. R., Ulrich, D. R., Eds.; Wiley-Interscience: New York, 1992. (b) Better Ceramics Through Chemistry V; Materials Research Society Symposia Proceedings; Hampden-Smith, M. J., Klemperer, W. G., Brinker, C. J., Eds.; Materials Research Society: Pittsburgh, 1992 Vol. 271. (c) Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley: New York, 1992. (d) Bowes, C. L.; Ozin, G. A. Adv. Mater. 1996, 8, 13. (e) Amabilino, D. B.; Stoddart, J. F. Chem. Rev. (Washington, D.C.) 1995, 95, 2725. (f) Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558. (g) Hubert-Pfalzgraf, L. G. New J. Chem. 1987, 11, 663. (h) Mehrotra, R. C. J. Non-Cryst. Solids 1988, 700, 1. (i) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 165. (j) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. (Washington, D.C.) 1993, 93, 1205.
11. References on the single-source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Materials Research Society Symposia Proceedings; Brinker, C. J.; Clark, D. E.; Ulrich, D. R., Eds.; North-Holland: New York, 1984 Vol. 32, p 152. (c) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. (d) Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169.
12. References on the single-source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Materials Research Society Symposia Proceedings; Brinker, C. J.; Clark, D. E.; Ulrich, D. R., Eds.; North-Holland: New York, 1984 Vol. 32, p 152. (c) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. (d) Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169.
13. References on the single-source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Materials Research Society Symposia Proceedings; Brinker, C. J.; Clark, D. E.; Ulrich, D. R., Eds.; North-Holland: New York, 1984 Vol. 32, p 152. (c) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. (d) Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169.
14. References on the single-source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Materials Research Society Symposia Proceedings; Brinker, C. J.; Clark, D. E.; Ulrich, D. R., Eds.; North-Holland: New York, 1984 Vol. 32, p 152. (c) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. (d) Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169.
15. References on the single-source precursor approach: (a) Cowley, A. H.; Jones, R. A. Angew. Chem., Int. Ed. Engl. 1989, 28, 1208. (b) Williams, A. G.; Interrante, L. V. In Better Ceramics Through Chemistry; Materials Research Society Symposia Proceedings; Brinker, C. J.; Clark, D. E.; Ulrich, D. R., Eds.; North-Holland: New York, 1984 Vol. 32, p 152. (c) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167. (d) Chaput, F.; Lecomte, A.; Dauger, A.; Boilot, J. P. Chem. Mater. 1989, 1, 199. (e) Hoffman, D. M. Polyhedron 1994, 13, 1169.
16. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001.
17. (b) Terry, K. W. Ph.D. Thesis, University of California at San Diego, 1993.
18. (c) Terry, K. W.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1992, 4, 1290.
19. (d) Terry, K. W.; Lugmair, C. G.; Gantzel, P. K.; Tilley, T. D. Chem. Mater. 1996, 8, 274.
20. (e) Terry, K. W.; Lugmair, C. G.; Tilley, T. D., manuscript in preparation.
21. Su, K.; Tilley, T. D.; Sailor, M. J. J. Am. Chem. Soc. 1996, 118, 3459.
22. (a) Transition Metal Oxides: Surface Chemistry and Catalysis; Kung, H. H.; Elsevier: Amsterdam, 1989.
23. (b) Kim, D. S.; Ostromecki, M.; Wachs, I. E.; Kohler, S. D.; Ekerdt, J. G. Catal. Lett. 1995, 33, 209.
24. (c) Sullivan, D. L.; Roark, R. D.; Ekerdt, J. G.; Deutsch, S. E.; Gates, B. C. J. Phys. Chem. 1995, 99, 3678.
25. (d) Suzuki, K.; Hayakawa, T.; Shimizu, M.; Takehira, K. Catal. Lett. 1995, 30, 159.
26. (e) Banares, M. A.; Hu, H. C.; Wachs, I. E. J. Catal. 1995, 155, 249.
27. (f) Williams, C. C.; Ekerdt, J. G. J. Catal. 1993, 141, 430.
28. (g) Elev, I. V.; Shelimov, B. N.; Kazanskii, V. B. 1989, 30, 787 and references therein.
29. Miner, C. S., Jr.; Bryan, L. A.; Holysz, R. P.; Pedlow, G. W., Jr. Ind. Eng. Chem, 1947, 39, 1368.
30. Chisholm, M. H.; Cotton, F. A.; Frenz, B. A.; Reichert, W. W.; Shive, L. W.; Stults, B. R. J. Am. Chem. Soc. 1976, 98, 4469.
31. Chisholm, M. H.; Cotton, F. A.; Extine, M. W.; Stults, B. R. J. Am. Chem. Soc. 1976, 98, 4477.
32. Chisholm, M. H.; Folting, K.; Hampden-Smith, M.; Smith, C. A. Polyhedron 1987, 6, 1747.
33. Chisholm, M. H.; Cotton, F. A. Acc. Chem. Soc. 1977, 11, 356.
34. Albright, T. A.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 7736.
35. Blatchford, T. P.; Chisholm, M. H.; Folting, K.; Huffman, J. C. Inorg. Chem. 1980, 19, 3175.
36. Blatchford, T. P.; Chisholm, M. H.; Huffman, J. C. Inorg. Chem. 1987, 26, 1920.
37. Chisholm, M. H.; Folting, K.; Hampden-Smith, M.; Smith, C. A. Polyhedron 1987, 6, 1747.
38. Chisholm, M. H.; Folting, K.; Haubrich, S. T.; Martin, J. D. Inorg. Chim. Acta 1993, 213, 17.
39. Akiyama, M.; Chisholm, M. L.; Cotton, F. A.; Extine, M. W.; Haitko, D. A.; Little, D.; Fanwick, P. E. Inorg. Chem. 1979, 18, 2266.
40. Chisholm, M. H.; Kramer, K. S.; Martin, J. D.; Huffman, J. C.; Lobkovsky, E. B.; Streib, W. E. Inorg. Chem. 1992, 31, 4469.
41. Chisholm, M. H.; Parkin, I. P.; Huffman, J. C.; Lobkovsky, E. M.; Folting, K. Polyhedron 1991, 10, 2839.
42. (a) Abe, Y.; Gunji, T.; Kimata, Y.; Kuramata, M.; Kasgöz, A.; Misono, T. J. Non-Cryst. Solids 1990, 121, 21.
43. (b) Gunji, T.; Nagao, Y.; Misono, T.; Abe, Y. J. Polym. Sci.; Part A: Polym. Chem. 1991, 29, 941.
44. (c) Gunji, T.; Nagao, Y.; Misono, T.; Abe, Y. J. Polym. Sci.; Part A: Polym. Chem. 1992, 30, 371.
45. Molybdenum. An Outline of Its Chemistry and Uses; Braithwaite, E. R., Haber, J., Eds.; Elsevier: Amsterdam, 1994; p 14.
46. Baxter, D. V.; Chisholm, M. H.; DiStasi, V. F.; Haubrich, S. T. Chem. Mater. 1995, 7, 84.