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20544462793
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A semiquantitative calculation for a similar phase transition in a mixed monolayer of SDS and dodecanol predicted that the phase transition would take place over a period of about 1 h (ref 5).
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-1 to obtain a vibrational spectrum of the fully deuterated component only. We did not acquire spectra in the C-D stretching region in this study because the signal-to-noise ratio is poorer than in the C-H region. Previous work showed excellent agreement between data from the two frequency regions (ref 22).
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43
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20544468920
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3 (within the Lorentz model), where e is the relative permittivity of the monolayer. For typical values of ∈, a 10% change in e would change the line strength by only 5%.
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44
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20544473045
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There is some evidence from theoretical calculations (ref 45) that the anisotropy in the Raman tensor, and hence in the hyperpolarizability tensor, is a nonlocal property of the methyl group and that consequently β may depend on the conformation of the hydrocarbon chain. A comparison of calculated values of the Raman tensor for trans- and gauche-butane suggests that the effect of conformation on β is likely to be at the percent level and can be safely neglected in the analysis here.
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