CAPRAM2.3: A chemical aqueous phase radical mechanism for tropospheric chemistry

Journal of Atmospheric Chemistry

Volumn 36, Issue 3, 2000, Pages 231-284

  Herrmann, H ^a   Ervens, B ^a   Jacobi, H W ^b,c   Wolke, R ^a   Nowacki, P ^a   Zellner, R ^b  

^a LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

^b UNIVERSITY OF DUISBURG ESSEN   (Germany)

^c ALFRED WEGENER INSTITUTE FOR POLAR AND MARINE RESEARCH   (Germany)

Author keywords

Cloud chemistry; Modelling; Multiphase; Radical chemistry

Indexed keywords

BROMIDE; CARBON; CARBONIC ACID; CHLORIDE; COPPER; FERRIC ION; HYDROGEN PEROXIDE; HYDROXYL RADICAL; MANGANESE; METAL; NITRATE; ORGANIC COMPOUND; OZONE; PEROXIDE; PEROXY RADICAL; RADICAL; SULFUR;

ATMOSPHERIC CHEMISTRY; RADICAL; TROPOSPHERE;

ARTICLE; CHEMICAL REACTION; CLOUD; GAS; LIQUID; OXIDATION; TROPOSPHERE;

EID: 0034120086     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1023/A:1006318622743     Document Type: Article

References (187)

1. Amels, P., Elias, H., Götz, U., Steinges, U., and Wannowius, K. J., 1996: Kinetic investigation of the stability of peroxonitric acid and of its reaction with sulfur(IV) in aqueous solution, in P. Warneck (ed.), Heterogeneous and Liquid Phase Processes, Vol. 2 of Transport and Chemical Transformation in Pollutants in the Troposphere, (P. Borell, P. M. Borrell, T. Cvitǎs, K. Kelly, and W. Seiler, Series Editors), Springer, Berlin, pp. 77-88.
2. Audiffren, N., Renard, M., Buisson, E., and Chaumerliac, N., 1998: Deviations from the Henry's law equilibrium during cloud events: A numerical approach of the mass transfer between phases and its specific numerical effects, Atmos. Res. 49, 139-161.
3. 2+ ions, J. Phys. Chem. 90, 6025-6028.
4. 6, Trans. Faraday Soc. 66, 1509-1519.
5. Barlow, S., Buxton, G. V., Murray, S. A., and Salmon, G. A., 1997: Oxidation of hydroxymethanesulfonate initiated by the hydroxyl radical, in P. M. Borrell, P. Borell, T. Cvitaš, K. Kelly, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Vol. 1, Proceedings of EUROTRAC Symposium '96: Computational Mechanics Publications, Southampton, U.K., pp. 361-365.
6. 2 and OH in aqueous solution, Trans. Faraday Soc. 67, 2532-2537.
7. Beckwith, R. C., Wang, T. X., and Margerum, D. W., 1996: Equilibrium and kinetics of bromine hydrolysis, Inorg. Chem. 35, 995-1000.
8. 2-oxidation in the droplet phase, Atmos. Environ. 12, 231-239.
9. Bell, R. P., 1966: The reversible hydration of carbonyl compounds, Adv. Phys. Org. Chem. 4, 1-29.
10. Bell, R. P. and Evans, P. G., 1966: Kinetics of the dehydration of methylene glycol in aqueous solution, Proc. R. Soc. London A 291, 297-323.
11. Bell, R. P., Rand, M. H., and Wynne-Jones, K. M. A., 1956: Kinetics of the hydration of acetaldehyde, Trans. Faraday Soc. 52, 1093-1102.
12. Benkelberg, H.-J., Schäfer, A., and Warneck, P., 1991: In K.-H. Becker (ed.), Air Pollution Research Report 33: Atmospheric Oxidation Processes, CEC, Brussels, pp. 130-133.
13. 4 quantum yields, J. Phys. Chem. 99, 5214-5221.
14. Berdnikov, V. M., 1973: Catalytic activity of the hydrated copper ion in the decomposition of hydrogen peroxide, Russ. J. Phys. Chem. 47, 1060-1062.
15. Betterton, E. A., 1992: Henry's law constants of soluble and moderately soluble organic gases: Effects on aqueous phase chemistry, in J. O. Nriagu (ed.), Gaseous Pollutants: Characterization and Cycling, Wiley, New York, pp. 1-50.
16. Betterton, E. A. and Hoffmann, M. R., 1988a: Henry's law constants of some environmentally important ldehydes, Environ. Sci. Technol. 22, 1415-1418.
17. 2 by peroxymonosulfate, J. Phys. Chem. 92, 5962-5965.
18. Betterton, E. A., Erel, Y., and Hoffmann, M. R., 1988: Aldehyde-bisulfite adducts: Prediction of some of their thermodynamic and kinetic properties, Environ. Sci. Technol. 22, 92-99.
19. 2 radicals in aqueous solution, J. Phys. Chem. Ref. Data 14, 1041-1100.
20. Bongartz, A., Schweighoefer, S., Roose, C., and Schurath, U., 1995: The mass accommodation coefficient of ammonia on water, J. Atm. Chem. 20, 35-58.
21. Bothe, E., Schuchmann, M. N., Schulte-Frohlinde, D., and von Sonntag, C., 1983: Hydroxyl radical-induced oxidation of ethanol in oxygenated aqueous solutions. A pulse radiolysis and product study, Z. Naturforsch. 38b, 212-219.
22. Brandt, C. and van Eldik, R., 1995: Transition metal-catalyzed oxidation of sulfur(IV) oxides. Atmospheric relevant processes and mechanisms, Chem. Rev. 95, 119-190.
23. Buxton, G. V., 1994: Mechanisms for chemical reactions in cloud droplets, in P. M. Borrell, P. Borrell, T. Cvitaš, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Proceedings of EUROTRAC Symposium '94: SPB Academic Publishing, The Hague, The Netherlands, pp. 978-983.
24. 2) in aqueous solution, J. Phys. Chem. Ref. Data 17, 513-886.
25. 2 in aqueous solution up to 200°C. A pulse radiolytic study, J. Chem. Soc. Faraday Trans. 84, 1113-1121.
26. Buxton, G. V., Salmon, G. A., and Wood, N. D., 1990: A pulse radiolysis study of the chemistry of oxysulfur radicals in aqueous solution, in G. restelli and G. Angeletti (eds), Proceedings of the Fifth European Symposium: Physico-Chemical Behaviour of Atmospheric Pullulants, Kluwer, Dordrecht, pp. 245-250.
27. Boxton, G. V., McGowan, S., Salmon, G. A., Williams, J. E., and Wood, N. D., 1996a: A study of the spectra and reactivity of oxysulphur-radical anions involved in the chain oxidation of S (IV): A pulse and gamma-radiolysis study, Atmos. Environ. 30, 2483-2493.
28. 2, J. Chem. Soc. Faraday Trans. 92, 1287-1289.
29. + in aqueous solution, J. Chem. Soc. Faraday Trans. 93(16), 2893-2897.
30. 2-radicals, a pulse radiolytic study, J. Am. Chem. Soc. 109, 3665-3669.
31. Chameides, W. L., 1984: The photochemistry of a Remote Marine Straaatiform Cloud, J. Geophys. Res. 89, 4739-4755.
32. 4, J. Phys. Chem. 79, 2693-2700.
33. Chin, M. and Wine, P. H., 1994: A temperature-dependent competitive kinetics study of the aqueousphase reactions of OH radicals with formate, formic acid, acetate, acetic acid and hydrated formaldehyde, in G. R. Helz, R. G. Zepp, and D. G. Crosby (eds), Aquatic and Surface Photochemistry, Lewis Publishers, Boca Raton, pp. 85-96.
34. Christensen, H. and Sehested, K., 1981: Pulse radiolysis at high temperatures and high pressures, Radiat. Phys. Chem. 18, 723-231.
35. Christensen, H., Sehested, K., and Corfitzen, H., 1982: Reactions of hydroxyl radicals with hydrogen peroxide at ambient and elevated temperatures, J. Phys. Chem. 86, 1588-1590.
36. 2), Water Chem. Nucl. React. Syst. 5, 141-144.
37. Clegg, S. L. and Brimblecombe, P., 1990: Solubility of volatile electolytes in multicomponent solutions with atmospheric applications, ACS Symposium Series 416, 58-73.
38. 4 alcohols, Int. J. Chem. Kinet. 21, 677-687.
39. Cope, V. W., Hoffman, M. Z., and Chen, S., 1978: Reactivity of the carbonate radical toward metal complexes in aqueous solution, J. Phys. Chem. 82, 2665-2669.
40. 2, Atmos. Environ. 17, 2005-2011.
41. Davidovits, M., Hu, J. H., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E., 1995: Entry of gas molecules into liquids, Faraday Discuss. 100, 65-82.
42. Davies, G., Kirschenbaum, L. J., and Kustin, K., 1968: The kinetics and stoichometry of the reaction between manganese(III) and hydrogen peroxide in acid perchlorate solution, Inorg. Chem. 7, 146-154.
43. 3 in aqueous solution, J. Phys. Chem. 94, 2191-2198.
44. 3 and OH, J. Geophys. Res. 98, 7149-7163.
45. Diebler, H. and Sutin, N., 1964: The kinetics of some oxidation-reduction reactions involving manganese(III), J. Phys. Chem. 68, 174-180.
46. Draganic, Z. D., Negron-Mendoza, A., Sehested, K., Vujosevic, S. I., Navarro-Gonzales, R., Albarran-Sanchez, M. G., and Draganic, I. G., 1991: Radiolysis of aqueous solution of ammonium bicarbonate over a large dose range, Radiat. Phys. Chem. 38, 317-321.
47. aq in aqueous solution, Radiat. Phys. Chem. 34, 753-758.
48. 2 in water up to 200°C, J. Chem. Soc. Faraday Trans. 88, 2465-2470.
49. - reactions and equilibria: A pulse radiolytic study, Radiat. Phys. Chem. 33, 69-74.
50. Elliot, A. J. and Simsons, A. S., 1984: Rate constants for reactions of hydroxyl radicals as a function of temperature, Radiat. Phys. Chem. 24, 229-231.
51. Eriksen, T. E., Lind, J., and Merenyi, G., 1985: On the acid-base equilibrium of the carbonate radical, Radiat. Phys. Chem., 26, 197-199.
52. Exner, M., 1990: Diploma Thesis, Bildung und Reaktionen von Radikalen und Radikalanionen in wäßriger Phase, Georg-August-University Göttingen.
53. 3-Radikals in wäßriger Lösung, Georg-August-University Göttingen.
54. 2 in aqueous solution, in K. H. Becker (ed.), Air Pollution Research Report 33: Atmospheric Oxidation Processes, Office for official Publications of the European Communities, Luxembourg, pp. 134-138.
55. Exner, M., Herrmann, H., and Zellner, R., 1992: Laser-based studies of reactions of the nitrate radical in aqueous solution, Ber. Bunsenges. Phys. Chem. 96, 470-477.
56. 3 reactions with S(IV) and organic compounds in aqueous solutions, in P. M. Borrell, P. Borrell, T. Cvitaš, and W. Seiler (eds), Photo-oxidants: Precursors and Products, Proceedings of EUROTRAC Symposium '92, SPB Academic Publishing, The Hague, The Netherlands, pp. 615-618.
57. - in aqueous solution between 278 and 328 K, J. Atmos. Chem. 18, 359-378.
58. Fisher, M. M. and Hamill, W. H., 1973: Electronic processes in pulse-irradiated aqueous and alcoholic systems, J. Phys. Chem. 77, 171-177.
59. Fornier de Violet, Ph., 1981: Polyhalide anions as intermediates in chemistry, Rev. Chem. Intermed. 4, 121-169.
60. Fuller, E. N., Diffusion coefficients for binary gas systems at low pressures: Empirical correlations, in C. Reid et al. (eds), Properties of Gases and Liquids, Mc Graw Hill, New York, p. 587.
61. 2(g) on water droplets, J. Geophys. Res. 92, 10887-10895.
62. 5 by water and NaCl solutions, J. Phys. Chem. 98, 8780-8784.
63. Gilbert, B. C., Larkin, J. P., and Norman, R. O. C., 1972: Electron spin resonance studies, part XXXIV. The use of the aci-anion from nitromethane as a spin trap for organic radicals in aqueous solution, J. Chem. soc. Perkin Trans. II, 1272-1279.
64. Goldstein, S., Czapski, G., Cohen, H., and Meyerstein, D., 1992: Deamination of β-alanine induced by hydroxyl radicals and monovalent copper ions. A pulse radiolytic study, Inorg. Chim. Acta 192, 87-93.
65. Graedel, T. E. and Weschler, C. J., 1981: Chemistry within aqueous atmospheric aerosols and raindrops, Rev. Geophys. Space Phys. 19, 505-539.
66. Graedel, T. E., Mandich, M. L., and Weschler, C. J., 1986: Kinetic model studies of atmospheric droplet chemistry 2. Homogeneous transition metal chemistry in raindrops, J. Geophys. Res. 91, 5205-5221.
67. 2 in the bulk solution during the radiolysis of concentrated aqueous solutions of chlorides, High Energy Chem. 21, 99-102.
68. 2 radical uptake coefficients on water and sulfuric acid surfaces, J. Phys. Chem. 96, 4979.
69. Harned, H. S. and Owen, B. B., 1958: The Physical Chemistry of Electrolytic Solutions, 3rd edn, Reinhold, New York.
70. Hart, E. J., Thomas, J. K., and Gordon, S., 1964: A review of the radiation chemistry of single-carbon compounds and some reactions of the hydrated electron in aqueous solution, Radiat. Res. Suppl. 4, 74-88.
71. Hemmes, P., Rich, L. D., Cole, D. L., and Eyring, E. M., 1971: Kinetics of hydrolysis of ferric ion in dilute aqueous solution, J. Phys. Chem. 75, 929-932.
72. 3) with inorganic and organic cloudwater constituents, Geochim. Cosmochim. Acta 58, 3239-3244.
73. x (x = 3, 4, 5) radical anions in aqueous solution, J. Mol. Struct. 348, 183-186.
74. Herrmann, H., Jacobi, H.-W., Raabe, G., Reese, A., and Zellner, R., 1996: Laser-spectrocopic laborabory studies of atmospheric aqueous phase free radical chemistry, Fresenius J. Anal. Chem. 355, 343-344.
75. 4, in P. M. Borrell, T. Cvitaš, K. Kelly, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Vol. 1, Proceedings of EUROTRAC Symposium '96, Computational Mechanics Publications, Southampton, U.K., pp. 407-411.
76. 3 radicals in aqueous solution, in Z. B. Alfassi, N-Centered Radicals, John Wiley and Sons Ltd.
77. Herrmann, H., Ervens, B., Nowacki, P., Wolke, R., and Zellner, R., 1999a: A chemical aqueous phase radical mechanism for tropospheric chemistry, Chemosphere 38, 1223-1232.
78. Herrmann, H., Reese, A., Ervens, B., Wicktor, F., and Zellner, R., 199b: Laboratory and modelling studies of tropospheric multiphase conversions involving some C1 and C2 peroxyl radicals, Phys. Chem. Earth 24, 287-290.
79. Hindmarsh, A. C., 1980: LSODE and LSODI, two initial value ordinary differential equation solver, ACM-SIGNUM Newsl. 15, 10-11.
80. Hoffmann, M. R., 1986: On the kinetics and mechanism of oxidation of aquated sulfur dioxide by ozone, Atmos. Environ. 20, 1145-1154.
81. Hoigné, J., Bader, H., Haag, W. R., and Staehelin, J., 1985: Rate constants of reactions of ozone with organic and inorganic compounds in water-III inorganic compounds and radicals, Water Res. 19, 993-1004.
82. Holdren, M. W., Spicer, C. W., and Hales, J. M., 1984: Peroxyacetyl nitrate solubility and decomposition rate in acidic water, Atmos. Environ. 18, 1171-1173.
83. 4, with anions, J. Phys. Chem. 94, 8561-8567.
84. Huie, R. E., Shoute, L. C. T., and Neta, P., 1991a: Temperature dependence of the rate constants for reactions of the carbonate with organic and inorganic reductants, Int. J. Chem. Kin. 23, 541-542.
85. Huie, R. E., Clifton, C. L., and Neta, P., 1991b: Electron transfer reaction rates and equilibria of the carbonate and sulfate radical anions, Radiat. Phys. Chem. 38, 477-481.
86. Jacob, D. J., 1986: Chemistry of OH in remote clouds and its role in the production of formic acid and peroxymonosulfate, J. Geophys. Res., 91, 9807-9826.
87. Jacob, D. J., Gottlieb, E. W., and Prather, M. J., 1989: Chemistry of a polluted cloud boundary layer, J. Geophys. Res. 94, 12975-13002.
88. Jacobi, H.-W., 1996: Kinetische Untersuchungen und Modellrechnungen zur troposphärischen Chemie von Radikalanionen und Ozon in wäßriger Phase, PhD Thesis, University-GH-Essen, Germany.
89. 2 radical in the aqueous phase, in Ph. Mirabel (ed.), Air Pollution Research Report 57: Homogenous and Heterogenous Chemical Processes in the Troposphere, Office for Official Publications of the European Communities, Luxembourg, pp. 172-176.
90. 2-radical anions in aqueous solution at 298 K, Ber. Bunsenges. Phys. Chem. 101, 1909-1913.
91. 2-radical anion with oxygenated hydrocarbons in aqueous solution, Int. J. Chem. Kin. 31, 169-181.
92. Jayson, G. G., Parson, B. J., and Swallow, A. J., 1973a: Same simple, highly reactive, inorganic chlorine derivatives in aqueous solution, J. Chem. Soc. Faraday Trans. 69, 1597-1607.
93. Jayson, G. G., Parson, B. J., and Swallow, A. J., 1973b, Oxidation of ferrous ions by per hydroxyl radicals, J. Chem. Soc. Faraday Trans. 69, 236-242.
94. Jiang, P.-Y., Katsumura, Y., Nagaishi, R., Domae, M., Ishikawa, K., Ishigure, K., and Yoshida, Y., 1992: Pulse radiolysis study of concentrated sulfuric acid solutions, Chem. Soc. Faraday Trans. 88, 1653-1658.
95. Khan, I. and Brimblecombe, P., 1992: Henry's law constants of low molecular weight (< 130) organic acids, J. Aerosol Sci. 23 (Suppl. 1), S897-S900.
96. Kirchner, W., Welter, F., Bongartz, A., Kames, J., Schweighoefer, S., and Schurath, U., 1990: Trace gas exchange at the air/water interface: Measurements of mass accommodation coefficients, J. Atmos. Chem. 10, 427-449.
97. - in aqueous solution, reactions of Cl- and Br-atoms, Ber. Bunsenges. Phys. Chem. 89, 243-245.
98. 2, J. Phys. Chem. 89, 760-763.
99. Kok, G. L., Gitlin, S. N., and Lazrus, A. L., 1986: Kinetics of the formation and decomposition of hydroxymethanesulfonate, J. Geophys. Res. 91, 2801-2804.
100. Kosak-Channing, L. E. and Helz, G. R., 1983: Solubility of ozone in aqueous solutions of 0-0.6 M Ionic Strength at 5-30°C, Environ. Sci. Technol. 17, 145-149.
101. Kozlov, Y. N. and Berdnikov, V. M., 1973: Photodecomposition of hydogen peroxide in the presence of copper ions. IV. Determinations of rate constants of elementary reactions, Russ. J. Phys. Chem. 47, 338-340.
102. 3 radical anions, High Energy Chem. 6, 338-339.
103. Lammel, G., Perner, D., and Warneck, P., 1990: Decomposition of pernitric acid in aqueous solution, J. Phys. Chem. 94, 6141-6144.
104. Laurence, G. S. and Thornton, A. T., 1973: Kinetics of oxidation of transition-metal ions by halogen radical anions. Part III, the oxidation of manganese(II) by dibromide and dichloride ions generated by flash photolysis, J. Chem. Soc. Dalton Trans., 1637-1644.
105. Leibrock, E. and Slemr, J., 1996: Determination of oxygenated hydrocarbons in air by GC/MS, in P. M. Borrell, P. Borrell, Y. Cvitaš, K. Kelly, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Vol. 1, Proceedings of EUROTRAC Symposium '96, Computational Mechanics Publications, Southampton, U.K., pp. 377-381.
106. Lelieveld, J. and Crutzen, P. J., 1990: Influences of cloud photochemical processes on tropospheric ozone, Nature, 343, 227-233.
107. Lelieveld, J. and Crutzen, P. J., 1991: The role of clouds in tropospheric photochemistry, J. Atmos. Chem. 12, 229-268.
108. Lind, J. A., Lazrus, A. L., and Kok, G. L., 1987, Aqueous phase oxidation of sulfur(IV) by hydrogen peroxide, methylhydroperoxide and peroxyacetic acid, J. Geophys. Res. 92, 4171-4177.
109. Lind, J. A. and Kok, G. L., 1994: Correction to 'Henry's law determinations for aqueous solutions of hydrogen peroxide, methylhydroperoxide and peroxyacetic acid', J. Geophys. Res. 99, 21119.
110. 3, Radiat. Phys. Chem. 41, 539-543.
111. Loomis, A. G., 1928: International Critical Tables Vol. III: Solubilities of Gases in Water, McGraw-Hill, New York, pp. 255-261.
112. Mackay, D. and Shiu, W. Y., 1981: A critical review of Henry's law constants for chemicals of environmental interest, J. Phys. Chem. Ref. Data 10, 1175-1199.
113. Marsh, A. R. W. and McElroy, W. J., 1985: The dissociation constant and Henry's law constant of HCl in aqueous solution, Atmos. Environ. 19, 1075-1080.
114. Maruthamuthu, P. and Neta, P., 1977: Radiolytic chain decomposition of peroxomonophosphoric and peroxomonosulphuric acids, J. Phys. Chem. 81, 937-940.
115. Matthijsen, J., Builtjes, P. J. H., and Sedlak, D. H., 1995: Cloud model experiments of the effect of iron and copper on tropospheric ozone under marine and continental conditions, Meteorol. Atmos. Phys. 57, 43-60.
116. 2+, J. Chem. Soc. Faraday Trans. 86, 2557-2564.
117. McElroy, W. J., 1997: The interactions of gases with aqueous aerosol particles, central Electr. Gen. Board, Part IV.
118. Merényi G. and Lind, J., 1994: Reaction mechanism of hydrogen abstraction by the bromine atom in water, J. Am. Chem. Soc. 116, 7872-7876.
119. Mirabel, P., 1996: Investigations of the uptake rate of some atmospheric trace gases, RINOXA Final Report.
120. Möller, D. and Mauersberger, G., 1992: Cloud chemistry effects on tropospheric photo-oxidants in polluted atmosphere - model results, J. Atmos. Chem. 14, 153-165.
121. Möller, D. and Mauersberger, G., 1995: Aqueous phase chemical reaction system used in cloud chemistry modelling, in A. Flossmann, T. Cvitaš, D. Möller, and G. Mauersberger (eds), Clouds: Models and Mechanisms, ISS, Garmisch-Partenkirchen, Germany, pp. 77-93.
122. National Bureau of Standards, 1971: JANAF thermodynamic tables, 2nd edn, NSDRS-NBS 37, U.S. Dept. of Commerce, Washington, D.C.
123. 3 radicals in aqueous solution, J. Phys. Chem. 90, 4644-4648.
124. Norman, R. O. C., Storey, P. M., and West, P. R., 1970: Electron spin resonance studies. Part XXV Reactions of the sulphate radical anion with organic compounds, J. Chem. Soc. B., 1087-1095.
125. Nowacki, P., 1998: Modeling of size-resolved multi-phase chemical processes in clouds under polluted atmospheric conditions, PhD Thesis in preparation, BTU Cottbus.
126. Olson, T. M. and Hoffmann, M. R., 1989: Hydroxyalkylsulfonate formation: Its role as a S(IV) reservoir in atmospheric water droplets, Atmos. Environ. 23, 985-997.
127. O'Sullivan, D. W., Lee, M., Noone, B. C., and Heikes, B. G., 1996: Henry's law constant determinations for hydrogen peroxide, ethyl hydroperoxide and peroxyacetic acid, J. Phys. Chem. 100, 3241-3247.
128. Park, J.-Y. and Lee, Y. N., 1988: Solubility and decomposition kinetics of nitrous acid in aqueous solution, J. Phys. Chem. 92, 6294-6302.
129. 2 solutions, J. Phys. Chem. 80, 1840-1843.
130. + ions in aqueous solutions: A pulse radiolysis study for atmospheric chemistry, Ber. Bunsenges. Phys. Chem. 97, 762-771.
131. Pikaev, A. K., Sibirskaya, G. K., Shirshov, E. M., Glazunov, P. Y., and Spitsyn, V. I., 1974: Pulsed radiolysis of concentrated aqueous solutions of nitric acid, Dokl. Phys. Chem., Proc. Acad. Sci. U.S.S.R., 215, 328-331.
132. 2, J. Atmos. Chem. 16, 1-21.
133. 3-Radikals in wäßriger Lösung, Cuvillier, Göttingen, Germany.
134. Rafi, A. and Sutton, H. C., 1965 : Radiolysis of aerted solutions of potassium bromide, Trans. Faraday Soc. 61, 877-890.
135. Redlich, O., 1946: The dissociation of strong electrolytes, Chem. Rev. 39, 333-356.
136. Redlich, O. and Hood, G. C., 1957: Ionic interaction, dissociation and molecular structure, Faraday Discuss. 24, 87-93.
137. x(x =3, 4, 5) in wäßriger Lösung, University Essen, Germany.
138. Reese, A., 1997: PhD Thesis, UV/VIS-spektrometrische und kinetische Untersuchungen von Radikalen und Radikalanionen in wäßriger Lösung, University Essen, Germany.
139. 2) in aqueous solution, in P. M. Borrell, P. Borrell, T. Cvitaš, K. Kelly, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Vol. 1, Proceedings of EUROTRAC Symposium '96, Computational Mechanics Publications, Southhampton, U.K., pp. 377-381.
140. 2 radical in aqueous solution, in P. M. Borrell and P. Borrell (eds), Proceedings of the EUROTRAC-2 '98 Symposium, WIT Press, Southampton, pp. 714-718.
141. Rettich, T. R., 1978: Some photochemical reactions of aqueous nitric acid, Diss. Abstr. Int. B 38, 5968.
142. Röth, E.-P., 1992: A fast algorithm to calculate the photonflux in optically dense media for use in photochemical models, Ber. Bunsenges. Phys. Chem. 96, 417-420.
143. 2 mixing ratios measured between 30°N and 30°S in the Atlantic region, J. Atmos. Chem. 15, 253-267.
144. 3 on pure water and ionic solutions, J. Geophys. Res. 101, 21023-21031.
145. Ruggaber, A., Dlugi, R., Bott, A., Forkel, R., Herrmann, H., and Jacobi, H.-W., 1997: Modelling of radiation quantities and photolysis frequencies in the aqueous phase in the troposhere, Atmos. Environ. 31, 3137-3150.
146. 2 with ferric ions and its implication on the occurrence of the Haber-Weiss-reaction 89, 5062-5066.
147. Sander, R. and Crutzen, P. J., 1996: Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res. 101, 9121-9138.
148. Saxena, P. and Hildemann, L. M., 1996: Water-soluble organics in atmospheric particles: A critical review of the literature and application of thermodynamics to identify candidate compounds, J. Atmos. Chem. 24, 57-109.
149. Schuchmann, M. N. and von Sonntag, C., 1988: The rapid hydration of the acetyl radical. A pulse radiolysis study of acetaldehyde in aqueous solution, J. Am. Soc. 110, 5698-5701.
150. Schwartz, S. E., 1986: Mass transport considerations pertinent to aqueous phase reactions of gases in liquid water clouds, in W. Jaeschke (ed.), Chemistry of Multiphase Atmospheric Systems, NATO ASI Series, Vol. 6, Springer, Berlin, pp. 415-471.
151. Schwartz, S. E. and White, W. H., 1983: Kinetics of reactive dissolution of nitrogen oxides into aqueous solution, Adv. Environ. Sci. Technol. 12, 1-115.
152. 2 and I atom reduction potentials, J. Phys. Chem. 90, 1445-1448.
153. Schweitzer, F., Magi, L., George, C., and Mirabel, P., 1998: Uptake rate measurements of methanesulfonic acid and glyoxal by aqueous droplets, J. Phys. Chem. 102, 593-600.
154. Sedlak, D. L. and Hoigné, J., 1993: The role of copper and oxalate in the redox cycling of iron in atmospheric waters, Atmos. Environ. 27A, 2173-2185.
155. Sehested, K., Holcman, J., and Hart, T. J., 1983: J. Phys. Chem. 87, 1951-1954.
156. 3 radical in aqueous solution, in P. M. Borrell, P. Borrell, T. Cvitaš, and W. Seiler (eds), Transport and Transformation of Pollutants in the Troposphere, Proceedings of EUROTRAC Symposium '94, SPB Academic Publishing, The Hague, The Netherlands, pp. 999-1004.
157. Shoute, L. C. T., Alfassi, Z. B., Neta, P., and Huie, R. E., 1991: Temperature Dependence of the rate constants for reaction of dihalide and azide radicals with inorganic reductances, J. Phys. Chem. 95, 3238-3242.
158. Sirs, J. A., 1958, Electronic stopped flow measurements of rapid reactions in solution. Part 2. Glass electrode pH measurements, Trans. Faraday Soc. 54, 207-212.
159. von Sonntag, C., 1987: The Chemical Basis of Radiation Biology, Taylor & Francis.
160. Stanbury, D. M., 1989, Reduction potentials involving inorganic free radicals in aqueous solution, Adv. Inorg. Chem. 33, 69-138.
161. Stockwell, W. R., Middleton, P., Chang, J. S., and Tang, X., 1990: The second generation regional acid deposition model. Chemical mechanism for regional air quality modeling, J. Geophys. Res. 95, 16343-16367.
162. Stockwell, W. R., Kirchner, F., Kuhn, M., and Seefeld, S., 1997: A new mechanism for regional atmospheric chemistry modeling, J. Geophys. Res. 102 (D22), 25847-25879.
163. 4 radical in aqueous solution, J. Photochem. Photobiol. A 44, 243-258.
164. Thomas, J. K., 1965: Rates of reaction of the hydroxyl radical, Trans. Faraday Soc. 61, 702-707.
165. 3 radicals with aqueous solutions: Solubility and sticking coefficient, J. Atmos. Chem. 29, 17-43.
166. Thornton, A. T. and Laurence, G. S., 1973: Kinetics of oxidation of transition-metal ions by halogen radical anions. I. The oxidation of iron(II) by dibromide and dichloride ions generated by flash photolysis, J. Chem. Soc. Dalton Trans., 804-813.
167. Wagner, I. and Strehlow, H., 1987: On the flash photolysis of bromide ions in aqueous solution, Ber. Bunsenges. Phys. Chem. 91, 1317-1321.
168. Wagner, I., Strehlow, H., and Busse, G., 1980: Flash photolysis of nitrate ions in aqueous solution, Z. Phys. Chem 123, 1-33.
169. Walling, C. and Goosen, A., 1973: Mechanism of the ferric ion catalyzed decomposition of hydrogen peroxide. Effect of organic substrates, J. Am. Chem. Soc. 95(9), 2987-2991.
170. Walling, C., 1975: Fenton's reagent revisited, Acc. Chem. Res. 8, 125-131.
171. Walcek, C. J., Yuan, H. H., and Stockwell, W. R., 1997: The influence of aqueous-phase chemical reactions on ozone formation in polluted and nonpolluted clouds, Atmos. Environ. 31(8), 1221-1237.
172. Wang, T. X. and Margerum, D. W., 1994: Kinetics of reversible chlorine hydrolysis: Temperature dependence and general-acid/base-assisted mechanisms, Inorg. Chem. 33, 1050-1055.
173. Warneck, P. (ed)., 1996: Heterogeneous and Liquid-Phase Processes, Springer Verlag, Berlin, Germany.
174. 3 in aqueous solution, J. Phys. Chem. 92, 6278-6283.
175. 2 production and destruction, Environ. Sci. Technol. 25, 791-800.
176. Welch, M. J., Lifton, J. F., and Seek, J. A., 1969: Tracer studies with radioactive Oxygen-15. Exchange between carbon dioxide and water, J. Phys. Chem. 73, 3351-3356.
177. Weschler, C. J., Mandich, M. L., and Graedel, T. E., 1986: Speciation, photosensitivity and reactions of transition metal ions in atmospheric droplets, J. Geophys. Res. 91, 5189-5204.
178. 2-Radikalanions in wäßriger Lösung, GDCh Umwelt und Chemie, Umwelttagung 1996.
179. Wilhelm, E., Battino, R., and Wilcock, R. J., 1977: Low-pressure solubility of gases in liquid water, Chem. Rev. 77, 219-262.
180. Wolke, R. and Knoth, O., 1966: Numerical solution of air pollution models: Aqueous chemistry, Zeitschrift für Angewandte Mathematik und Mechanik, Special Issues: ICIAM95, Issue 5: Applied Sciences, especially Mechanics, 551-552.
181. Zehavi, D. and Rabani, J., 1972: The oxidation of aqueous bromide ions by hydroxyl radicals. A pulse radiolysis investigation, J. Phys. Chem. 76, 312-319.
182. 2 at 308 and 351 nm in the temperature range of 278-353 K, J. Atmos. Chem. 10, 411-425.
183. Zellner, R., Herrmann, H., Exner, M., Jacobi, H.-W., Raabe, G., and Reese, A., 1994: Bildung und Reaktionen von Oxidantien in flüssiger Phase, Final Report, University-GH-Essen, Förderkennzeichen FK 07EU7801.
184. Zellner, R. and Herrmann, H., 1995: Free radical chemistry of the aqueous atmospheric phase, in R. J. H. Clark and R. E. Hester (eds), Advances in Spectroscopy, Spectroscopy in Environmental Science, Wiley, London, Vol. 3, pp. 381-4-51.
185. Zellner, R., Herrmann, H., Exner, M., Jacobi, H.-W., Raabe, G., and Reese, A., 1996: Formation and Reactions of Oxidants in the Aqueous Phase, in P. Warneck (ed.), Heterogeneous and Liquid Phase Processes, Springer, Berlin, pp. 146-152.
186. Ziajka, J., Beer, F., and Warneck, P., 1994: Iron-catalysed oxidation of bisulphite aqueous solution: Evidence for a free radical chain mechanism, Atmos. Environ. 28, 2549-2552.
187. Zimmermann, J. and Poppe, D., 1996: A supplement for the RADM2 chemical mechanism: The photooxidation of isoprene, Atmos. Environ. 30, 1255-1269.