Catalytic asymmetric hydrosilylation with (triazolinylidene)rhodium complexes containing an axis of chirality

Tetrahedron Asymmetry

Volumn 8, Issue 21, 1997, Pages 3571-3574

  Enders, D ^a   Gielen, H ^a   Breuer, K ^b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b BASF SE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; LIGAND; RHODIUM DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHIRALITY; COMPLEX FORMATION; PRIORITY JOURNAL; TEMPERATURE;

EID: 0031566718     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(97)00519-3     Document Type: Article

References (18)

1. 1. For a recent review of carbene chemistry, see Regitz, M. Angew. Chem. 1996, 108, 791; Angew, Chem. Int. Ed. Engl. 1996, 35, 725.
2. 1. For a recent review of carbene chemistry, see Regitz, M. Angew. Chem. 1996, 108, 791; Angew, Chem. Int. Ed. Engl. 1996, 35, 725.
3. 2. (a) Coleman, A. W.; Hitchcock, P. B.; Lappert, M. F.; Maskell, R. K.; Müller, J. H. J. Organomet. Chem. 1983, 250, C9;
4. (b) Coleman, A. W.; Hitchcock, P. B.; Lappert, M. F; Maskell, R. K.; Müller, J. H. ibid. 1985, 296, 173.
5. 3. (a) Herrmann, W. A.; Gooßen, L. J.; Köcher, C.; Artus, G. R. J. Angew. Chem. 1996, 108, 2980; Angew. Chem. Int. Ed. Engl. 1996, 35, 2805;
6. 3. (a) Herrmann, W. A.; Gooßen, L. J.; Köcher, C.; Artus, G. R. J. Angew. Chem. 1996, 108, 2980; Angew. Chem. Int. Ed. Engl. 1996, 35, 2805;
7. (b) Herrmann, W. A.; Gooßen, L. J.; Artus, G. R. J.; Köcher, C. Organometallics 1997, 16, 2472.
8. 4. (a) Enders, D.; Gielen, H.; Raabe, G.; Runsink, J.; Teles, J. H. Chem. Ber. 1996, 129, 1483;
9. (b) Enders, D.; Gielen, H.; Raabe, G.; Runsink, J.; Teles, J. H. Chem. Ber./Recueil 1997, 130, 1253.
10. 5. Lappert, M. F.; Maskell, R. K. J. Organomet. Chem. 1984, 264, 217.
11. 6. The new complexes 1-3 gave appropriate spectroscopic data (IR, NMR, MS, HR-MS).
12. 2O=2:1), the enantiomeric excess of the product alcohol was determined by gas chromatography (LIPODEX E, CP-CHIRASIL-DEX CB, 7-CD PERME).
13. 8. Brunner, H.; Brandl, P. J. Organomet. Chem. 1990, 390, C81.
14. 9. (a) Buschmann, H.; Scharf, H.-D.; Hoffmann, N.; Esser, P. Angew. Chem. 1991, 103, 480; Angew. Chem. Int. Ed. Engl. 1991, 30, 477;
15. 9. (a) Buschmann, H.; Scharf, H.-D.; Hoffmann, N.; Esser, P. Angew. Chem. 1991, 103, 480; Angew. Chem. Int. Ed. Engl. 1991, 30, 477;
16. (b) Gypser, A.; Norrby, P.-O. J. Chem. Soc., Perkin Trans. 2 1997, 939.
17. 10. (a) Haag, D. PhD thesis, RWTH Aachen, 1997;
18. (b) Haag, D.; Runsink, J.; Scharf, H.-D. Organometallics 1997, in press.