Surface-initiated polymerization on self-assembled monolayers: Effect of reaction conditions

Macromolecular Symposia

Volumn 217, Issue , 2004, Pages 223-230

  Schmelmer, Ursula ^a   Paul, Anne ^b   Küller, Alexander ^b   Jordan, Rainer ^a,d   Gölzhäuser, Armin ^b,c   Grunze, Michael ^b   Ulman, Abraham ^d  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

^b UNIVERSITY OF HEIDELBERG   (Germany)

^c BIELEFELD UNIVERSITY   (Germany)

^d POLYTECHNIC UNIVERSITY   (United States)

Author keywords

Azo initiator; Decomposition; Polymer brushes; Self assembled monolayers; Surface initiated polymerization

Indexed keywords

ELECTRON BEAMS; ELECTRON IRRADIATION; PHOTOCHEMICAL REACTIONS; REACTION KINETICS; SELF ASSEMBLY;

ELECTRON BEAM IRRADIATION; SURFACE-INITIATED POLYMERIZATION (SIP);

POLYMERIZATION;

CONFERENCE PAPER; DIAZOTIZATION; ELECTRON BEAM; IRRADIATION; PHOTOCHEMISTRY; PHOTOMETRY; POLYMERIZATION; REACTION ANALYSIS; THERMAL ANALYSIS;

EID: 9944259939     PISSN: 10221360     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1002/masy.200451318     Document Type: Conference Paper

References (19)

1. a) R. Jordan in: 'Polymeric Materials in Organic Synthesis and Catalysis', (M. R. Buchmeiser, Ed.), Wiley-VCH, Weinheim 2003, 371 -444.
2. b) B. Zhao, W. J. Brittain Prog. Polym. Sci. 2000, 25, 677.
3. U. Schmelmer, R. Jordan, W. Geyer, A. Gölzhäuser, W. Eck, M. Grunze, A. Ulman Angew. Chem. Int. Ed. 2003, 42, 559.
4. O. Prucker, J. Rühe Macromolecules 1998, 31, 592.
5. O. Prucker, J. Rühe Macromolecules 1998, 31, 602.
6. a) R. Jordan, A. Ulman J. Am. Chem. Soc. 1998, 120, 243.
7. b) R. Jordan, N. West, A. Ulman, Y.-M. Chou, O. Nuyken Macmmolecules 2001, 34, 1606.
8. R. Jordan, A. Ulman, J. F. Kang, M. H. Rafailovich, J. Sokolov J. Am. Chem. Soc. 1999, 121, 1016.
9. A. Ulman 'An Introduction to Ultrathin Organic Films: From Langmuir-Blodgett to Self-Assembly', Academic Press, New York 1991.
10. R. Schmidt, T. Zhao, J.-B. Green, D. J. Dyer Langmuir 2002, 18, 1281.
11. X. Chen, L. M. Tolbert, C. L. Henderson, D. W. Hess, J. Rühe J. Vac. Sci. Technol. B 2001, 19, 2013.
12. O. Prucker, J. Habicht, I.-J. Park, J. Rühe Mater. Sci. Eng., C, 1999, 8-9, 291.
13. J. P. Fouassier 'Photoinitiation, Photopolymerization and Photocuring', Hanser Verlag, München 1995.
14. a) F. Schreiber Prog. Surf. Sci. 2000, 65, 151.
15. b) F. Schreiber, P. Fenter (unpublished).
16. c) T. Y. B. Leung, P. V. Schwartz, G. Scoles, F. Schreiber, A. Ulman Surf. Sci. 2000, 458, 34.
17. d) T. Y. B. Leung, M. C. Gerstenberg, D. J. Lavrich, F. Schreiber, G. Scoles, G. Poirier Langmuir 2000, 16, 549.
18. Control experiments with spin cast polystyrene films showed that exhaustive washing and sonication in toluene is adequate to effectively remove adsorbed polystyrene from the surface.
19. O. Prucker, M. Schimmel, G. Tovar, W. Knoll, J. Rühe Adv. Mater. 1998, 10, 1073.