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Our results suggest that reverse phase HPLC would be most effective at removing dodecanol from commercial SDS if bulk concentrations well below the cmc were employed (∼1 mM). As the purity of the SDS increases, higher concentrations should be used.
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44
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5844343459
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The analogous monolayer of dodecanol at the air-water interface exhibits sharp Bragg peaks, indicative of quasi-long-range translational order, and hexagonally packed chains oriented perpendicular to the interface (ref 28).
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Monolayers of medium-chain alcohols adopt rotator phases rather than crystalline structures with herringbone packing (ref 28).
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55
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It should be noted that the sum-frequency measurements were made at a temperature 5 K lower than the neutron reflection measurements. If a phase transition were to occur between these two temperatures, significant changes in density and composition might be observed (see ref 36).
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