CO2 + O(1D) isotopic exchange: Laboratory and modeling studies

Journal of Geophysical Research Atmospheres

Volumn 105, Issue D12, 2000, Pages 15213-15229

  Johnston, J C ^a,b   Rockmann T ^a   Brenninkmeijer, C A M ^a  

^a MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

^b Iterations   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; CARBON DIOXIDE; TROPOSPHERE;

EID: 0007490348     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2000jd900070     Document Type: Article

References (63)

1. 2 gas, in References and Intercomparison Materials for Stable Isotopes of Light Elements, pp. 155-162, Int. At. Energy Agency, Vienna, 1995.
2. 2 at 298 K, J. Chem. Phys., 83, 1648-1656, 1985.
3. Anderson, S.M., J. Morton, and K. Mauersberger, Laboratory measurements of ozone isotopomers by tunable diode laser absorption spectroscopy, Chem. Phys. Lett., 156, 175-180, 1989.
4. 2+M, J. Chem. Phys., 107, 5385-5392, 1997.
5. Atkinson, R., D.L. Baulch, R.A. Cox, R.F.J. Hampson, J.A. Kerr, M.J. Rossi, and J. Troe, Evaluated kinetic and photochemical data for atmospheric chemistry: Supplement V, Atmos. Environ., 30, pp. 1125-1600, 1996.
6. 10, J. Chem. Phys., 90, 6099-6109, 1989.
7. Barth, V., and A. Zahn, Oxygen isotope composition of carbon dioxide in the middle atmosphere, J. Geophys. Res., 102, 12,995-13,007, 1997.
8. 1D) with carbon dioxide, Trans. Faraday Soc., 62, 2768-2773, 1966.
9. Bhattacharya, S.K., and M.H. Thiemens, New evidence for symmetry dependent isotope effects: O + CO reaction, Z. Naturforsch. A, 44, 435-444, 1989a.
10. 2 reaction, Z. Naturforsch. A, 44, 811-813, 1989b.
11. Blamont, J.E., and E. Chassefiére, First detection of ozone in the middle atmosphere of Mars from solar occultation measurements, Icarus, 104, 324-336, 1993.
12. 2, Science, 269, 1098-1102, 1995.
13. 2, 1, Surface fluxes, J. Geophys. Res., 102, 5857-5872, 1997.
14. 16O ratios in atmospheric nitrous oxide: A mass-independent anomaly, Science, 278, 1774-1776, 1997.
15. Coleman, J.J., X. Xu, M.H. Thiemens, and W.C. Trogler, Photopolymerization and mass independent fractionations in carbon disulfide, Science, 273, 774-776, 1996.
16. 1D) with carbon dioxide, J. Phys. Chem., 74, 2621-2625, 1970.
17. DeMore, W.B., S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Jet Propul. Lab., Pasadena, Calif., 1997.
18. 17O measurements of carbonate from ALH 84001, Science, 280, 1580-1582, 1998.
19. 3, J. Phys. Chem., 97, 7484-7490, 1993.
20. Gamo, T., M. Tsutsumi, H. Sakai, T. Nakazawa, M. Tanaka, H. Honda, H. Kubo, and T. Itoh, Carbon and oxygen isotopic ratios of carbon dioxide of a stratospheric profile over Japan, Tellus, Ser. B, 41, 127-133, 1989.
21. 2 over Japan, Geophys. Res. Lett., 22, 397-400, 1995.
22. Gear, C. W., The automatic integration of ordinary differential equations, Numer. Math., 14, 176-179, 1971.
23. Goldman, A., F.J. Murcray, D.G. Murcray, J.J. Kosters, C.P. Rinsland, J.-M. Flaud, C. Camy-Peyret, and A. Barbe, Isotopic abundances of stratospheric ozone from balloon-borne high-resolution infrared solar spectra, J. Geophys. Res., 94, 8467-8473, 1989.
24. Houghton, J.T., L.G. Meira Filho, B.A. Callander, N. Harris, A. Kattenberg, and K. Maskell, Climate Change 1995, The Science of Climate Change, Contribution of Working Group 1 to the Second Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge Univ. Press, New York, 1996.
25. Irion, F.W., M.R. Gunson, C.P. Rinsland, Y.L. Yung, M.C. Abrams, A.Y. Chang, and A. Goldman, Heavy ozone enrichments from ATMOS infrared solar spectra, Geophys. Res. Lett., 23, 2377-2380, 1996.
26. 3, J. Chem. Phys., 54, 919-926, 1971.
27. Jakosky, B.M., and J.H. Jones, The history of martian volatiles, Rev. Geophys., 35, 1-16, 1997.
28. 18O mixtures, J. Chem. Phys., 111, 7179-7182, 1999.
29. Karlsson, H.R., R.N. Clayton, E.K. Gibson, and T. Mayeda, Water in SNC meteorites: Evidence for a Martian hydrosphere, Science, 255, 1409-1411, 1992.
30. 3 in the gas phase, J. Chem. Phys., 36, 416-422, 1962.
31. Kaye, J.A., Mechanisms and observations for isotope fractionation of molecular species in planetary atmospheres, Rev. Geophys., 25, 1609-1658, 1987.
32. Kaye, J.A., and D.F. Strobel, Enhancement of heavy ozone in the Earth's atmosphere?, J. Geophys. Res., 88, 8447-8452, 1983.
33. Larsen, N.W., and T. Pedersen, Microwave spectroscopy of isotopic cyclobutene ozonide as a means of quantification of ozone isotopomers, J. Mol. Spectrosc., 166, 372-382, 1994.
34. Luz, B., E. Barkan, M.L. Bender, M.H. Thiemens, and K.A. Boering, Triple-isotope composition of atmospheric oxygen as a tracer for biospheric productivity, Nature, 400, 547-550, 1999.
35. Malleson, A.M., H.M. Kellett, R.G. Myhill, and W.P. Sweetenham, FACSIMILE users guide, Ind. Res. and Tech. Serv., Harwell Lab., Oxford, England, 1990.
36. Mauersberger, K., Measurement of heavy ozone in the stratosphere, Geophys. Res. Lett., 8, 935-937, 1981.
37. Mauersberger, K., Ozone isotope measurements in the stratosphere, Geophys. Res. Lett., 14, 80-83, 1987.
38. Mauersberger, K., J. Morton, B. Schueler, J. Stehr, and S.M. Anderson, Multi-isotope study of ozone: Implications for the heavy ozone anomaly, Geophys. Res. Lett., 20, 1031-1034, 1993.
39. Mauersberger, K., B. Erbacher, D. Krankowsky, J. Günther, and R. Nickel, Ozone isotope enrichement: Isotopomer-specific rate coefficients, Science, 283, 370-372, 1999.
40. 3 as observed in arctic ground-based FTIR -spectra, Geophys. Res. Lett., 23, 551-554, 1996.
41. 2, J. Chem. Phys., 45, 4469-4481, 1966.
42. Morton, J., J. Barnes, B. Schueler, and K. Mauersberger, Laboratory studies of heavy ozone, J. Geophys. Res., 95, 901-907, 1990.
43. Okabe, H., Photochemistry of Small Molecules, 431 pp., John Wiley, New York, 1978.
44. 12C ratios of atmospheric CO due to the presence of mass-independent oxygen isotope enrichment, Geophys. Res. Lett., 25, 3163-3166, 1998.
45. Röckmann, T., C.A.M. Brenninkmeijer, P. Neeb, and P.J. Crutzen, Ozonolysis of nonmethane hydrocarbons as a source of the observed mass-independent oxygen isotope enrichment in tropospheric CO, J. Geophys. Res., 103, 1463-1470, 1998a.
46. Röckmann, T., C.A.M. Brenninkmeijer, G. Saueressig, P. Bergamaschi, J.N. Crowley, H. Fischer, and P.C. Crutzen, Mass-independent oxygen isotope fractionation in atmospheric CO as a result of the reaction CO + OH, Science, 281, 1444-1448, 1998b.
47. Santrock, J., S.A. Studley, and J.M. Hayes, Isotopic analysis based on the mass spectrum of carbon dioxide, Anal. Chem., 57, 1444-1448, 1985.
48. Schueler, B., J. Morton, and K. Mauersberger, Measurement of isotopic abundances in collected samples of stratospheric ozone samples, Geophys. Res. Lett., 17, 1295-1298, 1990.
49. Steinfeld, J.I., J.S. Francisco, and W.L. Hase, Chemical Kinetics and Dynamics, 548 pp., Prentice-Hall, Englewood Cliffs, N. J., 1989.
50. Thiemens, M.H., Mass-independent isotope effects in planetary atmospheres and the early solar system, Science, 283, 341-345, 1999.
51. Thiemens, M.H., and J.E. Heidenreich, The mass-independent fractionation of oxygen: A novel isotope effect and its possible cosmochemical implications, Science, 219, 1073-1075, 1983.
52. Thiemens, M.H., and T. Jackson, Pressure dependence for heavy isotope enhancement in ozone formation, Geophys. Res. Lett., 17, 717-719, 1990.
53. 2, Geophys. Res. Lett., 18, 669-672, 1991.
54. 2, the link to ozone chemistry, and the possible occurrence in the Martian atmosphere, Geophys. Res. Lett., 22, 255-257, 1995a.
55. Thiemens, M.H., T. Jackson, E.C. Zipf, P.W. Erdman, and C. van Egmond, Carbon dioxide and oxygen isotope anomalies in the mesosphere and stratosphere, Science, 270, 969-972, 1995b.
56. 2: Measurements from the NOAA Global Air Sampling Network, J. Geophys. Res., 101, 25,897-25,916, 1996.
57. Urey, H., The thermodynamic properties of isotopic substances, J. Chem. Soc., 1947, 562-581, 1947.
58. 3: Dynamics of the dissociation, J. Chem. Phys., 86, 6745-6756, 1987.
59. 2 at low temperatures, J. Chem. Phys., 47, 1764-1769, 1967.
60. Wen, J., and M.H. Thiemens, Experimental and theoretical study of isotope effects on ozone decomposition, J. Geophys. Res., 96, 10,911-10,921, 1991.
61. 2 exchange and stratospheric consequences, J. Geophys. Res., 98, 12,801-12,808, 1993.
62. 1D) in the stratosphere, Geophys. Res. Lett., 18, 13-16, 1991.
63. Yung, Y.L., A.Y.T. Lee, F.W. Irion, W.B. DeMore, and J. Wen, Carbon dioxide in the atmosphere: Isotope exchange with ozone and its use as a tracer in the middle atmosphere, J. Geophys. Res., 102, 10,857-10,866, 1997.