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Volumn 36, Issue 9, 1997, Pages 972-973

Supramolecular Isomerism in Coordination Polymers: Conformational Freedom of Ligands in [Co(NO3)2(1,2-bis(4-pyridyl)ethane)1.5] n

Author keywords

Cobalt; Crystal engineering; Isomerizations; Microporosity; Supramolecular chemistry

Indexed keywords


EID: 0030988754     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199709721     Document Type: Article
Times cited : (812)

References (38)
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    • A search of the Cambridge Structural Database revealed twelve structures in which 1 sustains simple, linear, chain polymers (reference codes: BELNEL, DEDJAX, DEDJAX10, DUDZOR, FINGEO, KIDGOT, LAPLET, SIZWAZ, VINBAV, VOGGON, WEJXOY, WEJZIU, YIBHEW). F. H. Allen, O. Kennard, R. Taylor, Acc. Chem. Res. 1983, 16, 146.
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    • c) O. M. Yaghi, G. Li, Angew. Chem. 1995, 107, 232; Angew. Chem. Int. Ed. Engl. 1995, 34, 207;
    • (1995) Angew. Chem. , vol.107 , pp. 232
    • Yaghi, O.M.1    Li, G.2
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    • c) O. M. Yaghi, G. Li, Angew. Chem. 1995, 107, 232; Angew. Chem. Int. Ed. Engl. 1995, 34, 207;
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 207
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    • c) S. Subramanian, M. J. Zaworotko, Angew. Chem. 1995, 107, 2295; Angew. Chem. Int. Ed. Engl. 1995, 34, 2127;
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 2127
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    • 33947093788 scopus 로고
    • The observations reported herein are closely related to conformational polymorphism, which can be regarded as another type of supramolecular isomerism: a) J. Bernstein, A. T. Hagler, J. Am. Chem. Soc. 1978, 100, 673; b) J. Bernstein in Organic Solid State Chemistry Vol. 32, Elsevier, Amsterdam, 1987, chap. 13, pp. 471-518.
    • (1978) J. Am. Chem. Soc. , vol.100 , pp. 673
    • Bernstein, J.1    Hagler, A.T.2
  • 17
    • 0001909634 scopus 로고
    • Elsevier, Amsterdam, chap. 13
    • The observations reported herein are closely related to conformational polymorphism, which can be regarded as another type of supramolecular isomerism: a) J. Bernstein, A. T. Hagler, J. Am. Chem. Soc. 1978, 100, 673; b) J. Bernstein in Organic Solid State Chemistry Vol. 32, Elsevier, Amsterdam, 1987, chap. 13, pp. 471-518.
    • (1987) Organic Solid State Chemistry , vol.32 , pp. 471-518
    • Bernstein, J.1
  • 20
    • 0642382853 scopus 로고    scopus 로고
    • unpublished results
    • 2 and 1 have been recently obtained: P. Losier, M. J. Zaworotko, unpublished results.
    • Losier, P.1    Zaworotko, M.J.2
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    • 0030484816 scopus 로고    scopus 로고
    • P. Losier, M. J. Zaworotko, Angew. Chem. 1996. 108, 2957; Angew. Chem. Int. Ed. Engl. 1996, 35, 2779.
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 2779
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    • 33748234364 scopus 로고    scopus 로고
    • a) P. J. Stang, B. Olenyuk, Angew. Chem. 1996, 108, 798; Angew. Chem. Int. Ed. Engl. 1996, 35, 732;
    • (1996) Angew. Chem. Int. Ed. Engl. , vol.35 , pp. 732
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    • c) C. A. Hunter, Angew. Chem. 1995, 107, 1181; Angew. Chem. Int. Ed. Engl. 1995, 34, 1079;
    • (1995) Angew. Chem. , vol.107 , pp. 1181
    • Hunter, C.A.1
  • 27
    • 33748229364 scopus 로고
    • c) C. A. Hunter, Angew. Chem. 1995, 107, 1181; Angew. Chem. Int. Ed. Engl. 1995, 34, 1079;
    • (1995) Angew. Chem. Int. Ed. Engl. , vol.34 , pp. 1079
  • 30
    • 0642321470 scopus 로고    scopus 로고
    • note
    • w = 0.055 with GOF = 2.52. The guest molecules in 3b and 3c and the ethylene portion of the antispacer in 3b exhibited high thermal motion. One of the chloroform molecules in 3c was rotationally disordered.
  • 33
    • 84955392022 scopus 로고    scopus 로고
    • (Ed.: G. R. Desiraju), Wiley, Chichester
    • Direct analogies can be drawn between supramolecular isomerism in coordination polymers and polymorphism in molecular crystals. Indeed, the term "superisomerism" was recently applied to describe polymorphism in molecular crystals: J. D. Dunitz in The Crystal as a Supramolecular Entity (Ed.: G. R. Desiraju), Wiley, Chichester, 1996.
    • (1996) The Crystal As a Supramolecular Entity
    • Dunitz, J.D.1
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    • c) P. Baxter, J.-M. Lehn, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92; Angew. Chem. Int. Ed. Engl. 1993, 32, 69;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 69


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.