Cis double addition of CO2 to a coordinated arene of a thorium complex

Organometallics

Volumn 23, Issue 23, 2004, Pages 5379-5381

  Korobkov, Ilia ^a   Gambarotta, Sandro ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BONDING; COMPLEXATION; DISSOCIATION; MATHEMATICAL TRANSFORMATIONS; OXIDATION; SYNTHESIS (CHEMICAL); THORIUM;

BACK-BONDING INTERACTIONS; CHARGE-TRANSFER INTERACTIONS; LIGANDS; LOW-VALENT STATES;

CARBON DIOXIDE;

EID: 9144235599     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049470i     Document Type: Article

References (31)

1. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
2. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
3. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
4. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
5. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
6. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
7. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
8. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
9. See for example: (a) Avens, L. R.; Barnhardt, D. M.; Burns, C. J.; McKee, S. D. Inorg. Chem. 1996, 35, 537. (b) Castro-Rodriguez, I.; Olsen, K.; Gantzel, P.; Meyer, K. Chem. Commun. 2002, 23, 2764. (c) Castro-Rodriguez, I.; Nakai, H.; Gantzel, P.; Zakharov, L. N.; Rheingold, A. L.; Meyer, K. J. Am. Chem. Soc. 2003, 125, 15734. (d) Roussel, P.; Scott, P. J. Am. Chem. Soc. 1998, 120, 1070. (e) Evans, W. J.; Ulibarri, T. A.; Ziller, J. W. J. Am. Chem. Soc. 1988, 110, 6877. (f) Mindiola, D. J.; Tsai, Y. C.; Hara, R.; Chen, Q.; Meyer, K.; Cummins, C. C. Chem. Commun. 2001, 1, 125. (g) Cloke, F. G. N.; Hitchcock, P. B. J. Am. Chem. Soc. 2002, 124, 9352. (h) Evans, W. J.; Kozimor, S. A., Ziller, J. W. J. Am. Chem. Soc. 2003, 125, 14264. (i) Korobkov, I.;, Gambarotta, S.; Yap, G. P. A. Organometallics 2001, 20, 2552. (j) Korobkov, I.; Gambarotta, S.; Yap, G. P. A. Angew. Chem., Int. Ed. 2002, 41, 3433.
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30. 2 DME, 72.87; quaternary C, 156.92, 153.54, 136.97, 105.58, 47.60.
31. -1, F(000) = 2624, 41 513 reflections collected, 7075 independent reflections, GOF = 1.112, R1 = 0.0791, wR2 = 0.1824.