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Volumn 19, Issue 4, 2000, Pages 553-562

Palladium(II) complexes of chiral 1,2-diiminophosphoranes: Synthesis, structural characterization, and catalytic activity for the allylic alkylation

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0003314380     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990786d     Document Type: Article
Times cited : (52)

References (71)
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    • N-metalated iminophosphoranes (phosphoraneiminato complexes) have been more widely used in homogeneous catalysis. See for example: (c) Cavell, R. G.; Katti, K. V. US 005352813 A, Oct. 4, 1994. (d) Somogybari, A. F.; Creed, B. L.; Nicola, A. P.; Sanger, A. R.; Law, D. J.; Cavell, R. G. US 005557023 A, Sep. 17, 1996. (e) Law, D. J.; Cavell, R. G. J. Mol. Catal. 1994, 91, 175. (f) Stephan, D. W.; Guérin, F.; Spence, R.; Koch, L.; Gao, X.; Brown, S. J.; Swabey, J. W. Wang, Q.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 2046. (g) Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 1116. (h) Vollmerhaus, R. Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
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    • N-metalated iminophosphoranes (phosphoraneiminato complexes) have been more widely used in homogeneous catalysis. See for example: (c) Cavell, R. G.; Katti, K. V. US 005352813 A, Oct. 4, 1994. (d) Somogybari, A. F.; Creed, B. L.; Nicola, A. P.; Sanger, A. R.; Law, D. J.; Cavell, R. G. US 005557023 A, Sep. 17, 1996. (e) Law, D. J.; Cavell, R. G. J. Mol. Catal. 1994, 91, 175. (f) Stephan, D. W.; Guérin, F.; Spence, R.; Koch, L.; Gao, X.; Brown, S. J.; Swabey, J. W. Wang, Q.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 2046. (g) Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 1116. (h) Vollmerhaus, R. Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
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    • N-metalated iminophosphoranes (phosphoraneiminato complexes) have been more widely used in homogeneous catalysis. See for example: (c) Cavell, R. G.; Katti, K. V. US 005352813 A, Oct. 4, 1994. (d) Somogybari, A. F.; Creed, B. L.; Nicola, A. P.; Sanger, A. R.; Law, D. J.; Cavell, R. G. US 005557023 A, Sep. 17, 1996. (e) Law, D. J.; Cavell, R. G. J. Mol. Catal. 1994, 91, 175. (f) Stephan, D. W.; Guérin, F.; Spence, R.; Koch, L.; Gao, X.; Brown, S. J.; Swabey, J. W. Wang, Q.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 2046. (g) Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 1116. (h) Vollmerhaus, R. Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
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    • N-metalated iminophosphoranes (phosphoraneiminato complexes) have been more widely used in homogeneous catalysis. See for example: (c) Cavell, R. G.; Katti, K. V. US 005352813 A, Oct. 4, 1994. (d) Somogybari, A. F.; Creed, B. L.; Nicola, A. P.; Sanger, A. R.; Law, D. J.; Cavell, R. G. US 005557023 A, Sep. 17, 1996. (e) Law, D. J.; Cavell, R. G. J. Mol. Catal. 1994, 91, 175. (f) Stephan, D. W.; Guérin, F.; Spence, R.; Koch, L.; Gao, X.; Brown, S. J.; Swabey, J. W. Wang, Q.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 2046. (g) Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 1116. (h) Vollmerhaus, R. Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
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    • N-metalated iminophosphoranes (phosphoraneiminato complexes) have been more widely used in homogeneous catalysis. See for example: (c) Cavell, R. G.; Katti, K. V. US 005352813 A, Oct. 4, 1994. (d) Somogybari, A. F.; Creed, B. L.; Nicola, A. P.; Sanger, A. R.; Law, D. J.; Cavell, R. G. US 005557023 A, Sep. 17, 1996. (e) Law, D. J.; Cavell, R. G. J. Mol. Catal. 1994, 91, 175. (f) Stephan, D. W.; Guérin, F.; Spence, R.; Koch, L.; Gao, X.; Brown, S. J.; Swabey, J. W. Wang, Q.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 2046. (g) Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R.; Xu, W.; Zoricak, P.; Harrison, D. G. Organometallics 1999, 18, 1116. (h) Vollmerhaus, R. Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
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    • note
    • No racemization of the product dimethyl 1,3-diphenylprop-2-enylmalonate occurred in the presence of an excess of 2 or 3 at 36°C nor under the catalytic reaction conditions.


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