Radiation-induced autoxidation of bisulfite catalyzed by manganese (II) ions

Atmospheric Environment

Volumn 31, Issue 4, 1997, Pages 621-625

  Yermakov, Aleksander N ^a   Poskrebyshev, Grigoriy A ^a   Purmal, Anatoliy P ^a  

^a SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

Chain oxidation; HSO3 ; Ionizing radiation; Oxidation; Radiation yield

Indexed keywords

BISULFITE; MANGANESE;

AIR POLLUTION; ARTICLE; AUTOOXIDATION; CATALYST; CHEMICAL REACTION KINETICS; PRIORITY JOURNAL;

BISULPHITE; IONIZATION; MANGANESE; OXIDATION; RADIATION; RADIATION YIELD;

CATALYSIS; FREE RADICAL REACTIONS; MANGANESE COMPOUNDS; OXIDATION; REACTION KINETICS;

AUTOOXIDATION; CHAIN REACTIONS; RADIATION YIELD;

RADIATION CHEMISTRY;

EID: 0031060867     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1352-2310(96)00222-1     Document Type: Article

References (21)

1. Berglund J. and Elding L. I. (1992) Metal-ion catalyzed oxidation of S(IV) by oxygen in aqueous solution. Final Report No. STEP-0005-C(MB), contract coordinator P. Warneck.
2. Berglund J., Fronaeous S. and Elding L. I. (1993) Kinetics and mechanism for manganese-catalyzed oxidation of sulfur (IV) by oxygen in aqueous solution, Inorg. Chem. 32, 4527.
3. Berglund J., Elding L. I., Buxton G. V., McGowan S. and Salmon G.A. (1994) Reaction of peroxomonosulfate radical with manganese (II) in acidic aqueous solution. J. chem. Soc. Farad. Trans. 90, 3309.
4. 2 radicals in aqueous solution. J. phys. chem. Ref. Data 14, 1041.
5. Brandt C, Fabian I. and van Eldik R. (1994) Kinetics and mechanism of the iron (III)-catalyzed autoxidation of sulfur (IV) oxides in aqueous solution. Evidence for the redox cycling of iron in the presence of oxygen and modeling of the overall reaction mechanism, Inorg. Chem. 33, 687.
6. Buxton G. V., Greenstock C. L., Helman W. R. and Ross A. B. (1988) Rate constants for reaction of radicals in aqueous solution. J. phys. chem. Ref. Data 17, 513.
7. Buxton G. V., Croft S., McGowan S. and Salmon G. A. (1992) Laboratory studies of the aqueous chemistry of free radicals, transition metals and the formation of acidity in clouds. Final Report No. STEP-0005-C(MB), contract coordinator P. Warneck.
8. 2 radicals. 1. Sulfate, formate, and pyrophosphate complexes. J. phys. Chem. 88, 311
9. Draganich I. and Draganich Z. (1971) Radiation Chemistry of Water. Academic Press, New York.
10. Fisher M., Paydar M., Warneck P. and Ziajka J. (1992) Role of radicals in the oxidation of S(IV) by chain reaction and by transition metal catalysis. Final Report No. STEP-0005-C(MB), contract coordinator P. Warneck.
11. Huie R. E. and Neta P. (1987) Rate constants for some oxidation of S(IV) by radicals in aqueous solution. Atmospheric Environment 21, 1743.
12. Ibusuki T. and Barnes H. M. (1984) Manganese (II) catalyzed sulfur dioxide oxidation in aqueous solution at environmental conditions - I. Atmospheric Environment 18, 145.
13. Ibusuki T. and Takeuchi K. (1987) Sulfur dioxide oxidation by oxygen catalyzed by mixtures of manganese (II) and iron (III) in aqueous solutions at environmental conditions. Atmospheric Environment 21, 1555.
14. Martin L. R. and Good T. W. (1991) Catalyzed oxidation of sulfur dioxide in solution: The iron-manganese synergism. Atmospheric Environment 25a, 2395.
15. Sedlak D. I. and Hoigne J. (1993) The role of copper and oxalate in the redox cycling of iron in atmospheric water. Atmospheric Environment 27a, 2173.
16. Stanbury D. M. (1989) Reduction potentials involving inorganic free radicals in aqueous solution. In Advances in Inorganic Chemistry (edited by Sykes A. G.), Vol. 34, p. 69. Academic Press, New York.
17. Waygood S.J. (1992) A laser flash photolysis study of some reactions metal ions with oxysulfur radicals. Final Report No. STEP-0005-C(MB), contract coordinator P. Warneck.
18. 5 self-reaction. J. phys. Chem. 97, 10,712.
19. 3 oxidation in aqueous solution. Radiat, phys. chem. 43, 281.
20. 2 radicals reactivity in aqueous phase bisulfite oxidation. J. phys. Chem. 99, 3120.
21. Ziajka J., Beer F. and Warneck P. (1994) Iron-catalyzed oxidation of bisulfite aqueous solution: evidence for a free radical chain mechanism. Atmospheric Environment 28, 2549.