Two-step spin crossover in a mononuclear compound [Fe(DPEA)(bim)](ClO4)2·0.5 H2O[DPEA = (2-aminoethyl)-bis(2-pyridylmethyl)amine, bim = 2,2-bisimidazole] - Crystal structure, magnetic properties, Mössbauer spectroscopy, and photomagnetic effects

European Journal of Inorganic Chemistry

Volumn , Issue 11, 2001, Pages 2935-2945

  Matouzenko, Galina S ^a   Létard, Jean François ^b   Lecocq, Sylvain ^c   Bousseksou, Azzedine ^d   Capes, Laurence ^b,e   Salmon, Lionel ^d   Perrin, Monique ^c   Kahn, Olivier ^b   Collet, André ^a  

^a UNIVERSITÉ DE LYON   (France)

^b INST CHIM MATIERE COND BORDEAUX   (France)

^c UNIVERSITÉ LYON 1   (France)

^d LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^e Motorola Labs   (France)

Author keywords

Iron; M ssbauer spectroscopy; N ligands; Photomagnetism; Spin crossover

Indexed keywords

ENERGY DISPERSIVE X RAY ANALYSIS; EXCITED STATES; INORGANIC COMPOUNDS; IRON COMPOUNDS; ISOMERS; MAGNETIC SUSCEPTIBILITY; MOLECULES; SINGLE CRYSTALS; SPECTRUM ANALYSIS; SPIN DYNAMICS;

BIS(2-PYRIDYLMETHYL)AMINE; CRYSTALS STRUCTURES; LATTICE SITES; MAGNETIC CURVES; MÖSSBAUE SPECTROSCOPY; N LIGANDS; N-LIGANDS; PHOTOMAGNETISM; SPIN CROSSOVERS; SPIN TRANSITION;

CRYSTAL STRUCTURE;

IRON COMPLEX;

ARTICLE; COMPLEX FORMATION; CROSSOVER PROCEDURE; CRYSTAL STRUCTURE; MAGNETISM; MOSSBAUER SPECTROSCOPY; X RAY ANALYSIS;

EID: 0034752173     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200111)2001:11<2935::AID-EJIC2935>3.0.CO;2-D     Document Type: Article

References (64)

1. [1a] H. A. Goodwin, Coord. Chem. Rev. 1976, 18, 293-325.
2. [1b] P. Gütlich, Struct. Bonding 1981, 44, 83-164.
3. [1c] E. König, G. Ritter, S. K. Kulshreshtha, Chem. Rev. 1985, 85, 219-234.
4. [1d] H. Toftlund, Coord. Chem. Rev. 1989, 94, 67-108.
5. [1e] P. Gütlich, A. Hauser, Coord. Chem. Rev. 1990, 97, 1-22.
6. [1f] J. Zarembowitch, O. Kahn, New J. Chem. 1991, 15, 181-190.
7. [1g] E. König, Struct. Bonding. 1991, 76, 51-152.
8. [1h] P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. Ed. Engl. 1994, 33, 2024-2053.
9. [1i] O. Kahn, Molecular Magnetism; VCH: New York 1993.
10. [1j] O. Kahn, E. Codjovi, Phil. Trans. R. Soc. Lond. A 1996, 354, 359-379.
11. [2a] C. P. Slichter, H. G. Drikamer, J. Chem. Phys. 1972, 56, 2142-2160.
12. [2b] R. Zimmermann, E. König, J. Phys. Chem. Solids 1977, 38, 779-788.
13. [2c] P. S. Rao, P. Ganguli, B. R. McGarvey, Inorg. Chem. 1981, 20, 3682-3688.
14. [2d] N. Sasaki, T. Kambara, J. Chem. Phys. 1981, 74, 3472-3481.
15. [2e] S. Ohnishi, S. Sugano, J. Phys. C 1981, 14, 39-47.
16. [2f] H. Spiering, E. Meissner, C. P. Köhler, E. F. Müller, P. Gutlich, Chem. Phys. 1982, 68, 65-71.
17. [2g] H. Spiering, N. Willenbacher, J. Phys. Condens. Matter 1989, 10089-10105.
18. [3a] E. König, K. Madeja, Inorg. Chem. 1967, 6, 48-55.
19. [3b] E. König, K. Madeja, K. J. Watson, J. Am. Chem. Soc. 1968, 90, 1146-1153.
20. [3c] A. Ozarowski, B. R. McGarvey, A. B. Sarkar, E. Drake, Inorg. Chem. 1988, 27, 627-635.
21. G. S. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van. Koningsbruggen, M. Perrin, O. Kahn, A. Collet, Inorg. Chem. 1997, 36, 5869-5879.
22. [5a] P. Poganiuch, S. Decurtins, P. Gütlich, J. Am. Chem. Soc. 1990, 112, 3270-3278.
23. [5b] L. Wiehl, Acta Crystallogr., Sect. B 1993, 49, 289-303.
24. R. Hinek, H. Spiering, D. Schollmeyer, P. Gûtlich, A. Hauser, Chem. Eur. J. 1996, 2, 1427-1434.
25. G. Matouzenko, G. Vériot, J. P. Dutasta, A. Collet, J. Jordanov, F. Varret, M. Perrin, S. Lecocq, New J. Chem. 1995, 19, 881-885.
26. H. R. Chang, J. K. McCusker, H. Toftlund, S. R. Wilson, A. X. Trautwein, H. Winkler, D. N. Hendrickson, J. Am. Chem. Soc. 1990, 112, 6814-6827.
27. Y. Garcia, O. Kahn, L. Rabardel, B. Chansou, L. Salmon, J. P. Tuchagues, Inorg. Chem. 1999, 38, 4663-4670.
28. D. Boinnard, A. Bousseksou, A. Dworkin, J. M. Savariault, F. Varret, J. P. Tuchagues, Inorg. Chem. 1994, 33, 271-281.
29. [11a] S. Decurtins, P. Gütlich, C. P. Köhler, H. Spiering, A. Hauser, Chem. Phys. Lett. 1984, 105, 1-4.
30. [11b] S. Decurtins, P. Gütlich, K. M. Hasselbach, H. Spiering, A. Hauser, Inorg. Chem. 1985, 24, 2174-2178.
31. G. S. Matouzenko, A. Bousseksou, S. Lecocq, P. J. van Koningsbruggen, M. Perrin, O. Kahn, A. Collet, Inorg. Chem. 1997, 36, 2975-2981.
32. R. Ingalls, Phys. Rev. 1964, 133A, 787-795.
33. A. Ducouret-Cérèse, F. Varret, J. Phys. (Paris) 1988, 49, 661-666.
34. A. Hauser, Chem. Phys. Lett. 1986, 124, 543-548.
35. J.-F. Létard, L. Capes, G. Chastanet, N. Moliner, S. Létard, J.-A. Real, O. Kahn, Chem. Phys. Lett. 1999, 313, 115-120.
36. [17a] A. Hauser, J. Adler, P. Gütlich, Chem. Phys. Lett. 1988, 152, 468-472.
37. [17b] T. Buchen, P. Gütlich, Chem. Phys. Lett. 1994, 220, 262-266.
38. [17c] In LB film: J.-F. Létard, O. Nguyen, H. Soyer, C. Mingotaud, P. Delhaès, O. Kahn, Inorg. Chem. 1999, 38, 3020-3021.
39. [17d] A. Roubeau, J. G. Haasnoot, J. Linares, F. Varret, Mol. Cryst. and Liq. Cryst. 1999, 335, 541-550.
40. [18a] H. Köppen, E. W. Müller, C. P. Köhler, H. Spiering, E. Meissner, P. Gütlich, Chem. Phys. Lett. 1982, 91, 348-352.
41. [18b] A. M. Greenaway, C. J. O'Connor, A. Schrock, E. Sinn, Inorg. Chem. 1979, 18, 2692-2695.
42. [18c] M. Mikami, M. Konno, Y. Saito, Chem. Phys. Lett. 1979, 63, 566-569.
43. [18d] K. Kaji, M. Sorai, Thermochim. Acta 1985, 88, 185-190.
44. [18e] R. Jakobi, H. Spiering, P. Gütlich, J. Phys. Chem. Solids 1992, 53, 267-275.
45. [18f] C. P. Köhler, R. Jakobi, E. Meissner, L. Wiehl, H. Spiering, P. Gütlich, J. Phys. Chem. Solids 1990, 51, 239-247.
46. [18g] H. Spiering, T. Kohlhaas, H. Romstedt, A. Hauser, C. Bruns-Yilmaz, J. Kusz, P. Gütlich, Coord. Chem. Rev. 1999, 190-192, 629-647.
47. [19a] J. A. Real, H. Bolvin, A. Bousseksou, A. Dworkin, O. Kahn, F. Varret, J. Zarembowitch, J. Am. Chem. Soc. 1992, 114, 4650-4658.
48. [19b] J. A. Real, I. Castro, A. Bousseksou, M. Verdaguer, R. Burriel, M. Castro, J. Linares, F. Varret, Inorg. Chem. 1997, 36, 455-464.
49. [20a] S. W. Kaiser, R. B. Saillant, P. G. Rasmussen, J. Am. Chem. Soc. 1975, 97, 425-426.
50. [20b] S. W. Kaiser, R. B. Saillant, W. M. Butler, P. G Rasmussen, Inorg. Chem. 1976, 15, 2681-2694.
51. [20c] M. S. Haddad, D. H. Hendrickson, Inorg. Chem. 1978, 17, 2622-2625.
52. [20d] P. G. Rasmussen, O. H. Bailey, J. C. Bayon, Inorg. Chem. 1984, 23, 338-344.
53. F. Holmes, K. M. Jones, E. G. Torrible, J. Chem. Soc. 1961, 4790-4793.
54. [22a] B. Gallois, J. A. Real, C. Hauw, J. Zarembowitch, Inorg. Chem. 1990, 29, 1152-1158.
55. [22b] J.-F. Létard, P. Guionneau, L. Rabardel, J. A. K. Howard, A. E. Goeta, D. Chasseau, O. Kahn, Inorg. Chem. 1998, 37, 4432-4441.
56. [22c] P. Guionneau, J.-F. Létard, D. S. Yufit, D. Chasseau, G. Bravic, A. E. Goeta, J. A. K. Howard, O. Kahn, J. Mater. Chem. 1999, 9, 985-994.
57. E. Buhks, G. Navon, M. Bixon, J. Jortner, J. Am. Chem. Soc. 1980, 102, 2918-2923.
58. [24a] A. Hauser, A. Vef, P. J. Adler, Chem. Phys. 1991, 95, 8710-8717.
59. [24b] A. Hauser, Comment. Inorg. Chem. 1995, 17, 17-39.
60. H. Debus, Annalen. 1859, 107, 199-208.
61. F. Varret, Proceedings of the International Conference on Mössbauer Effect Applications. Jaipar, India, 1981; Indian National Science Academy: New Delhi, 1982.
62. G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Determination; University of Göttingen: Germany, 1997.
63. G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1997.
64. A. L. Spek, PLATON, A Multipurpose Crystallographic Tool; Utrecht University: Utrecht, The Netherlands, 1999.