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1542411879
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note
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Abbreviations: Tetraphenylporphyrin (TPP); 5-(4-pyridyl)-10,15,20-triphenylporphyrin (MPyP); 5,10-bis(4-pyridyl)-15,20-diphenylporphyrin (cis-DPyP); 5,15-bis(4-pyridyl)-10,20-diphenylporphyrin (trans-DPyP); 5,10,15-tris(4-pyridyl)-20-phenylporphyrin (TrPyP) and 5,10,15,20-tetra(4-pyridyl)porphyrin (TPyP).
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72
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1542411882
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note
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3 solution of comparable concentration (sharp doublet at 3.49 ppm and quartet at 0.94 ppm). This is ascribable to the very labile binding of methanol to Zn, which brings the molecule inside the anisotropic shielding cone of the porphyrin.
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