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Volumn 283, Issue 5400, 1999, Pages 370-372

Ozone isotope enrichment: Isotopomer-specific rate coefficients

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL REACTION KINETICS; ISOTOPE LABELING; MOLECULAR DYNAMICS; OZONE LAYER; PRIORITY JOURNAL; REACTION ANALYSIS; THEORY;

EID: 0033556318     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.283.5400.370     Document Type: Article
Times cited : (197)

References (30)
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    • M. H. Thiemens and T. Jackson, ibid. 15, 639 (1988); ibid. 17, 717 (1990); J. Morton, J. Barnes, B. Schueler, K. Mauersberger, J. Geophys. Res. 95, 901 (1990).
    • (1990) Geophys. Res. Lett. , vol.17 , pp. 717
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    • note
    • 18O] = 0.205% throughout the troposphere and stratosphere.
  • 10
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    • note
    • calc - 1] X 100% with mass M = 49 through 54. For ozone produced in atmospheric oxygen, we used the values listed in (6) to calculate the statistical ratios.
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    • S. M. Anderson and K. Mauersberger, J. Geophys. Res. 100, 3033 (1995); D. W. Arnold, C. Xu, E. H. Kim, D. M. Neumark, J. Chem. Phys. 101, 912 (1994).
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    • J. J. Valentini, J. Chem. Phys. 86, 6757 (1987); D. R. Bates, Geophys. Res. Lett. 15, 13 (1988); W. L. Morgan and D. R. Bates, Planet. Space Sci. 40, 1573 (1992); K. S. Griffith and G. I. Gellene, J. Chem. Phys. 96, 4403 (1992).
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    • J. J. Valentini, J. Chem. Phys. 86, 6757 (1987); D. R. Bates, Geophys. Res. Lett. 15, 13 (1988); W. L. Morgan and D. R. Bates, Planet. Space Sci. 40, 1573 (1992); K. S. Griffith and G. I. Gellene, J. Chem. Phys. 96, 4403 (1992).
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    • J. J. Valentini, J. Chem. Phys. 86, 6757 (1987); D. R. Bates, Geophys. Res. Lett. 15, 13 (1988); W. L. Morgan and D. R. Bates, Planet. Space Sci. 40, 1573 (1992); K. S. Griffith and G. I. Gellene, J. Chem. Phys. 96, 4403 (1992).
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    • J. J. Valentini, J. Chem. Phys. 86, 6757 (1987); D. R. Bates, Geophys. Res. Lett. 15, 13 (1988); W. L. Morgan and D. R. Bates, Planet. Space Sci. 40, 1573 (1992); K. S. Griffith and G. I. Gellene, J. Chem. Phys. 96, 4403 (1992).
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    • note
    • 16O = 1.245 was used; this ratio is in agreement with the experimental data presented in (13) and in Fig. 1.
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    • note
    • 36O. 22. We thank S. M. Anderson at Augsburg College, who contributed substantially to the experiment and obtained the first set of rate coefficients.
  • 30
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    • note
    • We thank S. M. Anderson at Augsburg College, who contributed substantially to the experiment and obtained the first set of rate coefficients.


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