Spin-crossover molecular materials

Current Opinion in Solid State and Materials Science

Volumn 1, Issue 4, 1996, Pages 547-554

  Kahn, Olivier ^a  

^a INST CHIM MATIERE COND BORDEAUX   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000313960     PISSN: 13590286     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1359-0286(96)80070-2     Document Type: Article

References (49)

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8. 2 after LIESST and thermal spin trapping. Inorg Chem 1994, 33:4573-4576. A HS state generated by LIESST stable up to 80 K.
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10. Hauser A: Intersystem crossing in iron(II) coordination compounds: a model process between classical and quantum mechanical behavior. Comment Inorganic Chem 1995, 17:17-40. An excellent review on the photophysical properties of spin-crossover compounds.
11. 2] (x=0.1, 1; ptz = 1 - propyltetrazole). J Chem Phys Solids 1996, in press. A thorough and convincing study of a complicated problem.
12. 2 spin-crossover system: fine tuning the energy gap. Inorg Chem 1994, 33:567-572. An interesting material with two iron(II) crystallographic sites.
13. 2 spin-crossover system. 1. High-spin→low-spin transition in two lattice sites. Chemistry, a European Journal 1996, in press.
14. •]), in which one of the sites shows a thermal hysteresis.
15. 2. Inorg Chem 1996, 35:155-161.
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17. Armand F, Badoux C, Bonville P, Ruaudel-Texier A, Kahn O: Langmuir-Blodgett films of spin transition iron(II) metalloorganic polymers. 1. Iron(II) complexes of octadecyl-1,2,4-triazole. Langmuir 1995, 11:3467-3472.
18. 2. Inorg Chem 1994, 33:2273-2279. A novel and very elegant approach of the optical addressing of spin-crossover compounds.
19. Toftlund H: The use of dinucleating tripodal ligands in the design of new magnetic materials. In Magnetism: A supramolecular function. Edited by Kahn O. Dorderecht: Kluwer; 1996, in press.
20. - radical anion.
21. Lemercier G, Verelt M, Bousseksou A, Varret F, Tuchagues JP: Towards control of the intrinsic characteristics of spin-crossover in ferrous materials. In Magnetism: A supramolecular function. Edited by Kahn O. Dordrecht: Kluwer; 1996, in press. An appealing family of compounds for which the spin-crossover regime is controlled by the nature of the counteranion.
22. 2 investigated by Mössbauer spectroscopy and magnetic measurements. J Mag Magn Mater 1995, 150:227-230.
23. 2, first example of spin conversion monitored by molecular vibrations. Inorg Chem 1996, 35:110-115.
24. 2-sal-N(1,4,7,10))]: 292, 153, and 103 K X-ray crystal and molecular structure and infrared, magnetic, Mössbauer, calorimetric, and theoretical studies. Inorg Chem 1994, 33:271-281. An important and well documented study concerning a compound showing an unusual two-step spin transition.
25. 2- sal-N(1,4,7,10))] investigated by Mössbauer spectroscopy and magnetic susceptibility. Chem Phys Lett 1995, 243:493-499.
26. 2bpym (L = 2-2-di-thiazoline (bt) and bpym; X = S, Se). X-ray absorption spectroscopy, magnetic, calorimetric and Mössbauer studies. Inorg Chem 1996, in press.
27. Kahn O, Codjovi E: Iron(II)-1,2,4-triazole spin transition molecular materials. Phil Trans Roy Soc London A 1996, 354:359-379. A short review on compounds exhibiting abrupt spin transitions around room temperature with wide thermal hystereses, and pronounced thermochromic effects.
28. 2O. Inorg Chem 1994, 33:2617-2623.
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30. 2O (Htrz = 1,2,4- 4H-triazole; trz = 1,2,4-triazolato). Chem Mater 1994, 6:1404-1412. A detailed study concerning materials which could be used as active elements in display devices.
31. Codjovi E, Sommier L, Kahn O, Jay C: A spin transition molecular material with an exceptionally large thermal hysteresis at room temperature. New J Chem 1996, 20:503-505.
32. Lavrenova FG, Yudina NG, Ikorskii VN, Varnek VA, Oglezneva IM, Larionov SV: Spin-crossover and thermochromism in complexes of iron iodide and thiocyanate with 4-amino-1,2,4-triazole. Polyhedron 1995, 14:1333-1337.
33. Lavrenova FG, Ikorskii VN, Varnek VA, Oglezneva IM, Larionov SV: Influence of magnetic dilution on the spin transition in the complex of iron(II) nitrate with 4-amino-1,2,4-triazole. J Struct Chem 1993, 34:960-965.
34. 2O (Htrz = 1,2,4- 4H-triazole; trz = 1,2,4-triazolato). Chem Mater 1995, 7:1833-1842.
35. Kröber J, Codjovi E, Kahn O, Grolière F, Jay C: A spin transition system with a thermal hysteresis at room temperature. J Am Chem Soc 1993, 115:9810-9811.
36. Real JA, Andrès E, Munoz C, Julve M, Granier T, Bousseksou A, Varret F: Spin crossover in a catenane supramolecular system. Science 1995, 268:265-267. A beautiful supramolecular architecture incorporating spin-crossover sites.
37. 4)·S. Inorg Chem 1993, 32:2681-2693.
38. 5Cl. J Phys Chem Solids 1994, 55:317-326. A good example of the very accurate thermodynamical studies performed by M Sorai.
39. 4 Cr(II) compound.
40. 2O. Inorg Chem 1994, 33:5535-5540.
41. Bousseksou A, Constant-Machado H, Varret F: Single Ising-like model for spin conversion including molecular vibrations. J Phy (France) 1995, 5:747-760.
42. Constant-Machado H, Linares J, Varret F, Haasnoot JG, Martin JP, Zarembowitch J, Dworkin A, Bousseksou A: Dilution effect in a spin-crossover system, modelled in terms of direct and indirect intermolecular interactions. J Phys (France) 1996, in press.
43. Bolvin H, Kahn O: Ising model for low-spin high-spin transitions in molecular compounds; within and beyond the mean-field approximation. Chem Phys 1995, 192:295-305.
44. 1 intersystem crossing in spin-crossover complexes: Empirical correlations between activation parameters and ligand structure in a series of polypyridyl ferrous complexes. Inorg Chem 1996, 35:2100-2112. A stimulating paper concerning the dynamics of intersystem crossing.
45. Bolvin H, Kahn O: Ferromagnetism and spin transition: An attempt at a unifying approach. Chem Phys Lett 1995, 243:355-358. An original comparison between Ising ferromagnets and spin transition compounds.
46. Lanfranc de Panthou F, Belorizki E, Calenczuk R, Luneau D, Marcenat C, Ressouche E, Turek P, Rey P: A new type of thermally induced spin transition associated with an equatorial axial conversion in a copper(II)-nitroxide cluster. J Am Chem Soc 1995, 117:11247-11253. The first report of a brand new type of spin-state change in molecular compounds.
47. Lanfranc de Panthou F, Luneau D, Musin R, Öhrström L, Grand A, Turek P, Rey P: Spin transition and ferromagnetic interactions in copper(II) complexes of 2-(3-pyridyl)imino-nitroxide. Dependence of the magnetic properties upon crystal packing. J Am Chem Soc 1996, in press.
48. III(catecholate) (semiquinolate)] valence- tautomeric conversion. J Am Chem Soc 1993, 115:8221-8229.
49. Kahn O, Kröber J, Jay C: Spin transition molecular materials for displays and data recording. Adv Mater 1992, 4:718-728.