Iron-catalyzed oxidation of sulfite: From established results to a new understanding

Progress in Reaction Kinetics and Mechanism

Volumn 28, Issue 3, 2003, Pages 189-255

  Yermakov, Alexander N ^a   Purmal, Anatol P ^b  

^a SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

^b NONE   (Russian Federation)

Author keywords

"Critical" phenomena; Branching reaction; Chain length; Chain carriers; External chain initiation; Homogeneous catalysis; Inhibitors; Kinetic criteria; Metal and chain carriers cycles; Rate restrictions; Redox initiators; Transition metal ions

Indexed keywords

CATALYSIS; CHAIN CONVEYORS; CORROSION INHIBITORS; IONS; IRON; OXIDATION; REACTION KINETICS; REDOX REACTIONS; TRANSITION METALS;

"CRITICAL" PHENOMENA; BRANCHING REACTION; CHAIN CARRIERS; CHAIN LENGTH; EXTERNAL CHAIN INITIATION; HOMOGENEOUS CATALYSIS; KINETIC CRITERIA; METAL AND CHAIN-CARRIERS CYCLES; RATE RESTRICTIONS; TRANSITION METAL IONS;

SULFUR COMPOUNDS;

EID: 9644295496     PISSN: 14686783     EISSN: None     Source Type: Journal    
DOI: 10.3184/007967403103165503     Document Type: Article

References (119)

1. Ch. Brandt and R. van Eldik, Chem. Rev. 1995, 95, 119.
2. A. Z. Titoff, Z. Phys. Chem., 1903, 45, 641
3. V. Linek and V. Vacek, Chem. Eng. Sci. 1981, 36, 1747.
4. H. Basset and W. G. Parker, J. Chem. Soc., 1951, 1540.
5. L. R. Martin, M. W. Hill, A. F. Tai and T. W. Good, J. Geophys. Res., 1991, 96, NO D2, 3085.
6. K. Bal Reddy and R. van Eldik, Atmos. Environ., 1992, 26A, 661.
7. J. Ziajka, F. Beer and P. Wameck, Atmos. Environ., 1994, 28, 2549.
8. Ch. Brandt, I. Fabian and R. van Eldik, J. Inorg. Chem., 1994, 33, 687.
9. J. Berglund, S. Fronaeous and L. I. Elding, Atmos. Environ., 1995, 29, 1379.
10. P. Warneck and J. Ziajka, Ber. Bunsenges Phys. Chem., 1995, 9, 59.
11. P. Warneck, V. Mirabel, G. A. Salmon, R. van Eldik, C. Vinkier, K. J. Wannowius and C. Zetcsch, Review of the Activities and Achievements of the EUROTRAC Subproject HALIPP; Warneck P. Ed.; Springer: Berlin, 1996, 2, 7.
12. R. van Eldik, N. Coichev, K. Bal Reddy and A. Gerhard, Ber. Bunsenges Phys. Chem., 1992, 96, 454.
13. J. Langner and H. Rodhe, J. Atmos. Chem., 1991, 13, 255.
14. P. Lai, S. Fuzzi, M. C. Facchini, G. Orsi, A. Berner, C. Kruisz, W. Wobrock, A. Halberg, K. N. Bower, M. W. Gallagher, K. M. Beswick, R. N. Colvile, T. W. Choularton, P. Nason and B. Jones, Atmos. Environ., 1997, 31, 2503.
15. P. Behra and L. Sigg, Nature, 1990, 344, 419.
16. D. Sedlak, J. Hoigne, M. M. David, R. N. Colvile, E. Seyffer, K. Acker, W. Wiepercht, J. A. Lind and S. Fuzzi, Atmos. Environ., 1997, 31, 2515.
17. S. F. Cullis and M. M. Hirshler, Atmos. Environ., 1980, 14, 1263.
18. J. L. Regens and R. W. Rycroft The acid rain controversy, 1988, Bayker and Taylor International, London
19. Learning to manage global environmental risks, 2001, The MIT press, Cambridge, Massachusetts, London, England
20. J. H. Seinfeld and S. N. Pandis, Atmospheric Chemistry and Physics. From Air Pollution to Climate Change; Wiley-Interscience: New-York, 1998, 1326.
21. H. Hoffmann, P. Hoffmann and K. Y. Lieser, Fresenius J. Anal. Chem., 1991, 340, 591.
22. R. K. Ulrich, G. T. Rochelle and R. E. Prado, Chem. Eng. Sci. 1986, 41, 2183.
23. High Sulfur Test Center, EPRI.
24. J. G. Muller and C. J. Burrows, Inorganica Chimica Acta. 1998. 275-276, 314.
25. W. Pasiuk-Bronikowska, Global atmospheric change and its impact on regional air quality. Ed. I. Barnes. Kluwer Academic Publishers. NATO Science Series. IV Earth and Environmental Sciences - 2002, 16, 121.
26. F. G. Neytzell-de-Wilde and L. Traverner, Proceedings of the second United Nations International Conference on Peacful uses of atomic energy, vol. 3, Geneva; United Nations, 1958, 303.
27. M. C. Rand and S. B. Gale, in Principles and applications of water chemistry. Ed. By Faust S. D., Hunter J. V. John Wiley & Sons Inc. 1967, 397.
28. P. Brimblecomb and D. J. Spedding Atmos. Environ. 1974, 8, 937.
29. S. Fuzzi, Atmos. Environ. 1978 12, 1439.
30. A. Huss, Jr, P. K. Lim and C. A. Eckert, J. Phys. Chem. 1982, 86, 4224.
31. L. R. Martin, Acid Precipitation Series/Ed. Culvert J. G., Boston, Butterworth, 1984, 3, 63.
32. T. Ibusuki and K. Takeuchi, K. Atmos. Environ. 1987, 21, 1555.
33. I. Grgić, V. Hudnick, M. Bizjak and J. Levee, Atmos. Environ. 1991, 25A, 1591.
34. J. Berglund, S. Fronaeous and L. I. Elding, J. Inorg. Chem. 1993, 32, 4527.
35. D. L. Sedlak and J. Hoigné, Emir. Sci. Tech. 1994, 28, 1898.
36. O. A. Travina, Ju. N. Kozlov, A. P. Purmal and I. J. Rod'ko, J. Phys. Chem. (Rus), 1999, 73, 1361.
37. E. R. Altwicker and T. Seculic, Environ. Lett., 1974, 7, 125.
38. R. C. Hoather and C. F. Goodeve, Trans. Farad. Soc. 1934, 30, 1151.
39. D. R. Coughanowr and F. E. Krause, Ind. Engng. Chem. Fund. 1965 4, 61.
40. S. A. Penkett, B. M. P. Jones and A. E. J. Eggleton, Atmos. Environ. 1979, 13, 139.
41. W. Pasiuk-Bronikowska and T. Bronikowskii, Chem. Ing. Sci. 1981, 36, 215.
42. W. Pasiuk-Bronikowska and J. Ziajka, Chem. Engng. Sci. 1985, 40, 1567.
43. R. Collins, PhD Thesis, Georgia Institute of Technology USA, 1987.
44. I. Grgić, V. Hudnick, M. Bizjak and J. Leveć, Atmos. Environ. 1992, 26A, 571.
45. S. Luňak, J. Vepřek-Šhiška, Coll. Czech. Chem. Comm. 1976, 41, 3495.
46. A. N. Yermakov, G. A. Poskrebyshev and A. P. Purmal, in Chemistry, Energy and the Environment, Ed. C. A. C. Sequeira and J. B. Moffat, The Royal Society of Chemistry, information Services, 1998, 201.
47. L. R. Martin and M. W. Hill, J. Phys. E: Sci. Instrum. 1987, 20, 1383.
48. A. N. Yermakov and A. P. Purmal, Program and Abstracts. IV Intent. Conf. Chem. Kinetics'97. NIST. Gaithersburg, MD, USA, 1997, 283.
49. Ch. Brandt and R. van Eldik, Transition Met. Chem. 1998, 23, 667.
50. G. V. Buxton, S. Croft, S. McGowan, J. E. Williams and N. D. Wood, Atmos. Environ. 1996, 30, 2483.
51. A. N. Yermakov, B. M. Zhitomirsky, G. A. Poskrebyshev and S. I. Stoliarov, J. Phys. Chem. 1995, 99, 3120.
52. R. E. Huie, C. L. Clifton and N. Altstein, Radiat. Phys. Chem., 1989, 33, 361.
53. G. V. Buxton, S. Croft, S. McGowan and G. A. Salmon, Final Report Contract No. STEP-0005-C(MB). Report E., 1992, 61.
54. U. Deister and P. Warnek, J. Phys. Chem. 1990, 94, 2191.
55. P. H. Wine, Y. Tang, R. P. Thorn and J. R. Wells, J. Geoph Res., 1989, 94, 1085.
56. A. N. Yermakov, B. M. Zhitomirsky, G. A. Poskrebyshev and D. M. Sozurakov, J. Phys. Chem. 1993, 97, 10712.
57. E. A. Betterton and M. R. Hoffman, J. Phys. Chem. 1988, 92, 5962.
58. H. Elias, U. Götz and K. J. Wannowius, Atmos. Environ., 1994, 28, 439.
59. J. Lagrange, P. Lagrange, C. Pallares and G. Wenger, Final Report Contract No. STEP - 0005 - C(MB). Report A. 1992. P. 11.
60. S. Barlow, G. V. Buxton, G. A. Salmon and J. E. Williams, EUROTRAC Ann. Rep. 1993, Part. 6. 48.
61. W. J. McElroy and S. Waygood, J. Chem. Soc. Faraday Trans. 1990, 86, 2557.
62. B. C. Gilbert and J. Stell, J. Chem. Soc. Perkin Trans. 1990, 2, 1281.
63. J. Berglund, L. I. Elding, G. V. Buxton, S. McGowan and G. A. Salmon, J. Chem. Soc. Faraday Trans., 1994, 90, 3309.
64. D. J. Jacob, E. W. Gottlieb and M. J. Prather, J. Geophys. Res., 1989, 94, 12975.
65. E. Hayon, A. Treinin and J. Wilf, J. Am. Chem. Soc. 1972, 94, 47.
66. H. -J. Benkelberg and P. Warneck, J. Phys. Chem., 1995, 99, 5214.
67. T. J. Larson, N. R. Horike and H. Harrison, Atmos. Environ. 1978, 12, 1597.
68. T. Sato, T. Goto, T. Okabe and F. Lawson, Bull. Chem. Soc. Japan, 1984, 57, 2082.
69. A. N. Yermakov and A. P. Purmal, Kinetics and Catalysis, 2001, 42, 531.
70. M. Radojevic, Environ. Tech. Lett. 1984, 5, 549.
71. E. C. Fuller and R. H. Crist, J. Amer. Chem. Soc. 1941, 63, 1644.
72. J. M. Miller and R. G. de Pena, J. Geophys. Res. 1972, 77, 5905.
73. S. Beilke, D. Lamb and J. Muller, Atmos. Environ. 1975, 9, 1083.
74. C. Aubuchon, Ph. D. Thesis, 1976, Johns Hopkins University, Baltimore, Md.
75. P. Warneck, J. Ziajka and W. Pasiuk-Bronikowska, Proc. VI European Symp. Varese 18-22 October 1993. Physico-Chemical Behaviour of Atmospheric Pollutants. Ed. G. Angeletti and G. Rastelli. 2, 901.
76. I. Grgić, M. Poznić and M. Bizjak, J. Atmos. Chem. 1999, 33, 89.
77. O. A. Travina, A. Yermakov, Ju. Kozlov, and A. P. Purmal, Kinetics and catalysis, 2003 in press
78. C. J. Weschler, M. L. Mandich and T. E. Graedel, J. Geophys. Res. 1986, 91, 5189.
79. J. Ziajka, W. Pasiuk-Bronikowska and P. Wameck, Proc. Joint EC/EUROTRAC workshop'95, Lactoz-Halipp. Rep. EUR 16766 EN/Ed. Mirabel Ph. BrusselsLuxemburg, 1996, 114.
80. C. Marsh and J. O. Edwards, Prog. React. Kinet. 1989, 15, 35.
81. O. F. Zeck and D. W. Carlyle, Inorg. Chem. 1974, 13, 34.
82. I. V. Zaharov, Kinetics and Catalysis (Rus), 1998, 39, 523.
83. M. Fisher, M. Paydar, P. Warneck and J. Ziajka, Final report No. STEP-OOOS-C(MB), contract coordinator P. Wameck, 1992.
84. T. N. Das, R. E. Huie and P. Neta, J. Phys. Chem. A, 1999, 103, 3581.
85. C. H. Barron and H. A. O'Hern, Chem. Eng. Sci., 1966, 21, 397.
86. H. A. C. McKay, Atmos. Environ. 1971, 5, 7.
87. D. A. Hegg and P. V. Hobbs, Atmos. Environ. 1978, 12, 241.
88. P. Brimblecombe and D. J. Spedding, Chemoshere, 1974, 3, 29.
89. F. F. Prinsloo, Ch. Brandt, V. Lepentsiotis, J. J. Pienaar and R,van Eldik, Inorg. Chem. 1991, 36, 119.
90. I. Grgić, A. Dovžan and G. Berćić, J. Atmos. Chem. 1998, 29, 315.
91. W. Pasiuk-Bronikowska, T. Bronikowskii and M. Ulejczyk, Proc. of EC/UROTRAC - 2, Aachen Germany, 20-22 September 1999. Joint Workshop, Ed. R. Vogt, Gudrin Axelsdroter, 2000, 195.
92. W. L. Chameides and D. D. Davis, J. Geophys. Res., 1982, 87, 4836.
93. B. C. Faust and J. Hoigne, Atmos. Environ. 1990, 24A, 79.
94. H. Hermann, B. Ervens, H. -W. Jacobi, R. Wolke, P. Nowacki and R. Zellner, J. Atmos. Chem., 2000. 36, 231.
95. J. Matthijsen, P. J. H. Builtjes and D. L. Sedlak, Meteor. Atmos. Phys. 1995, 57, 43.
96. M. W. Gery, G. Z. Witten, J. P. Killus and M. C. Dodge,Geophys. Res., 1989, 94, 12925.
97. A. N. Yermakov and A. P. Purmal, Kinetics and Catalysis, 2003, 44 in press
98. S. A. Penkett, B. M. R. Jones, K. A. Bruce and A. E. J. Eggleton, Atmos. Environ. 1979, 13, 123.
99. A. Jr. Huss, P. K. Lim and C. A. Eckert, J. Phys. Chem. 1982, 86, 4233.
100. J. Ziajka and W. Pasiuk-Bronikowska, Proc. of EUROTRAC'Symposium '98, Southhampton 23-27 March 1998. Transport and Chemical Transformation in the Troposhere. Ed. Borell P. M., Borell P., WIT Press 1999, 756.
101. A. N. Yermakov and A. P. Purmal, Kinetics and Catalysis, 2002, 43, 273
102. A. N. Yermakov and A. P. Purmal, Progr. Abstracts. Fifth Intern. Conf. Chem. Kinetics, July 16-20, 2001, NIST, Gaithersburg, MD, USA, 164.
103. A. N. Yermakov, G. A. Poskrebyshev and A. P. Purmal, Atmos. Environ. 1997, 31, 621,
104. A. N. Yermakov, G. A. Poskrebyshev and A. P. Purmal, Prog. React. Kin., 1997, 22, 141.
105. I. Grgić and G. Berćić, J. Atmos. Cliem., 2001, 39, 155,
106. M. Poznic, I. Grgić, G. Benćić, Proc. EUROTRAC Symposium'98, Editors P. M. Borrel and P. Borell, WITPRESS, Southampton, 734.
107. H. Herrmann, H. -W. Jacobi, A. Reese and R. Zellner, Fresenius J. Anal. Chem., 1996, 355, 343.
108. T. N. Das, J. Phys. Chem., 2001, 105, 9142.
109. Ch. M. Flynn, Chem. Rev. 1984, 84, 31.
110. A. G. Clark and M. Radojevic, Atmos. Emir., 1983, 17, 617.
111. A. Matsuura, J. Harada, T. Akehata and T. Shirai, J. Chem. Eng. Jap, 1969, 2, 199.
112. D. Winkelman, Z. Electrochemie, 1955, 59, 891.
113. S. Yagi and H. Inoe, Chem. Eng. Sci., 1962, 17, 411.
114. A. P. Van den Heuvel and B. J. Mason, Quart. J. Roy. Met. Soc., 1963, 89, 271.
115. L. C. Schroeter, J. Pharm. Sci., 1963, 52, 559.
116. S. Tsunogai, Geochemical Jour., 1971, 5, 175.
117. J. L. Hudson, J. Erwin and N. M. Catipovic, Report EPA-600/7-79-030. National Technical Information Service. US Department of Commerce. Springfield. V. A. 1979.
118. R. L. Steel, A. W. Gertler, V. Katz, D. Lamb and D. F. Miller, Atmos. Environ., 1981, 15, 2341.
119. G. C. Mishra and R. D. Srivastava, Chem. Eng. Sci., 1975, 30, 1387.