Switching of molecular spin states in inorganic complexes by temperature, pressure, magnetic field and light: Towards molecular devices

European Journal of Inorganic Chemistry

Volumn , Issue 22, 2004, Pages 4353-4369

  Bouseksou, Azzedine ^a,c   Molnár, Gábor ^a,d   Matouzenko, Galina ^b  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^b Laboratoire de Chimie Organique   (France)

^c SORBONNE UNIVERSITÉ   (France)

^d EÖTVÖS LORÁND UNIVERSITY   (Hungary)

Author keywords

Dielectric properties; Hysteresis loop; Ising like model; Magnetic field; Metastability; Pressure; Spin crossover

Indexed keywords

DIELECTRIC PROPERTIES; INORGANIC COMPOUNDS; MAGNETIC MATERIALS; SPIN DYNAMICS;

DIELECTRICS PROPERTY; INORGANIC COMPLEXES; ISING-LIKE MODELS; MAGNETIC-FIELD; METASTABILITIES; MOLECULAR DEVICE; MOLECULAR SPINS; SPIN CROSSOVERS; SPIN STATE; SPIN-CROSSOVER PHENOMENA;

MAGNETIC FIELDS;

INORGANIC COMPOUND;

DEVICE; LIGHT; MAGNETIC FIELD; MATERIALS; MOLECULAR STABILITY; PRESSURE; SHORT SURVEY; SYNTHESIS; TECHNIQUE; TEMPERATURE; THEORETICAL MODEL;

EID: 9744275989     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400571     Document Type: Short Survey

References (110)

1. "Topics in Current Chemistry", Spin Crossover in Transition Metal Compounds I.-III. (Eds.: P. Gütlich, H.A. Goodwin), 2004, vol. 233-235.
2. [2a] P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. Int. Ed. Engl. 1994, 33, 2024.
3. [2b] P. Gütlich, Struct. Bonding (Berlin) 1981, 44, 83.
4. [2c] H. A. Goodwin, Coord. Chem. Rev. 1976, 18, 293.
5. [2d] E. König, Struct. Bonding (Berlin) 1991, 76, 51.
6. [2e] O. Kahn, Molecular magnetism, VCH, New York, 1993.
7. [2f] H. Toftlund, Coord. Chem. Rev. 1989, 94, 67.
8. [2g] J. A. Real, in: Transition Metals in Supramolecular Chemistry (Ed.: J. P. Sauvage), Wiley, New York, 1999, p. 54.
9. [3a] L. Cambi, A. Cagnasso, Atti Accad. Naz. Lincei 1931, 13, 809.
10. [3b] L. Cambi, L. Szegö, Ber. Dtsch. Chem. Ges. 1931, 64, 259.
11. W. A. Baker, H. M. Bobonich, Inorg. Chem. 1964, 3, 1184.
12. E. König, K. Madeja, J. Chem. Soc., Chem. Commun. 1966, 61.
13. http://iacgu7.chemie.uni-mainz.de/toss/ [Philipp Gütlich (Mainz, Germany), Wolfgang Linert (Wien, Austria), François Varret (Versailles, France), Olivier Kahn (Bordeaux, France), Jaap G Haasnoot (Leiden, The Netherlands), Jose A. Real (Valencia, Spain), John J. McGarvey (Belfast, UK), Alfred X. Trautwein (Lübeck, Germany), Hans Toftlund (Odense, Danmark), Andreas Hauser (Genève, Switzerland)].
14. [7a] O. Kahn, C. J. Martinez, Science 1998, 279, 44.
15. [7b] O. Kahn, J.-P. Launay, Chemtronics 1988, 3, 140.
16. [7c] O. Kahn, Curr. Opin. Solid State Mater. Sci. 1996, 1, 547.
17. [7d] O. Kahn, J. Kröber, C. Jay, Adv. Mater. 1992, 11, 718.
18. A. Bousseksou, G. Molnár, P. Demont, J. Menegotto, J. Mater. Chem. 2003, 13 2069.
19. A. Bousseksou, C. Vieu, J.-F. Letard, P. Demont, J.-P. Tuchagues, L. Malaquin, J. Menegotto, Molecular Memory with Spin Crossover Complexes, French Patent filling, no. 01/11328 (31/ 08/2001), International extension PCT/FR02/02961, August 29, 2002.
20. [10a] J. Kröber, E. Codjovi, O. Kahn, F. Groliere, C. Jay, J. Am. Chem. Soc. 1993, 115, 9810.
21. [10b] J. Krober, J. P. Audiere, R. Claude, E. Codjovi, O. Kahn, J. Haasnoot, F. Groliere, C. Jay, A. Bousseksou, J. Linares, F. Varret, A. Gonthier-Vassal, Chem. Mater. 1994, 6, 1404.
22. [11a] A. Bousseksou, N. Negre, M. Goiran, L. Salmon, J. P. Tuchagues, M. L. Boillot, K. Boukhedaden, F. Varret, Eur. Phys. J. B 2000, 13, 451.
23. [11b] N. Negre, M. Goiran, A. Bousseksou, J. G. Haasnoot, K. Boukheddaden, S. Askenazy, F. Varret, Synth. Met. 2000, 115, 289.
24. [11c] N. Nègre, C. Consejo, M. Goiran, A. Bousseksou, F. Varret, J.-P. Tuchagues, R. Barbaste, S. Asḱnazy, J. G. Haasnot, Physica B 2001, 294/295, 91.
25. [11d] A. Bousseksou, K. Bokheddaden, M. Goiran, C. Consejo, M. L. Boulot, J. P. Tuchagues, Phys. Rev. B 2002, 65, 172412.
26. [11e] C. Conséjo, G. Molnár, M. Goiran, A. Bousseksou, Polyhedron 2003, 22, 2441.
27. [11f] A. Bousseksou, K. Boukheddaden, M. Goiran, J. P. Tuchagues, F. Varret, "Spin Crossover in Transition Metal Compounds III", in Top. Curr. Chem. 2004, 235, 65.
28. [11g] F. Varret, S. Arun Salunke, K. Boukheddaden, A. Bousseksou, É. Codjovi, C. Enachescu, J. Linares, C. R. Chim. 2003, 6, 385.
29. A. Bousseksou, G. Molnar, J. P. Tuchagues, N. Menendez, E. Codjovi, F. Varret, C. R. Chim. 2003, 6, 329.
30. [13a] S. Montant, G. Chastanet, S. Létard, S. Marcen, J. F. Létard, E. Freysz, 7th Spin Crossover Family Meeting, Seeheim, Germany, March 1, 2002.
31. [13b] H. W. Liu, K. Matsuda, Z. Z. Gu, K. Takahashi, A. L. Cui, R. Nakajima, A. Fujishima, O. Sato, Phys. Rev. Lett. 2003, 90, 167403.
32. [14a] H. Spiering, E. Meissner, H. Köppen, E. W. Müller, P. Gütlich, Chem. Phys. 1982, 68, 65.
33. [14b] N. Willenbacher, H. Spiering, J. Phys. C: Solid State Phys. 1988, 21, 1423.
34. [14c] H. Spiering, N. Willenbacher, J. Phys.: Condens. Matter 1989, 1, 10089.
35. [14d] J. Jung, G. Schmitt, L. Wiehl, A. Hauser, K. Knorr, H. Spiering, P. Gütlich, Z. Phys. B: Condens. Matter 1996, 700, 523.
36. J. Wajnflasz, R. Pick, J. Phys. 1971, 32, C1-91.
37. [16a] A. Bousseksou, J. Nasser, J. Linares, K. Boukheddaden, F. Varret, J. Phys. I 1992, 2, 1381.
38. [16b] A. Bousseksou, F. Varret, J. Nasser, J. Phys. I 1993, 3, 1463.
39. [16c] A. Bousseksou, J. Nasser, J. Linares, K. Boukheddaden, F. Varret, Mol. Crys. Liq. Cryst. 1993, 234, 269.
40. [16d] A. Bousseksou, H. Constant-Machado, F. Varret, J. Phys. I 1995, 5, 747.
41. [16e] A. Bousseksou, J. Nasser, F. Varret, J. Magn. Magn. Mater. 1995, 140-144, 1511.
42. M. Sorai, S. Seki, J. Phys. Chem. Solids 1974, 35, 555.
43. [18a] A. Bousseksou, J. J. McGarvey, F. Varret, J. A. Real, J. P. Tuchagues, A. C. Dennis, M. L. Boillot, Chem. Phys. Lett. 2000, 318, 409.
44. [18b] N. Moliner, L. Salmon, L. Capes, M. C. Munoz, J. F. Létard, A. Bousseksou, J. P. Tuchagues, J. J. McGarvey, A. C. Dennis, M. Castro, R. Burriel, J. A. Real, J. Phys. Chem, B 2002, 106, 4276.
45. [18c] G Molnár, V. Niel, A. B. Gaspar, J.-A. Real, A. Zwick, A. Bousseksou, J. J. McGarvey, J. Phys. Chem. B 2002, 106, 9701.
46. [I8d] K. Hosoya, T. Kitazawa, M. Takahashi, M. Takeda, J. F. Meunier, G. Molnar, A. Bousseksou, Phys. Chem. Chem. Phys. 2003, 5, 1682.
47. [18e] J. P. Tuchagues, A. Bousseksou, G Molnar, J. J. Mc Garvey, F. Varret, in "Spin Crossover in Transition Metal Compounds III", Top. Curr. Chem. 2004, 235, 85.
48. [18f] G. Molnar, T. Kitazava, L. Dubrovinsky, J. J. McGarvey, A. Bousseksou, J. Phys.: Condens. Matter 2004, 16, S1129-S1136.
49. [18g] T. Tayagaki, A. Galet, M. Carmen Muñoz, G Molnár, A. Zwick, K. Tanaka, J.-A. Real, A. Bousseksou, J. Phys. Chem. B., submitted.
50. [19a] G. Baranovic, D. Babic, Spectrochim. Acta A 2004, 60, 1013.
51. [19b] G. Brehm, M. Reiher, S. Schneider, J. Phys. Chem. A 2002, 106, 12024.
52. [19c] H. Paulsen, A. X. Trautwein, Top. Curr. Chem. 2004, 235, 197.
53. [20a] A. Bousseksou, M. Vereist, H. Constant-Machado, G. Lemercier, J.-P. Tuchagues, F. Varret, Inorg. Chem. 1996, 35, 110.
54. [20b] A. Bousseksou, L. Salmon, F. Varret, J.-P. Tuchagues, Chem. Phys. Lett. 1998, 282, 209.
55. [20c] N. Moliner, M. Muñoz, S. Létard, L. Salmon, J.-P. Tuchagues, A. Bousseksou, J.-A. Real, Inorg. Chem. 2002, 41, 6997.
56. S. Askénazy, C. Fert, J. Marquez, P. Bellan, P. Wallace, F. Herlach, Rev. Phys. Appl. 1986, 21, 563.
57. Y. Qi, E. W Muller, H. Spiering, P. Gütlich, Chem. Phys. Lett. 1982, 93, 567.
58. [23a] J. Lejay, A. G. W. Jansen, P. Wyder, Phys. Rev. B 1991, 43, 8196.
59. [23b] Y. Garcia, O. Kahn, J.-P. Ader, A. Buzdin, Y. Meurdesoif, M. Guillot, Phys. Lett. A 2000, 271, 145.
60. [24a] C. P. Slichter, H. G. Drickamer, J. Chem. Phys. 1971, 56, 2142.
61. [24b] J. R. Ferraro, Coord. Chem. Rev. 1979, 29, 1.
62. [24c] E. Meissner, H. Köppen, C. P. Kohler, H. Spiering, P. Gütlich, Hyperfine Interact. 1986, 28, 799.
63. [24d] P. Adler, H. Spiering, P. Gütlich, J. Phys. Chem. Solids 1989, 50, 587.
64. [24e] V. Ksenofontov, G. Levchenko, H. Spiering, P. Gütlich, J.-F. Létard, Y. Bouhedja, O. Kahn, Chem. Phys. Lett. 1998, 294, 545.
65. [24f] V. Ksenofontov, H. Spiering, A. Schreiner, G. Levchenko, H. A. Goodwin, P. Gütlich, J. Phys. Chem. Solids 1999, 60, 393.
66. [24g] S. Schenker, A. Hauser, W. Wang, I. Y. Chan, Chem. Phys. Lett. 1998, 297, 281.
67. [24h] A. Hauser, H. Romstedt, J. Jeftic, J. Phys. Chem. Solids 1996, 57, 1743.
68. [24i] J. Jeftic, A. Hauser, J. Phys. Chem. B 1997, 101, 10262.
69. [24j] E. Codjovi, N. Menéndez, J. Jeftic, F. Varret, C. R. Acad. Sci., Ser. IIc: Chim. 2001, 4, 181.
70. [24k] V. Ksenofontov, A. B. Caspar, P. Gütlich, Top. Curr. Chem. 2004, 235, 23.
71. [24l] T. Granier, B. Gallois, J. Gaultier, J. A. Real, J. Zarembowitch, Inorg. Chem. 1993, 32, 5305.
72. [24m] J. J. McGarvey, I. Lawthers, K. Heremans, H. Toftlund, J. Chem. Soc. Chem. Comm. 1984, 1575.
73. [25a] F. Varret, A. Bleuzen, K. Boukheddaden, A. Bousseksou, E. Codjovi, C. Enachescu, A. Goujon, J. Linares, N. Menendez, M. Verdaguer, Pure Appl. Chem. 2002, 74, 2159.
74. [25b] G. Molnar, V. Niel, J. A. Real, L. Dubrovinsky, A. Bousseksou, J. J. Mc-Garvey, J. Phys. Chem. B 2003, 107, 3149.
75. A. Bousseksou, L. Tommasi, G. Lemercier, F. Varret, J.-P. Tuchagues, Chem. Phys. Lett. 1995, 243, 493.
76. M. L. Boillot, J. Zarembowitch, J. P. Itié, A. Polian, E. Bourdet, J. Haasnot, New J. Chem. 2002, 26, 313.
77. R. Zimmermann, E. König, J. Phys. Chem. Solids 1977, 38, 779.
78. J. J. McGarvey, I. Lawthers, J. Chem. Soc., Chem. Commun. 1982, 906.
79. S. Decurtins, P. Gütlich, C. P. Köhler, H. Spiering, A. Hauser, Chem. Phys. Lett. 1984, 105, 1.
80. [31a] A. Hauser, J. Chem. Phys. 1991, 94, 2741. A. Hauser, Coord. Chem. Rev. 1991, 111, 275
81. [31a] A. Hauser, J. Chem. Phys. 1991, 94, 2741. A. Hauser, Coord. Chem. Rev. 1991, 111, 275.
82. [31b] A. Hauser, J. Jeftic, H. Romstedt, R. Hinek, H. Spiering, Coord. Chem. Rev. 1999, 190-192, 491.
83. [31c] A. Hauser, Top. Curr. Chem. 2004, 234, 155.
84. [31d] F. Varret, K. Boukheddaden, E. Codjovi, C. Enachescu, J. Linarès, Top. Curr. Chem. 2004, 234, 199.
85. J.-F. Létard, P. Guionneau, L. Goux-Capes, Top. Curr. Chem. 2004, 255, 221.
86. G. S. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van Koningsbruggen, M. Perrin, O. Kahn, A. Collet, Inorg. Chem. 1997, 36, 2975.
87. G. S. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van Koningsbruggen, M. Perrin, O. Kahn, A. Collet, Inorg. Chem. 1997, 36, 5869.
88. [35a] E. König, K. Madeja, Inorg. Chem. 1967, 6, 48.
89. [35b] E. König, K. Madeja, K. J. Watson, J. Am. Chem. Soc. 1968, 90, 1146.
90. [35c] A. Ozarowski, B. R. MacGarvey, A. B. Sarkar, E. Drake, Inorg. Chem. 1988, 27, 627.
91. [36a] p Poganiuch, S. Decurtins, P. Gütlich, J. Am. Chem. Soc. 1990, 112, 3270,
92. [36b] L. Wiehl, Acta Crystallogr., Sect. B 1993, 49, 289.
93. [36c] R. Hinek, H. Spiering, D. Schollmeyer, P. Gütlich, A. Hauser, Chem. Eur. J. 1996, 2, 1427.
94. [36d] G. Matouzenko, G. Vériot, J. P. Dutasta, A. Collet, J. Jordanov, F. Varret, M. Perrin, S. Lecocq, New J. Chem. 1995, 19, 881.
95. [36e] Y. Garcia, O. Kahn, L. Rabardel, B. Chansou, L. Salmon, J. P. Tuchagues, Inorg. Chem. 1999, 38, 4663.
96. G. S. Matouzenko, J.-F. Letard, S. Lecocq, A. Bousseksou, L. Capes, L. Salmon, M. Perrin, O. Kahn, A. Collet, Eur. J. Inorg. Chem. 2001, 2935.
97. G. S. Matouzenko, A. Bousseksou, S. A. Borshch, M. Perrin, S. Zein, L. Salmon, G. Molnar, S. Lecocq, Inorg. Chem. 2004, 43, 227.
98. [39a] M. Mikami, M. Konno, Y. Saito, Chem. Phys. Lett. 1979, 63, 566.
99. [39b] E. König, G. Ritter, S. K. Kulshreshtha, J. Waigel, L. Sacconi, Inorg. Chem. 1984, 23, 1241.
100. [39c] C-C. Wu, J. Jung, P. K. Gantzel, P. Gütlich, D. N. Hendrickson, Inorg. Chem. 1997, 36, 5339.
101. [40a] O. Kahn, E. Codjovi, Philos. Trans. R. Soc. London, Ser. A 1996, 354, 359.
102. [40b] O. Kahn, Y. Garcia, J.-F. Letard, C. Mathonière, NATO ASI Ser., Ser. C 1998, 518, 127.
103. [41a] L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Koord. Khim. 1986, 12, 207.
104. [41b] L. G. Lavrenova, V. N. Ikorskii, V. A. Varnek, I. M. Oglezneva, S. V. Larionov, Koord. Khim. 1990, 16, 654.
105. [41c] W. Vreugdenhil, J. H. van Diemen, R. A. G. de Graaff, J. G. Haasnoot, J. Reedjik, A. M. van der Kraan, O. Kahn, J. Zarembowitch, Polyhedron 1990, 9, 2971.
106. [42a] A. Michalowitch, J. Moscovici, J. Ducourant, D. Cracco, O. Kahn, Chem. Mater. 1995, 7, 1833.
107. [42b] A. Michalowitch, J. Moscovici, O. Kahn, J. Phys. IV 1997, 7, C2-633.
108. [43a] J. A. Real, E. Andrés, M. C. Munoz, M. Julve, T. Granier, A. Bousseksou, F. Varret, Science 1995, 268, 265.
109. [43b] N. Moliner, C. Munoz, S. Létard, X. Solans, N. Menéndez, A. Goujon, F. Varret, J. A. Real, Inorg. Chem. 2000, 39, 5390.
110. G. S. Matouzenko, G. Molnar, N. Bréfuel, M. Perrin, A. Bousseksou, S. A. Borshch, Chem. Mater. 2003, 15, 550.