The adsorption of sulfur on Rh(111) and Cu/Rh(111) surfaces

Journal of Chemical Physics

Volumn 108, Issue 7, 1998, Pages 3064-3073

  Rodriguez, José A ^a   Chaturvedi, Sanjay ^a   Kühn, Mark ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000189110     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.475697     Document Type: Article

References (67)

1. K. C. Taylor, Catal. Rev. Sci. Eng. 35, 457 (1993).
2. M. Shelef and G. W. Graham, Catal. Rev. Sci. Eng. 36, 433 (1994).
3. J. A. Rodriguez and D. W. Goodman, Surf. Sci. Rep. 14, 1 (1991).
4. J. S. Foord and A. E. Reynolds, Surf. Sci. 164, 640 (1985).
5. J. A. Rodriguez, M. Kuhn, and J. Hrbek, Chem. Phys. Lett. 251, 13 (1996).
6. To be published.
7. G. A. Somorjai, Introduction to Surface Chemistry and Catalysis (Wiley, New York, 1994).
8. J. M. Dumas, C. Géron, H. Hadrane, P. Marécot, and J. Barbier, J. Mol. Catal. 77, 87 (1992).
9. J. K. A. Clarke, Chem. Rev. 75, 291 (1975).
10. J. A. Rodriguez, R. A. Campbell, and D. W. Goodman, J. Phys. Chem. 95, 2477 (1991).
11. X. Jiang and D. W. Goodman, Surf. Sci. 255, 1 (1991).
12. R. Wu, to be published.
13. J. A. Rodriguez, M. Kuhn, and J. Hrbek, J. Phys. Chem. 100, 3799 (1996).
14. (a) W. Heegemann, K. H. Meister, E. Betchhold, and K. Hayek, Surf. Sci. 49, 161 (1975)
15. (b) G.-Q. Xu and J. Hrbek, Catal. Lett. 2, 35 (1989).
16. M. Dupuis, S. Chin, and A. Marquez, in Relativistic and Electron Correlation Effects in Molecules and Clusters, edited by G. L. Malli, NATO ASI Series (Plenum, New York, 1992).
17. P. J. Hay and W. R. Wadt, J. Chem. Phys. 82, 270 (1985).
18. J. A. Rodriguez and M. Kuhn, J. Phys. Chem. B 101, 3187 (1997).
19. J. A. Rodriguez and M. Kuhn, J. Phys. Chem. 98, 11, 251 (1994).
20. J. L. Whitten and H. Yang, Surf. Sci. Rep. 24, 55 (1996).
21. (a) R. A. van Santen and M. Neurock, Catal. Rev. Sci. Eng. 37, 557 (1995)
22. (b) Quantum Chemistry Approaches to Chemisorption and Heterogeneous Catalysis, edited by F. Ruette (Kluwer, Dordrecht, 1992).
23. J. Hrbek, S. Y. Li, J. A. Rodriguez, D. G. van Campen, H. H. Huang, and G.-Q. Xu, Chem. Phys. Lett. 267, 65 (1997).
24. S. Y. Li, J. A. Rodriguez, J. Hrbek, H. H. Huang, and G.-Q. Xu, Surf. Sci. 366, 29 (1996).
25. D. R. Mullins, P. F. Lyman, and S. H. Overbury, Surf. Sci. 277, 64 (1992).
26. P. C. Wong, M. Y. Zhou, K. C. Hui, and K. A. R. Mitchell, Surf. Sci. 163, 172 (1985).
27. To curve-fit the S 2p spectra in Fig. 4, we followed the methodology described in Refs. 5 and 23.
28. C. Kittel, Introduction to Solid State Physics, 6th ed. (Wiley, New York, 1986), pp. 24 and 55.
29. S. Hengrasmee, P. R. Watson, D. C. Frost, and K. A. R. Mitchell, Surf. Sci. 87, L249 (1979); 92, 71 (1980).
30. S. Hengrasmee, P. R. Watson, D. C. Frost, and K. A. R. Mitchell, Surf. Sci. 87, L249 (1979); 92, 71 (1980).
31. (a) R. J. Butcher and E. Sinn, J. Am. Chem. Soc. 98, 2440 (1976)
32. (b) P. Colamarino and P. Orioli, J. Chem. Soc. Dalton Trans., 845 (1976)
33. (c) E. Parthe, D. Hohnke, and F. Hullinger, Acta Crystallogr. 23, 832 (1967)
34. (d) Comprehensive Coordination Chemistry, edited by G. Wilkinson, R. D. Willard, and J. A. McCleverty (Pergamon, New York, 1987), Chap. 16.
35. 2 bonds
36. (b) R. S. Mulliken, J. Chem. Phys. 23, 1841 (1955)
37. (c) A. Szabo and N. S. Ostlund, Modern Quantum Chemistry (McGraw-Hill, New York, 1989).
38. T. Moeller, Inorganic Chemistry (Wiley, New York, 1982), pp. 82-83.
39. (a) P. J. Feibelman and D. R. Hamann, Surf. Sci. 149, 48 (1985)
40. (b) P. J. Feibelman, Phys. Rev. B 43, 9452 (1991).
41. W. F. Egelhoff, Surf. Sci. Rep. 6, 253 (1987).
42. K. P. Huber and G. Herzberg, Molecular Spectra and Molecular Structure IV: Constants of Diatomic Molecules (Van Nostrand-Reinhold, New York, 1974).
43. J. A. Rodriguez, J. Phys. Chem. B 101, 7254 (1997).
44. J. A. Rodriguez, S. Chaturvedi, M. Kuhn, J. Van Ek, U. Diebold, P. S. Robert, H. Geisler, and C. A. Ventrice, J. Chem. Phys. 107, 9146 (1997).
45. S. Chaturvedi, J. A. Rodriguez, and J. Hrbek, J. Phys. Chem. B 101, 10860 (1997).
46. M. Kuhn and J. A. Rodriguez, J. Phys. Chem. 98, 12,059 (1994), and references therein.
47. To be published.
48. (a) J. E. Houston, C. H. F. Peden, D. S. Blair, and D. W. Goodman, Surf. Sci. 167, 427 (1986)
49. (b) G. Pötschke, J. Schröder, C. Günther, R. Q. Hwang, and R. J. Behm, Surf. Sci. 251/252, 592 (1991).
50. M. Tikhov and E. Bauer, Surf. Sci. 232, 73 (1990).
51. J. A. Rodriguez, Surf. Sci. Rep. 24, 223 (1996).
52. Lange's Handbook of Chemistry, 13th ed. (McGraw-Hill, New York, 1985), Table 9-1.
53. -1 and Cu desorption temperatures of 1080-1240 K (see Fig. 11)
54. (b) P. A. Redhead, Vacuum 12, 203 (1962).
55. H. Höchst, E. Colavita, and G. B. Fisher, J. Vac. Sci. Technol. A 3, 1554 (1985).
56. J. Emsley, The Elements (Oxford University Press, Oxford, 1989).
57. (a) Y. Jeon, J. Chen, and M. Croft, Phys. Rev. B 50, 6555 (1994)
58. (b) Y. Jeon, B. Qi, F. Lu, and M. Croft, Phys. Rev. B 40, 1538 (1989).
59. T. E. Fisher and S. R. Kelemen, J. Catal. 53, 24 (1978).
60. Y. Matsumoto, T. Onishi, and K. Tamara, J. Chem. Soc. Faraday Trans. I 76, 1116 (1980).
61. E. L. Hardegree and J. M. White, Surf. Sci. 175, 78 (1986).
62. M. Kiskinova, A. Szabo, and J. T. Yates, J. Chem. Phys. 89, 7599 (1988).
63. M. P. Kiskinova, Surf. Sci. Rep. 8, 359 (1988).
64. J. A. Rodriguez and M. Kuhn, J. Phys. Chem. 99, 9567 (1995).
65. (a) M. Kuhn and J. A. Rodriguez, J. Vac. Sci. Technol. A 13, 1569 (1995)
66. (b) M. Kuhn and J. A. Rodriguez, Catal. Lett. 32, 345 (1995).
67. C. H. Bartholomew, P. K. Agrawal, and J. R. Katzer, Adv. Catal. 31, 135 (1982).