The Reactivity of the Unbridged Co-Sn Bond in [(η5-C5H5)(η2-C 2H4)Co-Sn{CH[Si(CH3)3] 2}2] the First Organometallic Complexes with direct Co-Sn-Chalcogen Bonding (Chalcogen = Se, Te)

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 7, 1997, Pages 739-741

  Schneider, Jörg J ^a   Hagen, Jörg ^a   Bläser, Dieter ^a   Boese, Roland ^a   Krüger, Carl ^b  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

Clusters; Cobalt; Metal metal bonds; Tin

Indexed keywords

EID: 0030838877     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199707391     Document Type: Article

References (43)

1. a) D. W. Stephan, Coord. Chem. Rev. 1989, 95, 41;
2. b) S. Friedrich, H. Memmler, L. H. Gade, W.-S. Li, M. McPartlin, Angew. Chem. 1994, 106, 705; Angew. Chem. Int. Ed. Engl. 1994, 33, 676;
3. b) S. Friedrich, H. Memmler, L. H. Gade, W.-S. Li, M. McPartlin, Angew. Chem. 1994, 106, 705; Angew. Chem. Int. Ed. Engl. 1994, 33, 676;
4. c) S. Friedrich, L. H. Gade, I. J. Scowen, M. McPartlin, ibid. 1996, 108, 1440 bzw. 1996, 35, 1338;
5. c) S. Friedrich, L. H. Gade, I. J. Scowen, M. McPartlin, ibid. 1996, 108, 1440 bzw. 1996, 35, 1338;
6. d) Organometallics 1995, 14, 5344;
7. e) D. Selent, R. Beckhaus, R. Pickardt, ibid. 1993, 12, 2857;
8. f) L. H. Gade, Angew. Chem. 1996, 108, 2225; Angew. Chem. Int. Ed. Engl. 1996, 35, 2089.
9. f) L. H. Gade, Angew. Chem. 1996, 108, 2225; Angew. Chem. Int. Ed. Engl. 1996, 35, 2089.
10. a) A. M. Glass, Science 1987, 235, 1003;
11. b) E. Oh, A. K. Ramdus, J. K. Furdyna, J. Lumin. 1992, 52, 183; H, Ehrenreich, Science 1987, 235, 1029;
12. b) E. Oh, A. K. Ramdus, J. K. Furdyna, J. Lumin. 1992, 52, 183; H, Ehrenreich, Science 1987, 235, 1029;
13. c) M. Ilegems, R. Dingle, L. W. Rupp, Jr., J. Appl. Phys. 1975, 46, 3059;
14. d) S. von Molnar in Diluted Magnetic Semiconductors (Eds.: R. L. Agarwal, J. K. Furdyna, S. von Molnar), 1987. p. 39.
15. a) P. Boudjouk, D. J, Seidler, D. Grier, G. J. McCarthy, Chem. Mater. 1996, 8, 1189;
16. b) J. Arnold, J. M. Walker, K. M. Yu, P. J. Bonasia, A. L. Seligson, E. D. Bourret, J. Cryst. Growth 1992, 124, 647;
17. c) J. Arnold, P. J. Bonasia (University of California, Berkeley), USA 5157136, 1992;
18. d) A. L. Seligson, J. Arnold, J. Am. Chem. Soc. 1993, 115, 8214;
19. e) U. Siemeling, Angew. Chem. 1993, 105, 70; Angew. Chem. Int. Ed. Engl. 1993, 32, 67.
20. e) U. Siemeling, Angew. Chem. 1993, 105, 70; Angew. Chem. Int. Ed. Engl. 1993, 32, 67.
21. a) M. L. Sieigerwald, Mat. Res. Soc. Symp. Proc. 1989, 131, 37;
22. b) K. M. Mc Gregor, G. B. Deacon, R. S. Dickson, G. D. Fallon, R. S. Rowe, B. O. West, J. Chem. Soc. Chem. Commun. 1990, 1293;
23. c) M. L. Steigerwald, T. Siegrist, E. M. Gyorgy, B. Hessen, Y.-U. Kwon, S. M. Tanzler, Inorg. Chem. 1994, 33, 3389.
24. a) D. R. Carey, J. Arnold, Inorg. Chem. 1994, 33, 1791;
25. b) A. R. Strezelicki, P. A. Timinski, B. A. Hebel, P. A. Bianconi, J. Am. Chem. Soc. 1992, 114, 3159;
26. c) M. Breuer, Khasnis, M. Buretea, M. Berardini, T. J. Emge, J. G. Brennan, Inorg. Chem. 1994, 33, 2743;
27. d) M. Berardini, T. Emge, J. G. Brennan, J. Am. Chem. Soc. 1994, 116, 6941;
28. e) D. V. Khasnis, M. Brewer, J. S. Lee, T. J. Emge, J. G. Brennan, ibid. 1994, 116, 7129.
29. K. Jonas, E. Deffense, D. Habermann, Angew. Chem. 1983, 95, 729; Angew. Chem. Int. Ed. Engl. 1983, 22, 716; Angew. Chem. Suppl. 1983, 1005.
30. K. Jonas, E. Deffense, D. Habermann, Angew. Chem. 1983, 95, 729; Angew. Chem. Int. Ed. Engl. 1983, 22, 716; Angew. Chem. Suppl. 1983, 1005.
31. K. Jonas, E. Deffense, D. Habermann, Angew. Chem. 1983, 95, 729; Angew. Chem. Int. Ed. Engl. 1983, 22, 716; Angew. Chem. Suppl. 1983, 1005.
32. R. G. Beevor, S. A. Frith, J. L. Spencer, J. Organomet. Chem. 1981, 221, C 25.
33. P. J. Davidson, D. H. Harris, M. F. Lappert, J. Chem. Soc. Dalton Trans. 1976, 2268.
34. K. Angermund, K. Jonas, C. Krüger, J. L. Latten, Y.-H. Tsay, J. Organomet. Chem. 1988, 353, 17.
35. 2)]/3, absolute structure parameter -0.01(3). The anisotropic displacement factors of several methyl groups, particularly at C25, indicate disorder, which, however, cannot be resolved. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Germany), on quoting the depository numbers CSD-100065, CSD-406237, and CSD-406281.
36. a) C. J. Cardin, D. J. Cardin, G. A. Lawless, J. M. Power, M. B. Power, M. B. Hursthouse, J. Organomet. Chem. 1987, 325, 203;
37. b) C. J. Cardin, D. J. Cardin, H. E. Parge, J. M. Power, J. Chem. Soc. Chem. Commun. 1984, 609;
38. c) C. J. Cardin, D. J. Cardin, J. M. Power, J. Am. Chem. Soc. 1985, 107, 505;
39. d) S. M. Hawkins, P. B. Hitchcock, M. F. Lappert, J. Chem. Soc. Chem. Commun. 1985, 1592.
40. 2] of 2.387(1) Å, which is similar to that in 3a, is indicative of Ni = Sn bonding: C. Pluta, K. R. Pörschke, R. Mynott, P. Betz, C. Krüger, Chem. Ber. 1991, 124, 1321.
41. We have recently prepared the Ni/Sn complex analogous to 4: J. J. Schneider, J. Hagen, unpublished results.
42. R. A. Zingaro, B. H. Stevens, K. Irgolic, J. Organomet. Chem. 1965, 4, 320.
43. J. J. Schneider, J. Hagen, O. Heinemann, J. Bruckmann, C. Krüger, Thin Film Solids 1997, in press.