Asymmetric epoxidation of allylic alcohols using vanadium complexes of (N)-hydroxy-[2.2]paracyclophane-4-carboxylic Amides

Synlett

Volumn , Issue 6, 2000, Pages 899-901

  Bolm, Carsten ^a   Kühn, Toralf ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

2.2 paracyclophane; Asymmetric catalysis; Epoxidation; Hydroxamic acids; Vanadium

Indexed keywords

ALCOHOL DERIVATIVE; AMIDE; PARACYCLOPHANE DERIVATIVE; VANADIUM;

ALCOHOL OXIDATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; EPOXIDATION; LIGAND BINDING; ORGANIC CHEMISTRY;

EID: 0038624539     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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34. 4, filtered and concentrated under reduced pressure. The residue was purified by column chromatography (silica, petroleum ether : MTBE = 1: 1) furnishing 2,3-epoxy alcohol 7 (103 mg, 85%) as colorless oil.
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