Guest sorption and desorption in the metal-organic framework [Co(INA) 2] (INA=isonicotinate) - Evidence of intermediate phases during desorption

Dalton Transactions

Volumn , Issue 12, 2004, Pages 1807-1811

  Wei, Qiang ^a   Nieuwenhuyzen, Mark ^a   Meunier, Frederick ^a   Hardacre, Chris ^a   James, Stuart L ^a  

^a QUEEN'S UNIVERSITY BELFAST   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; COBALT COMPOUNDS; CRYSTAL STRUCTURE; DESORPTION; DIFFRACTION; ETHANOL; HEATING; IRON COMPOUNDS; SYNTHESIS (CHEMICAL); VAN DER WAALS FORCES; X RAY CRYSTALLOGRAPHY;

DESOLVATED MATERIALS; GUEST SORPTION AND DESORPTION; METAL-ORGANIC FRAMEWORKS (MOF); X-RAY CRYSTAL STRUCTURES;

ORGANOMETALLICS;

EID: 8844234430     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b404485a     Document Type: Article

References (33)

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20. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
21. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
22. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
23. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
24. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
25. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
26. Examples of MOFs that reversibly desorb guest molecules with retention of single-crystallinity in addition to those in ref. 2: (a) M. P. Suh, J. W. Ko and H. J. Choi, J. Am. Chem. Soc., 2002, 124, 10976; (b) G. J. Halder, C. J. Kepert, B. Moubaraki, K. S. Murray and J. D. Cashion, Science, 2002, 298, 1762; (c) S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 2002, 124, 2568; (d) J. Y. Lu and A. M. Babb, Chem. Commun., 2002, 1340; (e) D. V. Soldatov, E. V. Grachev and J. A. Ripmeester, Cryst. Growth Des., 2002, 2, 401; (f) T. K. Maji, P. S. Mukherjee, G. Mostafa, E. Zangrando and N. R. Chaudhuri, Chem. Commun., 2001, 1368; (g) Y. H. Liu, H. L. Tsai, Y. L. Lu, Y. S. Wen, J. C. Wang and K. L. Li, Inorg. Chem., 2001, 40, 6426; (h) H. Li, M. Eddaoudi, M. O'keeffe and O. M. Yaghi, Nature, 1999, 402, 276; (i) C. J. Kepert and M. J. Rosseinsky, Chem. Commun., 1999, 375; (j) B. Rather and M. J. Zaworotko, Chem. Commun., 2003, 830.
27. (a) R.-G. Xiong, S. R. Wilson and W. B. Lin, J. Chem. Soc., Dalton Trans., 1998, 4089;
28. (b) Z. Wang, S. R. Wilson, B. M. Foxman and W. Lin, Cryst. Eng., 1999, 2, 91.
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30. 9 and hydrogen gives 6.1 Å. The ethanol structure was obtained from molecular mechanics using Chem3D.
31. SAINT-NT, program for data collection and data reduction, Bruker-AXS, Madison, WI, 1998.
32. G. M. Sheldrick, SHELXTL Version 5.0, A System for Structure Solution and Refinement, Bruker-AXS, Madison, WI, 1998.
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