Reactivity of the heavier group-13 monochlorides [{CH(SiMe3)2}2AlCl], InCl, TlCl, and of the elements Ga and Hg towards the unsupported Ni-Ni bond of [{(Ti5-Cp)Ni(PEt3)}2] - A straightforward synthetic approach to the synthesis of mixed main-group/transition-metal clusters containing unsupported metal-metal

Chemische Berichte

Volumn 130, Issue 10, 1997, Pages 1433-1440

  Jörg, Bonds ^a   Schneider, J ^a   Denninger, Uwe ^b   Hagen, Jörg ^b   Krüger, Carl ^b   Bläser, Dieter ^c   Boese, Roland ^c  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^c BAYER AG   (Germany)

Author keywords

Group 13 monochlorides; Insertion reactions; Main group elements; Metal metal bonds; Nickel

Indexed keywords

EID: 0000279673     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19971301013     Document Type: Article

References (82)

1. [1a] w. A. Herrmann, Ange\i: Cltein. 1986, 98, 51;
2. Angeu: Client. Int. Ed. Engl. 1986, 25, 56.
3. [1b) K. H. Whitmire, J. Coord Cliein. 1988, 17, 95.
4. [1cl T. P. Fehlner, Comments. Inorg. Client 1988, 7, 307.
5. See e.g.
6. [2a] R. A. Fischer, A. Miehr, T. Metzger, E. Born, O Ambacher, H. Aneerer, R. Dimitrov, Client. Maler. 1996, 8 1356.
7. [2b] R. A. Fischer, A. Miehr, Client. Mater. 1996, S, 497.
8. See e.g.:
9. [3a] R. A. Fischer, J. Behm, T. Priermeier, W. Scherer, Angew. Chcm. 1993, 705, 776; Augen: Chem., Int. Ed. Engl. 1993, 32, 746.
10. [3b] R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 32, 778;
11. Angew. Chem., Int. Ed. Engl. 1993, 32, 748.
12. [3c] R. A. Fischer, C/iem. Unserer Zeit 1995, 29, 141
13. Y.-J. Chen, H. D. Kaesz, Y. K. Kim, H. J. Müller, R. S. Williams, Z. Xue, Appl. Phys. Lett. 1989, 55, 2760
14. [5a] D. w. Stephan, Coord Client. Rev. 1989, 95, 41.
15. [5b] S. Friedrich, H. Memmler, L. H. Gade, W.-S. Li, M. McPartlin, Augen: Chem. 1994, 706, 705;
16. Angew. Chem., Int. Ed. Engl. 1994, 33, 676.
17. [5c] S. Friedrich, L. H. Gade, I. J. Scowen, M. McPartlin, Augen: Chem. 1996, 108, 1440;
18. Angew. Chem., Int. Ed. Engl. 1996, 35, 1338.
19. [5d] S. Friedrich, L. H. Gade, I. S. Scowen, M. McPartlin, Organometallics 1995, 14, 5344.
20. [5e] D. Selent, R. Deckhaus, J. Pickart, Organometallics 1993, 12, 2857.
21. [5f] L. H. Gade, Angew. Chem. 1996, 705, 2226;
22. Angew. Chem., Int. Ed. Engl. 1996, 35, 2089
23. J. J. Schneider, J. Hasen, D. Bläser, C. Krüger, R. Boese, Angew. Chem. 1997, 709, 771;
24. Angew. Chem., Int. Ed. Engl. 1997, 36, 739
25. U. Denninger, J. J. Schneider, G. Wilke, R. Goddard, C. Krüger, Inorg. Chini. Acta 1993, 213, 129
26. X-ray structure investigations: Further details of the crystal structure investigations are available on request from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany, on quoting the depository numbers CSD-406453 and -59429, the names of the authors, and the journal citation
27. R. A. Fischer, J. Behm, E. Herdtweck, C. Kronseder, J. Organomet. Chem. 1992, 437, C29
28. J J. Weiss, T. Priermeier, R. A. Fischer, Inorg. Chem. 1996, 35, 71
29. [l1a] R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 75, 5746. For other complexes with Ni-In bonds see:
30. [11b] R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934.
31. [11c] J. Weiss, A. Frank, E. Herdtweck, S. Nlate, M. R. Mattner, R. A. Fischer, Chem. Ber. 1996, 729, 297.
32. [11d] F. Demartin, M. C. lapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536.
33. [l1e] R. A. Fischer, J. Behm, J. Organomet. Chem. 1991, 413, C10
34. [12a] Al: w uhlj z. Naturforsch. 1988, 43b, 1113.
35. [12b] Ga: J. C. Beamish, R. W. H. Small, Inorg. Chem. 1979, 75, 220;
36. R. W. H. Small, I. J. Worall, Acta Crystallogr. Sect. B 1982, 38, 250.
37. [12c] /In: Uhl, M. Layh, W. Hiller, J. Organomet. Chem. 1989, 368, 139
38. [13a] c Dohmeier, C. Robl, M. Tacke, H. G. Schnecke!, Angew. Chem. 1991, 103, 594;
39. Angew. Chem., Int. Ed. Engl. 1991, 30, 564.
40. [13b] S. Schulz, H. W. Roesky, H. J. Koch, G. M. Sheldrick, D. Stalke, A. Kühn, ibid. 1993, 705, 1828;
41. Angew. Chem., Int. Ed. Engl 1993, 32, 1729.
42. [13c] R. J. Wehmschulte, K. Ruhlandt-Senge, M. M. Olmstead, H. Hope, B. E. Sturgeon, P. P. Power, Inorg. Chem. 1993, 32, 2983. For a recent review on M-M bonded complexes of the behavier group 13 elements see:
43. [13d] W. Uhl, Angeu: Chem. 1993, 705, 1449;
44. Angew. Chem., Int. Ed Engl. 1993, 32, 1386.
45. [13e] C. Dohmeier, D. Loos, H. Schnöckel, Angew. Chem. 1996, 70S, 141;
46. Angew. Chem., Int. Ed. Engl. 1996, 35, 129
47. For the recent characterisation of inorganic complexes with T1-T1 bonding see: K. W. Hellmann, L. H. Gade, A. Steiner, D. Stalke, F. Möller, Angew. Chem. 1997, 709, 99;
48. Angew. Chem., Int. Ed. Engl. 1997, 36, 160 and réf. cited therein
49. E. Bartmann, B. Bogdanovic, N. Janke, S. Liao, K. Schlichte, B. Spliethoff, J. Treber, U. Westeppe, U. Wilzcok, Chem. Ber. 1990, 723, 1517
50. W. R. Robinson, D. P. Schussler, Inorg. Chem. 1973, 72, 848
51. J. C. Calabrese, L. M. Clarkson, T. B. Marder, N. C. Norman, N. J. Taylor, J. Chem. Soc., Dalton Trans. 1992, 3525
52. W. Kalbfus, J. Kiefer, K. E. Schwarzhans, Z. Natnrforsch. 1973, 28b, 503
53. D. J. Patmore, W. A. G. Graham, Inorg. Chem. 1966, 5, 1586
54. A. T. T. Hsieh, M. J. Mays, J. Organomet. Chem. 1970, 22, 29
55. H. J. Haupt, F. Neuman, J. Organomet. Chem. 1971, 33, C56
56. A. T. T. Hsieh, M. J. Mays, J. Chem. Soc., Dalton Trans. 1972, 516
57. H. J. Haupt, F. Neumann, J. Organomet. Chem. 1974, 74, 184
58. H. J. Haupt, F. Neumann, H. Freut, J. Organomet. Chem. 1975, 99, 439
59. H. Preut, H. J. Neuman, Chem. Ber. 1974, 707, 2860
60. R. B. King, Inorg. Chem. 1970, 9, 1936.
61. A. J. Conway, P. B. Hitchcock, J. D. Smith, J. Chew. Soc., Dal- ton Trans. 1975, 1945
62. J. Rajaram, J. A. Ibers, Inorg. Chem. 1973, 12, 313.
63. V. G. Albano, M. Cane, M. C. lapalucci, G. Longoni, M. Mo nari, J. Organomet. Chem. 1991, 407, C9.
64. R. M. Campbell, L. M. Clarkson, W. Clege, D. C. R. Hockless N. L. Pickett, N. C. Norman, Chem. Ber. 1992, 125, 55.
65. T. B. Marder, J. Client Soc., Dation Trans. 1991, 2229.
66. [32a] o j Ezomo, D. M. P. Mingos. I. D. Williams, J. Chem Soc.. Chem. Commun. 1987, 924.
67. [32b] K. H. Whitmire, J. M Cassidy, A. L. Cassidy, A. L. Rheingold, R. R. Ryan, Inorg Chem. 1988, 27, 1347.
68. B. Walther, H. Albert, A. Kolbe, J. Organomet. Chem. 1978 145, 285.
69. [34a] H Schnöckel, Z. Naturforsch. 1976, 31b, 1291.
70. [34b] H Schnöckel, J. Mol. Struct. 1978, 50, 275, 267.
71. [34cl M. Tacke H. Schnöckel, Inorg. Chem. 1989, 28, 2895.
72. [34d] M. Tacke H. Kreienkamp, L. Plaegenberg, H. Schnöckel, Z. Anorg. Allg Chem. 1991, 604, 35.
73. S. Al-Hashimi, J. D. Smith, J. Organomet. Chem. 1978, 153, 253.
74. J. J. Schneider, R. Goddard, C. Krüger, Z. Naturforsch. 1995 50b, 448.
75. [37a] Q Dohmeier, H. Krautscheid, H. Schnöckel, Angew. Cliem 1994, 706, 2570;
76. Angew. Cliem., Int. Ed. Engl. 1994, 33, 2482 A rather long Ni-Al distance is discussed as a Ni-Al interaction:
77. [37b] K. R. Pörschke, W. Kleimann, Y.-H. Tsay, C. Krüger G. Wilke, Cliem. Ber. 1990, 123, 1267.
78. G. B. Vickers, R. S. Matyas, J. Chem. Soc., Client. Commun 1972, 972.
79. L. N. Zakharov, Yu. T. Struchkov, S. N. Titova, V. T. Bychkov G. A. Domrachev, G. A. Razuvaev, Cryst. Struct. Commun 1980, 9, 549.
80. S. N. Titova, V. T. Bychkov, G. A. Domrachev, G. A. Razuvaev Yu. T. Struchkov, L. N. Zakharov, J. Organomet. Client. 1980 757, 167.
81. [41a] X. L. R. Fontaine, S. J. Higgins, C. R. Langrick, B. L Shaw, J. Chem. Soc., Dalton Trans. 1987, 777.
82. [41b] A. L. Balch, U. M. Olmsted, S. P. Rowley, Inorg. Client. 1988, 27, 2275.