Polyoxoanion-Supported Organometallic Complexes: Carbonyls of Rhenium(I), Iridium(I), and Rhodium(I) That Are Soluble Analogs of Solid-Oxide-Supported M(CO)n+ and That Exhibit Novel M(CO)n+ Mobility

Inorganic Chemistry

Volumn 36, Issue 7, 1997, Pages 1366-1377

  Nagata, Toshi ^a,b   Pohl, Matthias ^a   Weiner, Heiko ^a,c   Finke, Richard G ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b KYOTO UNIVERSITY   (Japan)

^c TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000015669     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960910a     Document Type: Article

References (64)

1. Reviews: (a) Gates, B. C. Chem. Rev. 1995, 95, 511. (b) Lamb, H. H.; Gates, B. C.; Knözinger, H. Angew. Chem., Int. Ed. Engl. 1988, 27, 1127.
2. Reviews: (a) Gates, B. C. Chem. Rev. 1995, 95, 511. (b) Lamb, H. H.; Gates, B. C.; Knözinger, H. Angew. Chem., Int. Ed. Engl. 1988, 27, 1127.
3. Yang, A. C.; Garland, C. W. J. Phys. Chem. 1957, 61, 1504.
4. van't Blik, H. F. J.; van Zon, J. B. A. D.; Huizinga, T.; Vis, J. C.; Koningsberger, D. C.; Prins, R. J. Am. Chem. Soc. 1985, 107, 3139.
5. Frederick, B. G.; Apai, G.; Rhodin, T. N. J. Am. Chem. Soc. 1987, 109, 4797.
6. Binsted, N.; Evans, J.; Greaves, G. N.; Price, R. J. Organometallics 1989, 8, 613.
7. Herrero, J.; Blanco, C.; González-Elipe, A. R.; Espinós, J. P.; Oro, L. A. J. Mol. Catal. 1990, 62, 171.
8. Buchanan, D. A.; Hernandez, E.; Solymosi, F.; White, J. M. J. Catal. 1990, 125, 456.
9. (a) Kirlin, P. S.; DeThomas, F. A.; Bailey, J. W.; Gold, H. S.; Dybowski, C.; Gates, B. C. J. Phys. Chem. 1986, 90, 4882.
10. (b) Fung, A. S.; Tooley, P. A.; Kelley, M. J.; Koningsberger, D. C.; Gates, B. C. J. Phys. Chem. 1991, 95, 225.
11. (a) Yates, J. T., Jr.; Duncan, T. M.; Worley, S. D.; Vanghan, R. W. J. Chem. Phys. 1979, 70, 1219.
12. (b) Basu, P.; Panayotov, D.; Yates, J. T., Jr. J. Am. Chem. Soc. 1988, 110, 2074.
13. Ballinger, T. H.; Yates, J. T., Jr. J. Am. Chem. Soc. 1992, 114, 10074.
14. Wong, J. C. S.; Yates, J. T., Jr. J. Am. Chem. Soc. 1994, 116, 1610.
15. (e) Wovchko, E. A.; Yates, J. T., Jr. J. Am. Chem. Soc. 1995, 117, 12557.
16. See, for example: Koningsberger, D. C.; Prins, R. Trends Anal. Chem. 1981, 1, 16. Teo, B. K., Joy. D. C., Eds. EXAFS Spectroscopic Techniques and Applications; New York: Plenum, 1981.
17. See, for example: Koningsberger, D. C.; Prins, R. Trends Anal. Chem. 1981, 1, 16. Teo, B. K., Joy. D. C., Eds. EXAFS Spectroscopic Techniques and Applications; New York: Plenum, 1981.
18. Polyoxoanion lead references: (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: New York, 1983. (b) Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Proceedings of the July 15-17, 1992, Meeting at the Center for Interdisciplinary Research in Bielefeld, Germany; Müller, A.; Pope, M. T., Eds.; Kluwer Publishers: Dordrecht, The Netherlands, 1992.
19. Polyoxoanion lead references: (a) Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: New York, 1983. (b) Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity; Proceedings of the July 15-17, 1992, Meeting at the Center for Interdisciplinary Research in Bielefeld, Germany; Müller, A.; Pope, M. T., Eds.; Kluwer Publishers: Dordrecht, The Netherlands, 1992.
20. (a) The resemblance of polyoxoanions to discrete fragments of solid-metal oxides was first noted by Professor Baker: Baker, L. C. W. In Advances in the Chemistry of Coordination Compounds: Kirschner, S., Ed.; Macmillan: New York, 1961; p 604.
21. 13d,e
22. Finke, R. G.; Droege, M.; Hutchinson, J. R.; Gansow, O. J. Am. Chem. Soc. 1981, 103, 1587.
23. Figueras, F.; Figlarz, M.; Porteazix, J. L.; Forissier, M.; Gerand, B.; Guenot, J. J. Catal. 1981, 71, 389.
24. 3 perovskite structure: Wells, A. F. Structural Inorganic Chemistry; Clarendon Press: Oxford, U.K., 1995; pp 173, 474.
25. 8-, have been in progress for some time now, and will be repotted in due course (Aiken, J.; Weddle, K.; Edlund, D. J.; Finke, R. G. Unpublished results and experiments in progress).
26. 8-, have been in progress for some time now, and will be repotted in due course (Aiken, J.; Weddle, K.; Edlund, D. J.; Finke, R. G. Unpublished results and experiments in progress).
27. (a) Besecker, C. J.; Klemperer, W. G. J. Am. Chem. Soc. 1980, 102, 7598.
28. (b) Besecker, C. J.; Day, V. W.; Klemperer, W. G.; Thompson, M. R. Inorg. Chem. 1985, 24, 44.
29. Besecker, C. J., Day, V. W.; Klemperer, W. G. Organometallics 1985, 4, 564.
30. Klemperer, W. G.; Main, D. J. Inorg. Chem. 1990, 29, 2355.
31. (e) Besecker, C. J.; Day, V. W.; Klemperer, W. G.; Thompson, M. R. J. Am. Chem. Soc. 1984, 106, 4125.
32. (f) Day, V. W.; Klemperer, W. G.; Main, D. J. Inorg. Chem. 1990, 29, 2345.
33. 15b These, however, are not polyoxoanion-supported complexes; indeed, direct evidence available as part of Siedle and co-workers' studies demonstrated that the Rh(I) center and these non-basic polyoxoanions are too far apart for any direct interaction.
34. (b) Siedle, A. R.; Gleason, W. B.; Newmark, R. A.; Skarjune, R. P.; Lyon, P. A.; Markell, C. G.; Hodgson, K. O.; Roe, A. L. Inorg. Chem. 1990, 29, 1667.
35. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
36. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
37. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
38. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
39. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
40. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
41. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
42. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
43. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
44. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
45. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
46. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
47. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
48. 9-: Rapko, B. M.; Pohl, M.; Finke, R. G. Inorg. Chem. 1994, 33, 3624.
49. Weiner, H.; Aiken, J. D. III; Finke, R. G. Inorg. Chem. 1996, 35, 7905.
50. Schmidt, S. P., Trogler, W. C.; Basolo, F. Inorg. Synth. 1990, 28, 162.
51. (a) Edwards, D. A.; Marshalsea, J. J. Organomet. Chem. 1977, 131, 73.
52. 4 has been reported: Chan, L. Y. Y.; Isaacs, E. E.; Graham, W. A. G. Can. J. Chem. 1977, 55, 111.
53. Shriver, D. F.; Drezdzon, M. A. The Manipulation of Air-Sensitive Compounds, 2nd ed.; John Wiley & Sons; New York, 1986; pp 129-137.
54. 16i we have discussed the problem that literature chemical shifts variations as large as ±0.5 ppm are not uncommon due to the solution's volume susceptibility.
55. (a) Finke, R. G.; Nomiya, K.; Green, C. A.; Droege, M. W. Inorg. Synth. 1992, 29, 239.
56. (b) Lin, Y.; Nomiya, K.; Finke, R. G. Inorg. Chem. 1993, 32, 6040.
57. 1H-NMR.
58. (b) Day, V. W.; Klemperer, W. G.; Main, D. J. Inorg. Chem., 1990, 29, 2345-2355.
59. (a) Kläui, W.; Okuda, J.; Scotti, M.; Valderrama, M. J. Organometallic Chem. 1985, 280, C26.
60. (b) Kläui, W.; Scotti, M.; Valderrama, M.; Rojas, S.; Sheldrick, G. M.; Jones, P. G.; Schroeder, T. Angew. Chem., Int. Ed. Engl. 1985, 24, 683.
61. 7- will provide direct structural insight for or against this proposal. Hence, such additional studies are an important goal of future work.
62. (a) Attanasio, D.; Bachechi, F.; Suber, L. J. Chem. Soc., Dalton Trans. 1993, 2373.
63. (b) Abe, M.; Isobe, K.; Kida, K.; Yagasaki, A. Inorg. Chem. 1996, 35, 5114.
64. ∼300 Nanocluster "Soluble Heterogeneous Catalysts." Aiken, J. D., III; Lin, Y.; Finke, R. G. J. Mol. Catal. 1996, 114, 29.