Polyoxoanion-supported, atomically dispersed iridium(I) and rhodium(I): Na3[(C4H9)4N]5[Ir[α -Nb3P2W15O62]{η4- C8H12}] and Na3[(C4H 9)4N]5[Rh[α-Nb3P 2W15

Inorganic Syntheses

Volumn 31, Issue , 1997, Pages 186-201

  Nomiya, Kenji ^a   Pohl, Matthias ^b   Mizuno, Noritaka ^c   Lyon, David K ^b   Finke, Richard G ^d   Dickman, Michael H ^e   Glickman, Diana C ^e   Kortz, Uli ^e   Samonte, Joseph L ^e   Feibo, Xin ^e   Pope, Michael T ^e  

^a KANAGAWA UNIVERSITY   (Japan)

^b UNIVERSITY OF OREGON   (United States)

^c HOKKAIDO UNIVERSITY   (Japan)

^d Veterinary Dentistry and Oral Surgery   (United States)

^e GEORGETOWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RHODIUM COMPOUNDS;

POLYOXOANIONS;

IRIDIUM COMPOUNDS;

EID: 0001478771     PISSN: 00738077     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Article

References (37)

1. R. G. Finke, C. A. Green, and B. Rapko, Inorg. Synth., 27, 128 (1990) and references therein.
2. R. G. Finke, K. Nomiya, C. A. Green, and M. W. Droege, Inorg. Synth., 29, 239 (1992).
3. Y. Lin, K. Nomiya, and R. G. Finke, Inorg. Chem., 32, 6040 (1993).
4. R. G. Finke, D. K. Lyon, K. Nomiya, S. Sur, and N. Mizuno, Inorg. Chem, 29, 1784 (1990).
5. M. Pohl and R. G. Finke, Organometallics, 12, 1453 (1993).
6. M. Pohl, D. K. Lyon, N. Mizuno, K. Nomiya, and R. G. Finke, Inorg. Chem, 34, 1413 (1995). This paper should be consulted for additional details of, for example, the spectroscopic characterization of the precursor complexes and final product described herein.
7. (a) D. J. Edlund, R. J. Saxton, D. K. Lyon, and R. G. Finke, Organometallics, 7, 1692 (1988).
8. 62", H. Weiner, J. D. Aiken III, and R. G. Finke, Inorg. Chem. submitted.
9. R. G. Finke, D. K. Lyon, K. Nomiya, and T. J. R. Weakley, Acta Crystallogr., C46, 1592 (1990).
10. N. Mizuno, D. K. Lyon, and R. G. Finke, U.S. Patent 5,250,739, Oct. 5, 1993.
11. N. Mizuno, D. K. Lyon, and R. G. Finke, J. Catal., 128, 84 (1991).
12. D. J. Edlund, R. G. Finke, and R. J. Saxton, U.S. Patent 5,116,796, May 26, 1992.
13. (a) Y. Lin and R. G. Finke, J. Am. Chem. Soc., 116, 8335 (1994).
14. (b) Y. Lin and R. G. Finke, J. Inorg. Chem., 33, 4891 (1994).
15. J. D. Aiken III, M. Pohl and R. Finke, unpublished results.
16. R. G. Finke in Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity, M. T. Pope and A. Müller, Eds., Kluwer, Dodrecht, 1994, pp. 267-280.
17. (This monograph is Vol. 10 of Topics in Molecular Engineering, J. Maruani, Ed.)
18. 2 as a reagent in polyoxoanion synthesis was first reported by M. Dabbabi and M. Boyer, J. Inorg. Nucl. Chem., 38, 1011 (1976).
19. W. J. Randall, M. W. Droege, N. Mizuno, K. Nomiya, T. J. R. Weakley, and R. G. Finke, Inorg. Synth., 31, 167-185 (1996).
20. 17b).
21. (b) M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag, Berlin, 1983, p. 69.
22. 16).
23. (b) R. Contant and P. J. Ciabrini, J. Chem. Res. Synop., 1977, 222;
24. J. Chem. Res., Miniprint 1977, 2601.
25. (c) R. Contant, Inorg. Synth, 27, 108 (1990).
26. (d) R. G. Finke and M. W. Droege, Inorg. Chem., 22, 1006 (1983).
27. R. G. Finke, M. W. Droege, and P. J. Domaille, Inorg. Chem., 26, 3886 (1987). See also reference 7.
28. (a) M. Filowitz, R. K. C Ho, W. G. Klemperer, and W. Shum, Inorg. Chem., 18, 93 (1979).
29. (b) Klemperer has reported a preparation of crystalline material. C. J. Besecker, V. W. Day, W. G. Klemperer, and M. R. Thompson, J. Am. Chem. Soc., 106, 4125 (1984).
30. C. M. Flynn and G. D. Stucky, Inorg. Chem., 8, 178 (1969).
31. (a) R. H. Cundiff and P. C. Markunas, Anal. Chem., 30, 1447 (1958).
32. (b) R. H. Cundiff and P. C. Markunas, Anal. Chem., 30, 1450 (1958).
33. (c) R. H. Cundiff, and P. C. Markunas, Anal. Chem., 28, 792 (1956).
34. J. L. Herdé, J. C. Lambert, and C. V. Senoff, Inorg. Synth., 15, 18 (1974).
35. J. L. Herdé and C. V. Senoff, Inorg. Nucl. Chem. Lett., 7, 1029 (1971).
36. R. H. Crabtree, J. M. Quirk, H. Felkin, and T. Fillebun-Khan, Syn. React. Inorg. Met.-Org. Chem., 12, 407 (1982).
37. J. Chatt and L M. Venanzi, J. Chem. Soc., 4735 (1957).