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Volumn 64, Issue 4, 1999, Pages 1082-1083

Rapid microwave-induced palladium-catalyzed asymmetric allylic alkylation

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; PALLADIUM;

EID: 0033582656     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo981896h     Document Type: Article
Times cited : (61)

References (39)
  • 3
    • 0003431335 scopus 로고    scopus 로고
    • Liebeskind, L. S., Ed.; JAI Press: Greenwich
    • (b) Shibasaki, M. In Advances in Metal-Organic Chemistry; Liebeskind, L. S., Ed.; JAI Press: Greenwich, 1996; Vol. 5, p 119.
    • (1996) Advances in Metal-Organic Chemistry , vol.5 , pp. 119
    • Shibasaki, M.1
  • 24
    • 0001247165 scopus 로고
    • 2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl. See: Noyori, R.; Takaya, H. Acc. Chem. Res. 1990, 23, 345.
    • (1990) Acc. Chem. Res. , vol.23 , pp. 345
    • Noyori, R.1    Takaya, H.2
  • 30
    • 0345663092 scopus 로고    scopus 로고
    • note
    • One often overlooked hazard that may become prevalent under microwave irradiation is the formation of electrical arcs. Arcing could result in vessel rupture if air and flammable compounds are involved. We believe the possibility of running reactions in an inert gas atmosphere is a distinct advantage with the sealed reaction vessel strategy.
  • 35
    • 0344800127 scopus 로고    scopus 로고
    • note
    • The reaction time could probably be reduced below 2.0 min with higher microwave power, but 500 W is the limit of our currently available apparatus (MicroWell 10).
  • 36
    • 0344368351 scopus 로고    scopus 로고
    • note
    • +, the ion strength of the solution depends only on the Pd-catalyst and dissolved KOAc (partly dissolved). Calculation yields I = 0.014-0.026 for 3 and I = 0.011-0.017 for 4 (lower limit: no KOAc dissolved, higher limit: all KOAc dissolved).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.