Amine-grafted MCM-48 and silica xerogel as superior sorbents for acidic gas removal from natural gas

Industrial and Engineering Chemistry Research

Volumn 42, Issue 12, 2003, Pages 2427-2433

  Huang, Helen Y ^a   Yang, Ralph T ^a   Chinn, Daniel ^b   Munson, Curtis L ^b  

^a UNIVERSITY OF MICHIGAN   (United States)

^b CHEVRON ENERGY TECHNOLOGY COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION ISOTHERMS; INFRARED SPECTROSCOPY; NATURAL GAS; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

SILICA XEROGEL;

SILICA GEL;

ADSORBENT; AMINE; CARBON DIOXIDE; HYDROGEN SULFIDE; MCM 48; NATURAL GAS; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ACID; AMINE; GAS SEPARATION; NATURAL GAS; SORPTION;

ACIDITY; ADSORPTION; ARTICLE; CHEMICAL BINDING; DESORPTION; GEL; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; MOISTURE; PRESSURE; RECYCLING; SOLID; SURFACE PROPERTY; SYNTHESIS; TEMPERATURE; THERMOGRAVIMETRY; WATER VAPOR;

EID: 0037980448     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020440u     Document Type: Article

References (37)

1. Maddox, R. N.; Mains, G. J.; Rahman, M. A. Reactions of Carbon Dioxide and Hydrogen Sulfide with Some Alkanolamines. Ind. Eng. Chem. Res. 1987, 26, 27.
2. 2S into Aqueous Methyldiethanolamine. Chem. Eng. Commun. 1987, 59, 85.
3. 2S by an Aqueous Methyldiethanolamine Solution at 296 and 343 K. J. Chem. Eng. Data 1997, 42, 865.
4. Posey, M. L.; Tapperson, K. G.; Rochelle, G. T. Simple Model for the Prediction of Acid Gas Solubilities in Alkanolamines. Gas. Sep. Purif. 1996, 10, 181.
5. Bhide, B. D.; Voskericyan, A.; Stern, S. A. Hybrid Processes for the Removal of Acid Gases from Natural Gas. J. Membr. Sci. 1998, 140, 27.
6. Diaf, A.; Enick, R. M.; Beckman, E. J. Molecular Redesign of Expanded Polystyrene to Allow Use of Carbon Dioxide as a Foaming Agent. J. Appl. Polym. Sci. 1993, 50, 835.
7. 2 on Molecular Sieves and Activated Carbon. Energy Fuels 2001, 15, 279.
8. Satyapal, S.; Filburn, T.; Trela, J.; Strange, J. Performance and Properties of a Solid Amine Sorbent for Carbon Dioxide Removal in Space Life Support Applications. Energy Fuels 2001, 15, 250.
9. Leal, O.; Bolivar, C.; Ovalles, C.; Garcia, J. J.; Espidel, Y. Reversible Adsorption of Carbon Dioxide on Amine Surface-bonded Silica Gel. Inorg. Chim. Acta 1995, 240, 183.
10. Kikkinides, E. S.; Yang, R. T.; Cho, S. H. Concentration and Recovery of Carbon Dioxide from Flue Gas by Pressure Swing Adsorption. Ind. Eng. Chem. Res. 1993, 32, 2714.
11. Kikkinides, E. S.; Sikavitsas, V. I.; Yang, R. T. Natural Gas Desulfurization by Adsorption: Feasibility and Multiplicity of Cyclic Steady States. Ind. Eng. Chem. Res. 1995, 34, 255.
12. Chen, Y. D.; Ritter, J. A.; Yang, R. T. Nonideal Adsorption from Multicomponent Gas Mixtures at Elevated Pressures on a 5A Molecular Sieve. Chem. Eng. Sci. 1990, 45, 2877.
13. 2 Recovery from Flue Gas by Pressure Swing Adsorption. Ind. Eng. Chem. Res. 1995, 34, 591.
14. Jaroniec, C. P.; Kruk, M.; Jaroniec, M.; Sayari, A. Tailoring Surface and Structural Properties of MCM-41 Silicas by Bonding Organosilanes. J. Phys. Chem. B 1995, 102, 5503.
15. Cauvel, A.; Renard, G.; Brunel, D. Monoglyceride Synthesis of Heterogeneous Catalysis Using MCM-41 Type Silicas Functionalized with Amino Groups. J. Org. Chem. 1997, 62, 749.
16. Shephard, D. S.; Zhou, W.; Maschmeyer, T.; Matters, J. M.; Roper, C. L.; Parsons, S.; Johnson, B. F. G.; Duer, M. J. Site- Directed Surface Derivatization of MCM-41: Use of High-Resolution Transmission Electron Microscopy and Molecular Recognition for Determining the Position of Functionality within Mesoporous Materials. Angew. Chem., Int. Ed. 1998, 37, 2719.
17. Lasperas, M.; Llorett, T.; Chaves, L.; Rodriguez, I.; Cauvel, A.; Brunel, D. Heterogeneous Catalysis and Fine Chemicals; Elsevier Science: New York, 1997; Vol. Iv, p 75.
18. Angeletti, E.; Canepa, C.; Martinetti, G.; Venturello, P. Silica Gel Functionalized with Amino Groups as a New Catalyst for Knoevenagel Condensation under Heterogeneous Catalysis Conditions. Tetrahedron Lett. 1988, 29, 2261.
19. Mercier, L.; Pinnavaia, T. J. Direct Synthesis of Hybrid Organic-Inorganic Nanoporous Silica by a Neutral Amine Assembly Route: Structure-Function Control by Stoichiometric Incorporation of Organosiloxane Molecules. Chem. Mater. 2000, 12, 188.
20. Jaroniec, M.; Kruk, M.; Jaroniec, C. P. Modification of Surface and Structural Properties of Ordered Mesoporous Silicates. Adsorption, 1999, 5, 39.
21. Burwell, R. L., Jr.; Leal, O. Modified Silica Gels as Selective Adsorbents for Sulfur Dioxide. Chem. Commun. 1974, 342.
22. Angeletti, E.; Canepa, C.; Martinetti, G.; Venturello, P. Amino Groups Immobilized on Silica Gel - An Efficient and Reusable Heterogeneous Catalyst for the Knoevenagel Condensation. J. Chem. Soc., Perkin Trans. I 1989, 105.
23. Zhao, X. S.; Lu, G. Q. Modification of MCM-41 by Surface Silylation with Trimethylchlorosilane and Adsorption Study. J. Phys. Chem. B 1998, 102, 1556.
24. Jentys, A.; Kleestorfer, K.; Vinek, H. Concentration of Surface Hydroxyl Groups on MCM-41. Microporous Mesoporous Mater. 1999, 27, 321.
25. Landmesser, H.; Kosslick, H.; Storek, W.; Fricke, R. Interior Surface Hydroxyl Groups in Ordered Mesoporous Silicates. Solid State Ionics 1997, 101-103, 271.
26. Takei, T.; Kato, K.; Meguro, A.; Chikazawa, M. Infrared Spectra of Geminal and Novel Triple Hydroxyl Groups on Silica Surface. Colloids Surf. A 1999, 150, 77.
27. 29Si CP/MAS NMR, FTIR, Pyridine-TPD, and TGA. J. Phys. Chem. B 1997, 101, 6525.
28. Scott, R. P. W. Silica Gel and Bonded Phases-Their Production, Properties and Use in LC; John Wiley & Sons: New York, 1993; Chapter 8.
29. Deshpande, R.; Smith, D. M.; Brinker, C. J. Preparation of High Porosity Xerogels by Chemical Surface Modification. U.S. Patent 5,565,142, 1996.
30. Schumacher, K.; Ravikovitch, P. I.; Chesne, A. D.; Neimark, A. V.; Unger, K. K. Characterization of MCM-48 Materials. Langmuir 2000, 16, 4648.
31. Xu, J.; Luan, Z.; He, H.; Zhou, W.; Kevan, L. Reliable Synthesis of Cubic Mesoporous MCM-48 Molecular Sieve. Chem. Mater. 1998, 10, 3690. A
32. Iler, R. K. The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry; Wiley: New York, 1979; Chapter 6.
33. Bergna, H. E. The Colloid Chemistry of Silica; American Chemical Society: Washington, DC, 1994; Chapter 8.
34. Macquarrie, D. J. Direct Preparation of Organically Modified MCM-type Materials. Preparation and Characterisation of Aminopropyl-MCM and 2-Cyanoethyl-MCM. Chem. Commun. 1996, 1961.
35. Urban, M. W. Vibrational Spectroscopy of Molecules and Macromolecules on Surfaces; Wiley: New York, 1993; Chapter 4.
36. Socrates, G. Infrared Characteristic Group Frequencies Tables and Charts, 2nd ed.; Wiley: New York, 1997; Chapter 9.
37. Lin-Vien, D.; Colthup, N. B.; Fateley, W. G.; Grasselli, J. G. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press: New York, 1991; Chapter 14.