(2-(Dimethylamino)indenyl)zirconium dichlorides

Organometallics

Volumn 15, Issue 13, 1996, Pages 3092-3094

  Luttikhedde, Hendrik J G ^a   Leino, Reko P ^a   Wilén, Cari Eric ^a   Näsman, Jan H ^a   Ahlgrén, Markku J ^b   Pakkanen, Tapani A ^b  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b UNIVERSITY OF EASTERN FINLAND   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001241126     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960086y     Document Type: Article

References (24)

1. For a recent review, see: Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
2. (a) Spaleck, W.; Antberg, M.; Rohrmann, J.; Winter, A.; Bachmann, B.; Kiprof, P.; Behm, J.; Herrmann, W. A. Angew. Chem., Int. Ed. Engl. 1992, 31, 1347.
3. (b) Spaleck, W.; Küber, F.; Winter, A.; Rohrmann, J.; Bachmann, B.; Antberg, M.; Dolle, V.; Paulus, E. F. Organometallics 1994, 13, 954.
4. Kaminsky, W.; Rabe, O.; Schauwienold, A.-M.; Schupfner, G. U.; Hanss, J.; Kopf, J. J. Organomet. Chem. 1995, 497, 181.
5. Coates, G. W.; Waymouth, R. M. Science 1995, 267, 217.
6. Plenio, P.; Burth, D. Angew. Chem., Int. Ed. Engl. 1995, 34, 800.
7. Edlund, U. Acta Chem. Scand. 1973, 27, 4027.
8. Edlund, U. Chem. Scr. 1973, 7, 85.
9. Ce(1) and Ce(2) denote the centroids of the five-membered portions of the indene rings, with the lowest and highest crystallographic numbering, respectively.
10. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
11. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
12. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
13. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
14. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
15. For molecular structures of nonbridged group IV bis(indenyl) complexes, see ref 4 and: (a) O'Hare, D.; Murphy, V. M.; Diamond, G. M.; Arnold, P.; Mountford, P. Organometallics 1994, 13, 4689. (b) Krüger, C.; Lutz, F.; Nolte, M.; Erker, G.; Aulbach, M. J. Organomet. Chem. 1993, 452, 79. (c) Erker, G.; Aulbach, M.; Knickmeier, M.; Wingbermühle, D.; Krüger, C.; Nolte, N.; Werner, S. J. Am. Chem. Soc. 1993, 115, 4590. (d) Piccolrovazzi, N.; Pino, P.; Consiglio, G.; Sironi, A.; Moret, M. Organometallics 1990, 9, 3098. (e) Rausch, M. D.; Moriarty, K. J.; Atwood, J. L.; Hunter, W. E.; Samuel, E. J. Organomet. Chem. 1987, 327, 39. (f) Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757.
16. Lide, D. R., Jr. Tetrahedron 1962, 125.
17. Selected torsion angles (deg) for 3: C(121)-N(12)-C(12)-C(13) = -2.8(14), C(122)-N(12)-C(12)-C(11) = 7.8(13), C(221)-N(22)-C(22)-C(23) = -0.7(13), C(222)-N(22)-C(22)-C(21) = 9.9(13).
18. Stahl, K.-P.; Boche, G.; Massa, W. J. Organomet. Chem. 1984, 227, 113.
19. Piemontesi, F.; Camurati, I.; Resconi, L.; Balboni, D.; Sironi, A.; Moret, M.; Ziegler, R.; Piccolrovazzi, N. Organometallics 1995, 14, 1256 and references therein.
20. (a) Selected torsion angles (deg) for 4: C(121)-N(1)-C(12)-C(11) = 57.9(7), C(122)-N(1)-C(12)-C(13) = 8.6(7), C(222)-N(2)-C(22)-C(21) = 60.1(7), C(221)-N(2)-C(22)-C(23) = 8.1(8).
21. (b) In the solid state two interatomic hydrogen distances are shorter than the sum of their relevant van der Waals radii, (see Supporting Information).
22. Ewen, J. A.; Elder, M. J.; Jones, R. L.; Haspeslagh, L.; Atwood, J. L.; Bott, S. G.; Robinson, K. Makromol. Chem. Macromol. Symp. 1991, 48/49, 253.
23. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467.
24. Sheldrick, G. M. SHELX93: Program for the Refinement of Crystal Structures; University of Göttongen, Göttongen, Germany, 1993.