Modeling CO2 adsorption on amine-functionalized mesoporous silica: 1. A semi-empirical equilibrium model

Chemical Engineering Journal

Volumn 161, Issue 1-2, 2010, Pages 173-181

  Serna Guerrero, Rodrigo ^a   Belmabkhout, Youssef ^a   Sayari, Abdelhamid ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

Adsorption isotherm; Aminosilane grafting; Heat of adsorption; MCM 41

Indexed keywords

ADSORPTION; ADSORPTION ISOTHERMS; GRAFTING (CHEMICAL); MESOPOROUS MATERIALS; PHYSISORPTION; SILICA;

AMINE FUNCTIONAL GROUPS; AMINE-FUNCTIONALIZED MESOPOROUS SILICA; AMINOSILANES; EQUILIBRIUM MODELING; HEAT OF ADSORPTION; NORMALIZED STANDARD DEVIATIONS; SEMI-EMPIRICAL METHODS; TEMPERATURE DEPENDENT;

CARBON DIOXIDE;

EID: 85030580623     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2010.04.024     Document Type: Article

References (39)

1. 2-loaded solvent, Energy Fuels 24 (2010) 213-219.
2. Y. Li, Study on corrosion and material selection for desulphurization unit in refinery, Petroleum Refinery Eng. 38 (2008) 24-27.
3. 2 capture focusing on emissions from amine-based scrubbing solvents to air, Environ. Sci. Technol. 44 (2010) 1496-1502.
4. 2 removal from flue gas, Ind. Eng. Chem. Res. 48 (2009) 7314-7324.
5. 2 on amine-functionalized Y-type zeolites, Energy Fuels 24 (2010) 1441-1448.
6. 2 adsorbents, J. Environ. Eng. 135 (2009) 426-432.
7. 2 by impregnated spherical carbons, Micropor. Mesopor. Mater. 120 (2009) 76-83.
8. H.Y. Huang, R.T. Yang, D. Chinn, C.L. Munson, Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas, Ind. Eng. Chem. Res. 42 (2003) 2427-2433.
9. N. Hiyoshi, K. Yogo, T. Yashima, Adsorption characteristics of carbon dioxide on organically functionalized SBA-15, Micropor. Mesopor. Mater. 84 (2005) 357-365.
10. 2 adsorbents, Fuel Process. Technol. 86 (2005) 1435-1448.
11. 2 sorbent, Ind. Eng. Chem. Res. 44 (2005) 3099-3105.
12. 2 capture by as-prepared SBA-15 with an occluded organic template, Adv. Funct. Mater. 16 (2006) 1717-1722.
13. C. Knöfel, J. Descarpentries, A. Benzaouia, V. Zelenak, S. Mornet, P.L. Llewelyn, V. Hornebecq, Functionalized micro-/mesoporous silica for the adsorption of carbon dioxide, Micropor. Mesopor. Mater. 99 (2007) 79-85.
14. 4, Chem. Eng. Sci. 62 (2007) 1101-1110.
15. 2 adsorption on SBA-15 modified by aminosilane, Chin. J. Catal. 28 (2007) 805-810.
16. 2 reversibly, J. Am. Chem. Soc. 130 (2008) 2902-2903.
17. 2 adsorption over a wide range of conditions, Adsorption 15 (2009) 318-328.
18. 2S from various gas streams, J. Am. Chem. Soc. 131 (2009) 5777-5783.
19. A. Zukal, I. Dominguez, J. Mayerov, J. Cejka, Functionalization of delaminated zeolite ITQ-6 for the adsorption of carbon dioxide, Langmuir 25 (2009) 10314-10321.
20. 4, J. Am. Chem. Soc. 131 (2009) 6326-6327.
21. 4 mixtures in the highly flexible MIL-53(Cr) MOF, J. Am. Chem. Soc. 131 (2009) 17490-17499.
22. A.O. Yazaydin, R.Q. Snurr, T.H. Park, K. Koh, J. Liu, M.D. LeVan, A.I. Benin, P. Jakubczak, M. Lanuza, D.B. Galloway, J.J. Low, R.R. Willis, Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach, J. Am. Chem. Soc. 131 (2009) 18198-18199.
23. 2 uptake in a cobalt adeninate metalorganic framework exhibiting pyrimidine and amino-decorated pores, J. Am. Chem. Soc. 132 (2010) 38-39.
24. 2 dynamic and equilibrium adsorption performance, Ind. Eng. Chem. Res. 46 (2007) 446-458.
25. S. Choi, J.H. Drese, C.W. Jones, Adsorbent materials for carbon dioxide capture from large anthropogenic point sources, ChemSusChem 2 (2009) 796-854.
26. A. Sayari, Periodic mesoporous materials: synthesis, characterization and potential applications, Stud. Surf. Sci. Catal. 102 (1996) 1-46.
27. A. Sayari, Mesoporous materials, in: P. Yang (Ed.), The Chemistry of Nanostructured Materials, World Scientific, Singapore, 2003, pp. 39-68.
28. A. Sayari, M. Kruk, M. Jaroniec, I.L. Moudrakovski, New approaches to pore size engineering of mesoporous silicates, Adv. Mater. 10 (1998) 1376-1379.
29. A. Sayari, Y. Yang, M. Kruk, M. Jaroniec, Expanding the pore size of MCM-41 silicas: use of amines as expanders in direct synthesis and postsynthesis procedures, J. Phys. Chem. B 103 (1999) 3651-3658.
30. P. Selvam, S.K. Bhatia, C.G. Sonwane, Recent advances in processing and characterization of periodic mesoporous MCM-41 silicate molecular sieves, Ind. Eng. Chem. Res. 40 (2001) 3237-3261.
31. A. Stein, B.J. Melde, R.C. Schroden, Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age, Adv. Mater. 12 (2000) 1403-1419.
32. A. Sayari, S. Hamoudi, Periodic mesoporous silica-based organic-inorganic nanocomposite materials, Chem. Mater. 13 (2001) 3151-3168.
33. 2 with amine-functionalized silica, Ind. Eng. Chem. Res. 47 (2008) 9406-9412.
34. 2 adsorption, Chem. Eng. Sci. 64 (2009) 3721-3728.
35. 2 binary mixtures, Chem. Eng. Sci. 64 (2009) 3729-3785.
36. D.D. Do, Adsorption Analysis: Equilibria and Kinetics, Imperial College Press, London, 1998.
37. R. Serna-Guerrero, A. Sayari, Applications of pore-expanded mesoporous silica. 7. Adsorption of volatile organic compounds, Environ. Sci. Technol. 41 (2007) 4761-4766.
38. M. Kruk, M. Jaroniec, A. Sayari, Application of large pore MCM-41 molecular sieves to improve pore size analysis using nitrogen adsorption measurements, Langmuir 13 (1997) 6267-6273.
39. C. Knofel, C. Martin, V. Hornebecq, P. Llewellyn, Study of carbon dioxide adsorption on mesoporous aminopropylsilane-functionalized silica and titania combining microcalorimetry and in situ infrared spectroscopy, J. Phys. Chem. C 113 (2009) 21726-21734.