-
1
-
-
85087252988
-
-
m and is normally determined from the Gibbs equation. The efficiency of adsorption is widely quoted as the concentration of surfactant required to reduce the surface tension by 20 mN/m
-
m and is normally determined from the Gibbs equation. The efficiency of adsorption is widely quoted as the concentration of surfactant required to reduce the surface tension by 20 mN/m.
-
-
-
-
2
-
-
0041782853
-
-
For example, see: Gillap, W. R.; Weiner, N. D.; Gibaldi, M. J. Phys. Chem. 1968, 72, 2218. Nearn, M. R.; Spaull, A. J. B. Trans. Faraday Soc. 1969, 65, 1785.
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(1968)
J. Phys. Chem.
, vol.72
, pp. 2218
-
-
Gillap, W.R.1
Weiner, N.D.2
Gibaldi, M.3
-
3
-
-
0014538327
-
-
For example, see: Gillap, W. R.; Weiner, N. D.; Gibaldi, M. J. Phys. Chem. 1968, 72, 2218. Nearn, M. R.; Spaull, A. J. B. Trans. Faraday Soc. 1969, 65, 1785.
-
(1969)
Trans. Faraday Soc.
, vol.65
, pp. 1785
-
-
Nearn, M.R.1
Spaull, A.J.B.2
-
5
-
-
11644252617
-
-
note
-
The structure of the monolayer is not the sole determinant of interfacial properties. From a thermodynamic perspective, it is often useful to consider the surface tension and other surface thermodynamic parameters as properties of the whole system, not just of the interface. Many applications of surfactants also involve nonequilibrium conditions where mass transport to the interface plays an important role.
-
-
-
-
6
-
-
0029274983
-
-
Lyttle, D. J.; Lu, J. R.; Su, T. J.; Thomas, R. K.; Penfold, J. Langmuir 1995, 11, 1001.
-
(1995)
Langmuir
, vol.11
, pp. 1001
-
-
Lyttle, D.J.1
Lu, J.R.2
Su, T.J.3
Thomas, R.K.4
Penfold, J.5
-
7
-
-
33751156983
-
-
Lu, J. R.; Li, Z. X.; Smallwood, J.; Thomas, R. K.; Penfold, J. J. Phys. Chem. 1995, 99, 8233.
-
(1995)
J. Phys. Chem.
, vol.99
, pp. 8233
-
-
Lu, J.R.1
Li, Z.X.2
Smallwood, J.3
Thomas, R.K.4
Penfold, J.5
-
8
-
-
33751392409
-
-
Simister, E. A.; Thomas, R. K.; Penfold, J.; Aveyard, R.; Binks, B. P.; Cooper, P.; Fletcher, P. D. I.; Lu, J. R.; Sokolowski, A. J. Phys. Chem. 1992, 96, 1383. Lu, J. R.; Simister, E. A.; Thomas, R. K.; Penfold, J. J. Phys. Chem. 1993, 97, 6024.
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(1992)
J. Phys. Chem.
, vol.96
, pp. 1383
-
-
Simister, E.A.1
Thomas, R.K.2
Penfold, J.3
Aveyard, R.4
Binks, B.P.5
Cooper, P.6
Fletcher, P.D.I.7
Lu, J.R.8
Sokolowski, A.9
-
9
-
-
33751386396
-
-
Simister, E. A.; Thomas, R. K.; Penfold, J.; Aveyard, R.; Binks, B. P.; Cooper, P.; Fletcher, P. D. I.; Lu, J. R.; Sokolowski, A. J. Phys. Chem. 1992, 96, 1383. Lu, J. R.; Simister, E. A.; Thomas, R. K.; Penfold, J. J. Phys. Chem. 1993, 97, 6024.
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(1993)
J. Phys. Chem.
, vol.97
, pp. 6024
-
-
Lu, J.R.1
Simister, E.A.2
Thomas, R.K.3
Penfold, J.4
-
11
-
-
33751295177
-
-
Bell, G. R.; Bain, C. D.; Ward, R. N. J. Chem. Soc. Faraday Trans. 1996, 92, 515.
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(1996)
J. Chem. Soc. Faraday Trans.
, vol.92
, pp. 515
-
-
Bell, G.R.1
Bain, C.D.2
Ward, R.N.3
-
12
-
-
0026203287
-
-
Bain, C. D.; Davies, P. B.; Ong, T. H.; Ward, R. N.; Brown, M. A. Langmuir 1991, 7, 1563.
-
(1991)
Langmuir
, vol.7
, pp. 1563
-
-
Bain, C.D.1
Davies, P.B.2
Ong, T.H.3
Ward, R.N.4
Brown, M.A.5
-
14
-
-
6744248168
-
-
Shen, Y. R. Nature (London) 1989, 337, 519. Eisenthal, K. B. Annu. Rev. Phys. Chem. 1992, 43, 627.
-
(1989)
Nature (London)
, vol.337
, pp. 519
-
-
Shen, Y.R.1
-
16
-
-
33751157400
-
-
and references therein
-
Ward, R. N.; Duffy, D. C.; Davies, P. B.; Bain, C. D. J. Phys. Chem. 1994, 98, 8536 and references therein.
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 8536
-
-
Ward, R.N.1
Duffy, D.C.2
Davies, P.B.3
Bain, C.D.4
-
17
-
-
85087252437
-
-
note
-
-1 in the longer chains is experimentally significant. This peak appears at a frequency characteristic of the antisymmetric methylene stretch, but the specific conformation that gives rise to it is not known.
-
-
-
-
18
-
-
11644312880
-
-
note
-
+ mode of <5% falls within the limits of error engendered by uncertainty in A.
-
-
-
-
19
-
-
0011588299
-
-
Renault, A.; LeGrand, J. F.; Goldmann, M.; Berge, B. J. Phys. II (France) 1993, 3, 761.
-
(1993)
J. Phys. II (France)
, vol.3
, pp. 761
-
-
Renault, A.1
LeGrand, J.F.2
Goldmann, M.3
Berge, B.4
-
20
-
-
11644270209
-
-
note
-
In this calculation, we used the full expression for 〈βyyz〉 and line strengths obtained from a computer fit to the whole sum-frequency spectrum, but excluded local field effects (see ref 9).
-
-
-
-
21
-
-
0001132732
-
-
Braun, R.; Casson, B. D.; Bain, C. D. Chem. Phys. Lett. 1995, 245, 326.
-
(1995)
Chem. Phys. Lett.
, vol.245
, pp. 326
-
-
Braun, R.1
Casson, B.D.2
Bain, C.D.3
-
23
-
-
0001210554
-
-
Böcker, J.; Schlenkrich, M.; Bopp, P.; Brickmann, J. J. Phys. Chem. 1992, 96, 9915.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 9915
-
-
Böcker, J.1
Schlenkrich, M.2
Bopp, P.3
Brickmann, J.4
-
25
-
-
85087252710
-
-
note
-
-5 to correct for the effect of the NaBr on the relative permittivity of the subphase. This correction factor was calculated on the assumption that ∈ = 2.0 for the monolayer, but is insensitive to the exact value chosen for ∈. The effect of the temperature dependence of the relative permittivity of water is negligible and has been ignored.
-
-
-
-
27
-
-
11644311540
-
-
note
-
All-trans chains are significantly anisotropic. Conformational disorder will, however, reduce the anisotropy of the chains. Furthermore, a monolayer composed of chains tilted at the magic angle (55°) will be optically isotropic, even though the chains themselves are anisotropic, if the direction of the tilt is random. The mean tilt in these monolayers is close to the magic angle and so any anisotropy will be small.
-
-
-
-
29
-
-
85087251931
-
-
note
-
-3.
-
-
-
-
31
-
-
85087251814
-
-
note
-
18TAB.
-
-
-
-
32
-
-
85087251976
-
-
note
-
2) of a deuterated fragment whose intrinsic thickness is negligible compared to w.
-
-
-
-
33
-
-
4043049343
-
-
Lu, J. R.; Li, Z. X.; Thomas, R. K.; Penfold, J. J. Chem. Soc., Faraday Trans. 1996, 92, 403.
-
(1996)
J. Chem. Soc., Faraday Trans.
, vol.92
, pp. 403
-
-
Lu, J.R.1
Li, Z.X.2
Thomas, R.K.3
Penfold, J.4
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