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Volumn 10, Issue 22, 2004, Pages 5737-5750

Readily prepared metallo-supramolecular triple helicates designed to exhibit spin-crossover behaviour

Author keywords

Helical structures; N ligands; Noncovalent interactions; Spin crossover; Supramolecular chemistry

Indexed keywords

COMPLEXATION; HYDROGEN BONDS; NEGATIVE IONS; SWITCHING; SYNTHESIS (CHEMICAL);

EID: 9244231758     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400518     Document Type: Article
Times cited : (86)

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    • note
    • While distance alone does not give an accurate picture of hydrogen-bonding interactions, it is used here to qualitatively assess the extent of N-H⋯X interactions. Interaction distances up to 3.0 Å are listed, but are not intended to imply strong hydrogen bonds at such distances.
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    • note
    • One of the tetrafluoroborate anions is disordered over two positions, but makes the short bridging contacts in both of these positions. In the second orientation this tetrafluoroborate uses one fluorine atom to make one hydrogen bond to one helix and this fluorine atom and an additional one to make a pair of hydrogen bonds to an NH of the adjacent helix. The F⋯HN distances to the additional position are 2.13 Å for the single hydrogen bond and 2.08 and 2.60 Å for the pair. For clarity this additional position is not shown in the diagram.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.