Protonation of fischer-type alkylidyne carbonyltungsten complexes. Structural comparison of alkylidyne and alkylidene metal complexes, including a neutron diffraction study of [W(CHCH3)Cl2(CO) (PMe3)2]

Inorganica Chimica Acta

Volumn 279, Issue 1, 1998, Pages 7-23

  Bastos, Cecilia M ^a   Lee, Ken S ^a,e   Kjelsberg, Michael A ^d   Mayr, Andreas ^a,b   Van Engen, Donna ^d   Koch, Stephen A ^a   Franolic, John D ^a   Klooster, Wim T ^c   Koetzle, Thomas F ^c  

^a STONY BROOK UNIVERSITY   (United States)

^b UNIVERSITY OF HONG KONG   (Hong Kong)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

^d PRINCETON UNIVERSITY   (United States)

^e JACKSON STATE UNIVERSITY   (United States)

Author keywords

Alkylidene complexes; Crystal structures; Neutron diffraction; Tungsten complexes

Indexed keywords

CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; LIGANDS; METAL COMPLEXES; NEUTRON DIFFRACTION; NEUTRONS; PROTONATION; TUNGSTEN COMPOUNDS;

ALKYLIDENE COMPLEXES; NEUTRON DIFFRACTION DATA; NEUTRON DIFFRACTION STUDIES; SOLID-STATE STRUCTURES; STRUCTURAL COMPARISON; TRIETHYLAMINES; TUNGSTEN COMPLEX; X-RAY DIFFRACTION STUDIES;

X RAY CRYSTALLOGRAPHY;

EID: 0001794685     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(98)00004-8     Document Type: Article

References (94)

1. (a) E.O. Fischer, Angew. Chem. 86 (1974) 651; E.O. Fischer, Adv. Organomet. Chem. 14 (1976) 1;
2. (a) E.O. Fischer, Angew. Chem. 86 (1974) 651; E.O. Fischer, Adv. Organomet. Chem. 14 (1976) 1;
3. (b) E.O. Fischer, U. Schubert, J. Organomet. Chem. 100 (1975) 59;
4. (c) H. Fischer, P. Hofmann, F.R. Kreissl, R.R. Schrock, U. Schubert, K. Weiss, Carbyne Complexes, VCH, Weinheim, 1988;
5. (d) H.P. Kim, R.J. Angelici, Adv. Organomet. Chem. 27 (1987) 51;
6. (e) R.R. Schrock, Acc. Chem. Res. 19 (1986) 342;
7. (f) M.A. Gallop, W.R. Roper, Adv. Organomet. Chem. 25 (1986) 121;
8. (g) F.G.A. Stone, Adv. Organomet. Chem. 31 (1991) 53;
9. (h) A. Mayr, H. Hoffmeister, Adv. Organomet. Chem. 32 (1991) 227;
10. (i) A. Mayr, C.M. Bastos, Prog. Inorg. Chem. 40 (1992) 1;
11. (j) P.F. Engel, M. Pfeffer, Chem. Rev. 95 (1995) 2281;
12. (k) A. Mayr, S. Ahn, Adv. Trans. Met. Coord. Chem. 1 (1996) 1;
13. (1) R.A. Henderson, Angew. Chem. 108 (1996) 1049; Angew. Chem., Int. Ed. Engl. 35 (1996) 947;
14. (1) R.A. Henderson, Angew. Chem. 108 (1996) 1049; Angew. Chem., Int. Ed. Engl. 35 (1996) 947;
15. (m) L. McElwee-White, Synlett. (1996) 806.
16. (a) F.R. Kreissl, W.J. Sieber, M. Wolfgruber, J. Riede, Angew. Chem. 96 (1984) 618; Angew., Chem. Int. Ed. Engl. 23 (1984) 640;
17. (a) F.R. Kreissl, W.J. Sieber, M. Wolfgruber, J. Riede, Angew. Chem. 96 (1984) 618; Angew., Chem. Int. Ed. Engl. 23 (1984) 640;
18. (b) F.R. Kreissl, W.J. Sieber, H. Keller, J. Riede, M. Wolfgruber, J. Organomet. Chem. 320 (1987) 83;
19. (c) J.A.K. Howard, J.C. Jeffery, S. Li, F.G.A. Stone, J. Chem. Soc., Dalton Trans. (1992) 627;
20. (d) J.C. Jeffery, S. Li, F.G.A. Stone, J. Chem. Soc., Dalton Trans. (1992) 635;
21. (e) K.B. Kingsbury, J.D. Carter, A. Wilde, H. Park, F. Takusagawa, L. McElwee-White, J. Am. Chem. Soc. 115 (1993) 10 056;
22. (f) M.D. Mortimer, J.D. Carter, L. McElwee-White, Organometallics 1 (1993) 4493.
23. J.A.K. Howard, J.C. Jeffery, J.C.V. Laurie, I. Moore, F.G.A. Stone, A. Stringer, Inorg. Chim. Acta 100 (1985) 23.
24. K.E. Garrett, J.B. Sheridan, D.B. Pourreau, W.C. Feng, G.L. Geoffroy, D.L. Staley, A.L. Rheingold, J. Am. Chem. Soc. 111 (1989) 8383.
25. (a) A.C. Filippou, W. Grünleitner, Z. Naturforsch., Teil B 44 (1989) 1023;
26. (b) E.M. Carnahan, S.J. Lippard, J. Am. Chem. Soc. 114 (1992) 4166;
27. (c) J.J.R. Fraústo Da Silva, M.A. Pellinghelli, J.A.L. Pombeiro, R.L. Richards, A. Tiripicchio, Y. Wang, J. Organomet. Chem. 454 (1993) C8.
28. (a) S.A. Brew, F.G.A. Stone, Adv. Organomet. Chem. 35 (1993) 135;
29. (b) A.P. James, F.G.A. Stone, J. Organomet. Chem. 310 (1986) 47.
30. (a) F.R. Kreissl, W.J. Sieber, M. Wolfgruber, J. Organomet. Chem. 270 (1984) C45;
31. (b) H.P. Kim, S. Kim, R.A. Jacobson, R.J. Angelici, Organometallics 3 (1984) 1124;
32. (c) R.A. Doyle, R.J. Angelici, Organometallics 8 (1989) 2207;
33. (d) M. Etienne, P.S. White, J.L. Templeton, J. Am. Chem. Soc. 113 (1991) 2324;
34. (e) J.C. Jeffery, F.G.A. Stone, G.K. Wiliams, Polyhedron 10 (1991) 215;
35. (f) G.C. Bruce, F.G.A. Stone, Polyhedron 11 (1992) 1607.
36. (a) P.R. Sharp, S.J. Holmes, R.R. Schrock, M.R. Churchill, H.J. Wasserman, J. Am. Chem. Soc. 103 (1981) 965;
37. (b) S.J. Holmes, R.R. Schrock, J. Am. Chem. Soc. 103 (1981) 4599;
38. (c) S.J. Holmes, D.N. Clark, H.W. Turner, R.R. Schrock, J. Am. Chem. Soc. 104 (1982) 6322;
39. (d) M.R. Churchill, H.J. Wasserman, H.W. Turner, R.R. Schrock, J. Am Chem. Soc. 104 (1982) 1710;
40. (e) M. Green, A.G. Orpen, I.D. Williams, J. Chem. Soc., Chem. Commun. (1982) 493;
41. (f) M. Bottrill, M. Green, A.G. Orpen, D.R. Saunders, I.D. Williams, J. Chem. Soc., Dalton Trans. (1989) 511.
42. A. Mayr, M.F. Asaro, M.A. Kjelsberg, K.S. Lee, D. Van Engen, Organometallics 6 (1987) 432.
43. C.M. Bastos, N. Daubenspeck, A. Mayr, Angew. Chem. 105 (1993) 793; Angew. Chem., Int. Ed. Engl. 32 (1993) 743.
44. C.M. Bastos, N. Daubenspeck, A. Mayr, Angew. Chem. 105 (1993) 793; Angew. Chem., Int. Ed. Engl. 32 (1993) 743.
45. (a) E.O. Fischer, A. Maasböl, Chem. Ber. 100 (1967) 2445;
46. (b) E.O. Fischer, A. Ruhs, F.R. Kreissl, Chem. Ber. 110 (1977) 805.
47. (a) A. Mayr, G.A. McDermott, A.M. Dorries, Organometallics 4 (1985) 608;
48. (b) G.A. McDermott, A.M. Dorries, A. Mayr, Organometallics 6 (1987) 925.
49. (a) A. Mayr, T.-Y. Lee, M.A. Kjelsberg, K.S. Lee, Organometallics 13 (1994) 2512;
50. (b) P. Steil, A. Mayr, Z. Naturforsch., Teil B 47 (1992) 656.
51. (a) L.M. Atagi, S.C. Critchlow, J.M. Mayer, J. Am. Chem. Soc. 114 (1992) 9223.
52. E.O. Fischer, T.L. Lindner, F.R. Kreissl, P. Braunstein, Chem. Ber. 110 (1977) 3139.
53. J.H. Wengrovius, R.R. Schrock, M.R. Churchill, H.J. Wasserman, J. Am. Chem. Soc. 104 (1982) 1739.
54. A.J. Bondi, J. Chem. Phys. 68 (1964) 441.
55. M.R. Churchill, H.J. Wasserman, Inorg. Chem. 22 (1983) 1574.
56. A. Mayr, C.M. Bastos, J. Am. Chem. Soc. 112 (1990) 7797.
57. (a) N.M. Kostíć, R.F. Fenske, Organometallics 1 (1982) 489;
58. (b) J. Ushio, H. Nakatsuji, T. Yonezawa, J. Am. Chem. Soc. 106 (1984) 5892.
59. A. Mayr, Comm. Inorg. Chem. 10 (1990) 227.
60. A. Mayr, K.S. Lee, M.A. Kjelsberg, D. Van Engen, J. Am. Chem. Soc. 108 (1986) 6079.
61. A.J. Schultz, R.K. Brown, J.M. Williams, R.R. Schrock, J. Am. Chem. Soc. 103 (1981) 169.
62. J. Espuelas, M.A. Esteruelas, F.J. Lahoz, L.A. Oro, N. Ruiz, J. Am. Chem. Soc. 115 (1993) 4683.
63. P. Schwab, R.H. Grubbs, J.W. Ziller, J. Am. Chem. Soc. 118 (1996) 100.
64. A. Höhn, H. Werner, J. Organomet. Chem. 255 (1990) 382.
65. G.R. Clark, K. Marsden, W.R. Roper, L.J. Wright, J. Am. Chem. Soc. 102 (1980) 6570.
66. M. Brookhart, M.L.H. Green, L.-L. Wong, Prog. Inorg. Chem. 36 (1988) 1.
67. J.H. Freudenberger, R.R. Schrock, Organometallics 4 (1985) 1937.
68. T.G. Appleton, H.C. Clark, L.E. Manzer, Coord. Chem. Rev. 10 (1973) 335.
69. J. Feldman, R.R. Schrock, Prog. Inorg. Chem. 39 (1991) 1.
70. (a) R. Taylor, O. Kennard, J. Am. Chem. Soc. 104 (1982) 5063;
71. (b) L. Brammer, J.M. Charnock, P.L. Goggin, R.J. Goodfellow, A.G. Orpen, T.F. Koetzle, J. Chem. Soc., Dalton Trans. (1991) 1789.
72. A. Albinati, V.I. Bakhmutov, K.G. Caulton, E. Clot, J. Eckert, O. Eisenstein, D.G. Gusev, V.V. Grushin, B.E. Hauger, W.T. Klooster, T.F. Koetzle, R.K. McMullan, T.J. O'Loughlin, M. Pélissier, J.S. Ricci, M.P. Sigalas, A.B. Vymenits, J. Am. Chem. Soc. 115 (1993) 7300.
73. S.G. Feng, P.S. White, J.L. Templeton, J. Am. Chem. Soc. 112 (1990) 8192.
74. A. Mayr, M.F. Asaro, T.J. Glines, D. Van Engen, G.M. Tripp, J. Am. Chem. Soc. 115 (1993) 8187.
75. J.L. Templeton, Adv. Organomet. Chem. 29 (1989) 1.
76. A. Mayr, C.M. Bastos, R.T. Chang, J.X. Haberman, K.S. Robinson, D.A. Belle-Oudry, Angew. Chem. 104 (1992) 802; Angew. Chem., Int. Ed. Engl. 31 (1992) 747.
77. A. Mayr, C.M. Bastos, R.T. Chang, J.X. Haberman, K.S. Robinson, D.A. Belle-Oudry, Angew. Chem. 104 (1992) 802; Angew. Chem., Int. Ed. Engl. 31 (1992) 747.
78. K.H. Dötz, H. Fischer, P. Hofmann, F.R. Kreissl, U. Schubert, K. Weiss, Transition Metal Carbene Complexes, Verlag Chemie, Weinheim, 1983.
79. R.J. Goddard, R. Hoffmann, E.D. Jemmis, J. Am. Chem. Soc. 102 (1980) 7667.
80. (a) D.C. Brower, K.R. Birdwhistell, J.L. Templeton, Organometallics 5 (1986) 94;
81. (b) W.J. Sieber, M. Wolfgruber, N.H. Tran-Huy, H.R. Schmidt, H. Heiss, P. Hofmann, F.R. Kreissl, J. Organomet. Chem. 341 (1988) 340.
82. P.J. Brothers, Prog. Inorg. Chem. 28 (1981) 1.
83. G.J. Kubas, Acc. Chem. Res. 21 (1988) 120.
84. R.K. McMullan, J. Epstein, J.R. Ruble, B.M. Craven, Acta Crystallogr., Sect. B 35 (1979) 688.
85. J. de Meulenaer, H. Tompa, Acta Crystallogr. 19 (1965) 1014.
86. L.K. Templeton, D.H. Templeton, Abstr. Am. Crystallogr. Assoc. Meet., Storrs, CT, 1973, p. 143.
87. L. Koester, Springer Tracts Mod. Phys. 80 (1977) 36.
88. J.-O. Lundgren, Crystallographic Computer Programs, Rep. UUIC-B13-4-05, Institute of Chemistry, University of Uppsala, Sweden, 1982.
89. P.J. Becker, P. Coppens, Acta Crystallogr., Sect. A 30 (1974) 129.
90. C.K. Johnson, ORTEP II, Report ORNL-5138, Oak Ridge National Laboratory, TN, 1976
91. S. Lincoln, S.A. Koch, Inorg. Chem. 25 (1986) 1594.
92. N. Walker, D. Stuart, Acta Crystallogr., Sect. A 39 (1983) 158.
93. Single Crystal Structure Analysis Software, Version 1.6, Molecular Structure Corporation, The Woodlands, TX, 1993.
94. International Tables of X-ray Crystallography, Vol. IV, Kynoch, Birmingham, UK, 1975, pp. 99, 149.