Structural characterization of M(s-aVii4-C4H6)(Me4C5SiMe2NR) M = Ti or Zr, R = CMe3 or CHCMe(l-C10H7)

Journal of the Chemical Society, Dalton Transactions

Volumn , Issue 12, 2000, Pages 1881-1886

  Dahlmann, Marc ^a   Schottek, Jörg ^b   Fröhlich, Roland ^a   Kunz, Doris ^b   Nissinen, Maija ^a   Erker, Gerhard ^b   Fink, Gerhard ^a   Kleinschmidt, Ralph ^b  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000649231     PISSN: 1470479X     EISSN: None     Source Type: Journal    
DOI: 10.1039/b000570n     Document Type: Article

References (77)

1. G. Erker, J. Wicher, K. Engel, F. Rosenfeldt, W. Dietrich and C. Krüger, J. Am. Cliem. Soc., 1980,102, 6344.
2. Reviews: H. Yasuda, K. Tatsumi and A. Nakamura, Ace. Client. Res., 1985, 18, 120;
3. G. Erker, C. Krüger and G. Müller, Adr. Organomei. Clicm., 1985, 2-1, 1;
4. H. Yasuda and A. Nakamura, Ange\v. Chcm., 1987,99, 745
5. ; Angew. Client., Int. Ed Engl., 1987,26, 723.
6. G. Erker, J. Wicher, K. Engel and C. Krüger, Chew. Ber., 1982,115, 3300;
7. G. Erker, K. Engel, C. Krüger and A.-P. Chianc, Client. Ber, 1982, 115, 3311;
8. H. Yasuda, Y. Kajihara, K. Mashima, K. Nagasuna, K. Lee and A. Nakamura, Organoineiallics, 1982,1,388;
9. Y. Kai, N. Kanehisa, K. Miki, N. Kasai, K. Mashima, K. Nagasuna, H. Yasuda and A. Nakamura, J. Client. Soc., Client. Commun., 1982, 191;
10. T. Okamoto, N. Kanehisa, A. Nakamura, H. Yasuda, Y. Kai and N. Kasai, J. Am. Client. Soc., 1988, 110, 5008;
11. see also: H.C. Strauch, G. Erker and R. Fröhlich, Organometallics, 199S, 17, 5746 and references cited therein.
12. Reviews: H. Sinn and W. Kaminsky, Adv. Organoniet. Client., 1980, 18, 99;
13. R.F. Jordan, Adv. Organoniet. Chem., 1991, 32, 325; T. J. Marks, Ace. Chem. Res., 1992, 25, 57;
14. M. Aulbach and F. Küber, Client. Unserer Zeit, 1994, 28, 197;
15. H.-H. Brintzinger, D. Fischer, R. Mülhaupt, B. Rieger and R. Waymouth, Angeu: Chem., 1995, 107, 1255;
16. Ange\r. Chem., Int. Ed. Eng!., 1995, 34, 1143;
17. M. Bochmann, J. Client. Soc., Dalton Trans., 1996,255.
18. B. Temme, G. Erker, J. Karl, H. Luftmann, R. Fröhlich and S. Kotila, Angeu: Chem., 1995, 107, 1867;
19. Angew. Chcm., Int. Ed. Engl., 1995,3-1,1755;
20. B. Temme, J. Karl and G. Erker, Client. Eur.J., 1996. 2, 919;
21. J. Karl, G. Erker and R. Fröhlich, J. Am. Chem. Soc., 1997. 119, 11165;
22. G.J. Pindado, M. Thornton-Pett, M. Bowkamp, A. Meetsma, B. Hessen and M. Bochmann, Ange\\: Chem., 1997, 109, 2457
23. ; Angew. Chem., Int. Ed. Engl., 1997, 36, 2358;
24. J. Karl, G. Erker and R. Fröhlich, J. Organoniet. Chem., 1997, 535, 59;
25. J. Karl and G. Erker, Client. Ber.lRecueil, 1997, 130, 1261; J. Karl, M. Dahlmann, G. Erker and K. Bergander, J. Am. Chem. Soc., 1998, 120, 5643;
26. M. Dahlmann, G. Erker, M. Nissinen and R. Fröhlich, J. Am. Chem. Soc., 1999, 121, 2820.
27. (a) P.J. Shapiro, W. D. Cotter, W. P. Schaefer, J. A. Labinger and J. E. Bercaw, J. Am. Chem. Soc., 1994, 116, 4623;
28. W.E. Piers, P. J. Shapiro, E. E. Bunel and J. E. Bercaw, Synletl, 1990, 2, 74;
29. E.E. Bunel, B. J. Burger and J. E. Bercaw, J. Am. Chem. Soc., 1988, 110, 976;
30. P.J. Shapiro, E. E. Bunel, W. P. Schaefer and J. E. Bercaw, Organometallics, 1990, 9, 867;
31. (b) J.C. Stevens, F. J. Timmers, D. R. Wilson, G. F. Schmidt, P. N. Nickias, R. K. Rosen, G. W. Knight and S. Lai, Eur. Pal. Appl., EP 416815-A2, 1991 (Dow Chemical Co.);
32. J.M. Canich, Eur. Pat. Appl., EP 420436Al, 1991 (Exxon Chemical Co.); J. M. Canich, G. G. Hlatky and H. W. Turner, PCTAppl., WO 92-00333, 1992.
33. Review: A.L. McKnieht and R. M. Waymouth, Client. Rev., 1998, 98,2587.
34. For C,-bridged analogues see e.g.: L. Duda, G. Erker, R. Fröhlich and F. Zippel, Eur.J. Inorg. Chem., 1998, 1153; A. Bertuleit, M. Könemann, L. Duda, G. Erker and R. Fröhlich, Top. Calai, 1999,7, 37.
35. D.D. Dévore, F. J. Timmers, D. L. Hasha, R. K. Rosen, T. J. Marks, P. A. Deck and C. L. Stern, Organometallics, 1995, 14, 3132.
36. M. Dahlmann, Doctoral Dissertation, Universität Münster, 1999.
37. H.E.Ramsden, US Pat., 3388179, 1968;
38. Y.Nakano, K.Natsukawa, H. Yasuda and H. Tani, Tetrahedron Lett., 1972, 2833;
39. K. Fujita, Y. Ohnuma, H. Yasuda and H. Tani, J. Organomet. Chem., 1976, 113, 201;
40. H. Yasuda, Y. Nakano, K. Natsukawa and H. Tani, Afacromoleciiles, 1978, 11, 586;
41. Y. Kai, N. Kanehisa, K. Miki, N. Kasai, K. Mashima, H. Yasuda and A. Nakamura, Client. Lett., 1982, 1277.
42. See also: S. Datta, S.S. Wreford, R. P. Beatty and T. J. McNeese, J. Am. Chem. Soc., 1979,101,1053;
43. S.S. Wreford and J. F. Whitney, Inorg. Chem., 1981, 20, 3918.
44. P. Czisch, G. Erker, H.-G. Korth and R. Sustmann, Organometallics, 1984, 3, 945;
45. R. Beckhaus and K.-H. Thiele, J. Organomet. Chem., 1986, 317, 23;
46. U. Böhme, K.-H. Thiele and A. Rufinska, Z. Anorg. Allg. Chem., 1994, 620, 1455.
47. For "prone" and "supine" definition see: H. Yasuda, K. Tatsumi, T. Okamoto, K. Mashima, K. Lee, A. Nakamura, Y. Kai, N. Kanehisa and N. Kasai, J. Am. Chem. Soc., 1985,107,2410.
48. anii, definition see: E.G. Hoffmann, R. Kallweit, G. Schroth, K. Seevogel, W. Stempfle and G. Wilke, J. Organomet. Chem., 1975,97, 183.
49. The complex Zr[n.5Me,C5SiMe?NCHMe(l-C10H7)]Cl2 7 was synthesized for the first time following the general route described in réf. 6(b) using l-naphthylethylamine as reagent to form the amido ligand.
50. D.J. Cardin, M. F. Läppert and C. L. Raston, in Chemistry of Organo-Zirconium and -Hafnium Compounds, Wiley, New York, 1986; Comprehensive Organometallic Chemistry, eds. E. W. Abel, F. G. A. Stone and G. Wilkinson, Pergamon, Oxford, 1995, vol. 4.
51. G. Erker, K. Encel, C. Krüeer and G. Müller, Organometallics, 1984,3, 128; C. Krüger, G. Müller, G. Erker, U. Dorf and K. Engel, Organometallics, 1985, 4, 215; G. Erker, T. Mühlenbernd, R. Bcnn,
52. A. Rufinska, Y.-H. Tsay and C. Krüger, Angew. Client., 1985, 97, 336; Angew. Client., Int. Ed. Engl, 1985,24, 321.
53. For related mono-Cp or Cp-free butadiene Group 4 metal complexes see e.g.: Zr, B. Hessen and J.H. Teuben, J. Organomet. Client., 1988,358,135;
54. Y. Wielstra, A. Meetsma and S. Gambarotta, Organometallics, 1989, 8, 258;
55. Y. Wielstra, S. Gambarotta and A.L. Spek, Organometallics, 1990, 9, 572;
56. M.D. Fryzuk, T. S. Haddad and S. J. Rettig, Organometallics, 1989, 8, 1723;
57. G.M. Diamond, M. L. H. Green, N. M. Walker, J. A. K. Howard and S. A. Mason, J. Client. Soc., Dalton Trans., 1992, 2641;
58. L. Giannini, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Angew. Client., 1994, 106, 2279;
59. Angew. Client., Int. Ed. Engl, 1994, 33, 2204;
60. A. Caselli, L. Giannini, E. Solari, C. Floriani, N. Re, A. Chiesi-Villa and C. Rizzoli, Organometallics, 1997, 16, 5457;
61. Ti, M. Mena, P. Royo, R. Serrano, M.A. Pellinghelli and A. Tiripicchio, Organometallics, 1988, 7, 258;
62. Organometallics, 1989, 8, 476;
63. H. Yamamoto, H. Yasuda, K. Tatsumi, K. Lee, A. Nakamura, J. Chen, Y. Kai and N. Kasai, Organometallics, 1989, 8, 105;
64. F.G. N. Cloke and A. McCamley, J. Client. Soc., Client. Commun., 1991, 1470;
65. G.J. Balaich, J. E. Hill, S. A. Waratuke, P. E. Fanwick and I. P. Rothwell, Organometallics, 1995, 14, 656;
66. M.D. Spencer, S. R. Wilson and G. S. Girolami, Organometallics, 1997,16, 3055.
67. T. Bürgi, H. Berke, D. Wingbermühle, C. Psiorz, R. Noe, T. Fox, M. Knickmeier, M. Berlekamp, R. Fröhlich and G. Erker, J. Organomet. Client., 1995,497, 149.
68. G. Erker, K. Berg, C. Krüger, G. Müller, K. Angermund, R. Benn and G. Schroth, Angew. Giern., 1984, 96, 445; Angew. Chem., Int. Ed. Eng!., 1984,23,455.
69. J.W. Lauher and R. Hoffmann, J. Am. Chem. Soc, 1976, 98, 1729; J. C. Green, Chem. Soc. Rev., 1998, 27, 263.
70. T.K. Woo, P. M. Margl, J. C. W. Lohrenz, P. E. Blöchl and T. Ziegler, J. Am. Chem. Soc., 1996, 118, 13021;
71. T.K. Woo, L. Fan and T. Ziegler, Organometallics, 1994, 13, 2252;
72. L. Fan, D. Harrison, T.K. Woo and T. Ziegler, Organomelallics, 1995, 14, 2018;
73. T.K. Woo, P. M. Margl, T. Ziegler and P. E. Blöchl, Organometallics, 1997,16, 3454.
74. S. Braun, H.-O. Kalinowski and S. Berger, in 150 and More Basic N MR Experiments, VCH, Weinheim, 1998 and references cited therein.
75. EXPRESS, Nonius B.V., Delft, 1994; MOLEN, K. Fair, Enraf Nonius B.V., Delft, 1990;
76. SHELXS 97, G.M. Sheldrick, Ada Cryslallogr., 1990, 46, 467;
77. SHELXL 97, Universität Göttingen, 1997, SCHAKAL, E. Keller, Universität Freiburg, 1997.