High kinetic resolution in the addition of a racemic allenylzinc onto enantiopure N-tert-butanesulfinimines: Concise synthesis of enantiopure trans-2-ethynylaziridines

Journal of Organic Chemistry

Volumn 69, Issue 24, 2004, Pages 8244-8250

  Chemla, Fabrice ^a   Ferreira, Franck ^a  

^a SORBONNE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHELATION; CONDENSATION; NITROGEN; PHASE TRANSITIONS; REACTION KINETICS; STEREOCHEMISTRY; ZINC;

ALLENYLZINC SPECIES; AZIRIDINES; IMINE; KINETIC RESOLUTION;

ORGANIC COMPOUNDS;

2 ETHYNYLAZIRIDINE; 3 CHLORO 1 TRIMETHYLSILYLPROPYNE; AZIRIDINE DERIVATIVE; BUTANE; HYDROCHLORIC ACID; N TERT BUTANESULFINIMINE; NITROGEN; OXYGEN; SILANE DERIVATIVE; UNCLASSIFIED DRUG; ZINC; ZINC DERIVATIVE;

ARTICLE; ATOM; CHELATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENANTIOMER; POLYMERIZATION; STEREOCHEMISTRY; SYNTHESIS;

ALKADIENES; AZIRIDINES; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; ZINC;

EID: 9344259155     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0490696     Document Type: Article

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