Detailed investigations of the pump-probe spectroscopy of the equilibrated solvated electron in alcohols

Journal of Physical Chemistry A

Volumn 102, Issue 28, 1998, Pages 5701-5707

  Silva, Carlos ^a   Walhout, Peter K ^a,b   Reid, Philip J ^a,c   Barbara, Paul F ^a  

^a University of Minnesota ^*  (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

^c UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000373714     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp980861i     Document Type: Article

References (55)

1. Alfano, J. C.; Walhout, P. K.; Kimura, Y.; Barbara, P. F. J. Chem. Phys. 1993, 98, 5996.
2. Kimura, Y.; Alfano, J. C.; Walhout, P. K.; Barbara, P. F. J. Phys. Chem. 1994, 98, 3450.
3. Walhout, P. K.; Alfano, J. C.; Kimura, Y.; Silva, C.; Reid, P. J.; Barbara, P. F. Chem. Phys. Lett. 1995, 232, 135.
4. Silva, C.; Walhout, P. K.; Yokoyama, K.; Barbara, P. F. Phys. Rev. Lett. 1998, 80, 1086.
5. Yokoyama, K.; Silva, C.; Son, D.; Walhout, P. K.; Barbara, P. F. J. Phys. Chem. A, submitted.
6. Schwartz, B. J.; Rossky. P. J. J. Chem. Phys. 1994, 101, 6902.
7. Schwartz, B. J.; Rossky, P. J. J. Chem. Phys. 1994, 101, 6917.
8. Schwartz, B. J.; Rossky, P. J. J. Chem. Phys. 1996, 105, 6997.
9. Schwartz, B. J.; Bittner, E. R.; Prezhdo, O. V.; Rossky, P. J. J. Chem. Phys. 1996, 104, 5942.
10. Prezhdo, O. V.; Rossky, P. J. J. Chem. Phys. 1997, 107, 5863.
11. Turi, L.; Mosyak, A.; Rossky, P. J. J. Chem. Phys. 1997, 107, 1970.
12. Bratos, S.; Leicknam, J.-C. Chem. Phys. Lett. 1996, 261, 117.
13. Bratos, S.; Leicknam, J.-C.; Borgis, D.; Staib, A. Phys. Rev. E 1997, 55, 7217.
14. Staib, A.; Borgis, D. J. Chem. Phys. 1995, 103, 2642.
15. Barnett, R. B.; Landman, U.; Nitzan, A. J. Chem. Phys. 1989, 90, 4413.
16. Neria, E.; Nitzan, A. J. Chem. Phys. 1993, 99, 1109.
17. Graf, P.; Nitzan, A.; Diercksen, G. H. F. J. Phys. Chem. 1996, 100, 18916.
18. Rips, I. Chem. Phys. Lett. 1995, 245, 79.
19. Sander, M.; Brummund, U.; Luther, K.; Troe, J. Ber. Bunsen-Ges. Phys. Chem. 1992, 96, 1486.
20. Sander, M. U.; Luther, K.; Troe, J. J. Phys. Chem. 1993, 97, 11489.
21. Reuther, A.; Laubereau, A.; Nikogosyan, D. N. J. Phys. Chem. 1996, 100, 16794.
22. Crowell, R. A.; Bartels, D. M. J. Phys. Chem. 1996, 100, 17940.
23. Shi, X.; Long, F. H.; Lu, H.; Eisenthal, K. B. J. Phys. Chem. 1995, 99, 6917.
24. Shi, X.; Long, F. H.; Lu, H.; Eisenthal, K. B. J. Phys. Chem. 1996, 100, 11903.
25. Migus, A.; Gauduel, Y.; Martin, J. L.; Antonetti, A. Phys. Rev. Lett. 1987, 58, 1559.
26. Mcgowen, J. L.; Ajo, H. M.; Zhang, J. Z.; Schwartz, B. J. Chem. Phys. Lett. 1994, 237, 504.
27. Pépin, C.; Goulet, T.; Houde, D.; Jay-Germ, J.-P. J. Phys. Chem. 1994, 98, 7009.
28. Pépin, C.; Goulet, T.; Houde, D.; Jay-Gerin, J. P. J. Phys. Chem. A 1997, 101, 4351.
29. Turi, L.; Holpar, P.; Keszei, E.; Pépin, C.; Houde, D. J. Phys. Chem. A 1997, 101, 5469.
30. Tuttle, T. R.; Golden, S. J. Phys. Chem. 1991, 95, 5725.
31. Spirk, M.; Impey, R. W.; Klein, M. L. J. Stat. Phys. 1986, 43, 967.
32. Schnitker, J.; Motakabbir, K.; Rossky, P. J.; Friesner, R. Phys. Rev. Lett. 1988, 60, 456.
33. Wallqvist, A.; Martyna, G.; Berne, B. J. J. Phys. Chem. 1988, 92, 1721.
34. Romero, C.; Jonah, C. D. J. Chem. Phys. 1989, 90, 1877.
35. Long, F. H.; Lu, H.; Eisenthal, K. B. Phys. Rev. Lett. 1990, 64, 1469.
36. Webster, F. J.; Schnitker, J.; Friedrichs, M. S.; Friesner, R. A.; Rossky, P. J. Phys. Rev. Lett. 1991, 66, 3172.
37. Murphrey, T. H.; Rossky, P. J. J. Chem. Phys. 1993, 99, 515.
38. Del Buono, G. S.; Rossky, P. J.; Murphrey, T. H. J. Phys. Chem. 1992, 96, 7761.
39. Goulet, T. Private communication.
40. Kliner, D. A. V.; Alfano, J. C.; Barbara, P. F. J. Chem. Phys. 1993, 98, 5375.
41. Walhout, P. K.; Alfano, J. C.; Thakur, K. A. M.; Barbara, P. F. J. Phys. Chem. 1995, 99, 7568.
42. Shida, T.; Imamura, M. J. Phys. Chem. 1974, 78, 232.
43. Bromberg, A.; Thomas, J. K. J. Chem. Phys. 1975, 63, 2124.
44. Kenney-Wallace, G. A.; Hall, G. E.; Hunt, L. A.; Sarantidis, K. J. Phys. Chem. 1980, 84, 1145.
45. The photodynamical model consists of first-order kinetic processes representing excitation of a fraction of the initial s-state population to a p state by a Gaussian optical pulse (standard deviation = 100 fs), absorption of the p state, and radiationless decay from the p state with a 1 ps lifetime. Stimulated emission is neglected, since it is not expected to participate in the >300 fs dynamics in this wavelength range (see ref 6). After the time-dependent populations are calculated, the total change in optical density at the probe wavelength is determined and the results are convoluted with a Gaussian probe pulse. Spatial integration along the pump beam profile does not significantly change the results due to the relative pump and probe spot sizes.
46. Fowles, P. Trans. Faraday Soc. 1971, 67, 428.
47. Matsumura, H.; Mafuné, F.; Kondow, T. J. Phys. Chem. 1995, 99, 5861.
48. Farhataziz; Kalachandra, S. IEEE Trans. Nucl. Sci. 1983, NS-30, 1645.
49. Indeed, previously published data on the solvated electron in alcohols (see ref 3) may be in the moderate excitation regime and are presumably partly contaminated by two-photon effects.
50. Horng, M. L.; Gardecki, J. A.; Papazyan, A.; Maroncelli, M. J. Phys. Chem. 1995, 99, 17311.
51. Jonah, C. D.; Bartels, D. M.; Chernovitz, A. C. Radiat. Phys. Chem. 1989, 34, 145.
52. Wolff, R. K.; Bronskill, M. J.; Aldrich, J. E.; Hunt, J. W. J. Phys. Chem. 1973, 77, 1350.
53. Lam, K. Y.; Hunt, J. W. Int. J. Radiat. Phys. Chem. 1975, 7, 317.
54. Razem, D.; Hamill, W. H.; Funabashi, K. Chem. Phys. Lett. 1978, 53, 84.
55. Lewis, M. A.; Jonah, C. D. J. Phys. Chem. 1986, 90, 5367.