Superior Flame-Resistant Cellulose Nanofibril Aerogels Modified with Hybrid Layer-by-Layer Coatings

ACS Applied Materials and Interfaces

Volumn 9, Issue 34, 2017, Pages 29082-29092

  Köklükaya, Oruç ^a   Carosio, Federico ^b   Wågberg, Lars ^a  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b POLITECNICO DI TORINO   (Italy)

Author keywords

aerogel; cellulose nanofibril; flame retardant; layer by layer assembly; thermal stability

Indexed keywords

CELLULOSE; CELLULOSE FILMS; COATINGS; FILM PREPARATION; FLAME RETARDANTS; HEAT FLUX; MULTILAYERS; NANOFIBERS; POLYELECTROLYTES; SILICON OXIDES; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

LAYER-BY-LAYER ASSEMBLIES; LAYER-BY-LAYER TECHNIQUES; MULTILAYER STRUCTURES; NANOFIBRIL; POLYELECTROLYTE TITRATION; SILICON OXIDE SURFACES; SOLUTION CONCENTRATION; VINYLPHOSPHONIC ACIDS;

AEROGELS;

AEROGELS; CELLULOSE; COATINGS; FLAME RETARDANTS; MONTMORILLONITE; THERMAL STABILITY;

EID: 85028701297     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.7b08018     Document Type: Article

References (54)

1. Klemm, D.; Heublein, B.; Fink, H. P.; Bohn, A. Cellulose: Fascinating Biopolymer and Sustainable Raw Material Angew. Chem., Int. Ed. 2005, 44, 3358-3393 10.1002/anie.200460587
2. Eichhorn, S. J.; Dufresne, A.; Aranguren, M.; Marcovich, N.; Capadona, J.; Rowan, S.; Weder, C.; Thielemans, W.; Roman, M.; Renneckar, S. et al. Review: Current International Research into Cellulose Nanofibres and Nanocomposites J. Mater. Sci. 2010, 45, 1-33 10.1007/s10853-009-3874-0
3. Zhu, H.; Luo, W.; Ciesielski, P. N.; Fang, Z.; Zhu, J.; Henriksson, G.; Himmel, M. E.; Hu, L. Wood-Derived Materials for Green Electronics, Biological Devices, and Energy Applications Chem. Rev. 2016, 116, 9305-9374 10.1021/acs.chemrev.6b00225
4. Klemm, D.; Kramer, F.; Moritz, S.; Lindström, T.; Ankerfors, M.; Gray, D.; Dorris, A. Nanocelluloses: A New Family of Nature-Based Materials Angew. Chem., Int. Ed. 2011, 50, 5438-5466 10.1002/anie.201001273
5. Turbak, A.; Snyder, F.; Sandberg, K. Microfibrillated Cellulose, a New Cellulose Product: Properties, Uses, and Commercial Potential J. Appl. Polym. Sci.: Appl. Polym. Symp. 1983, 37, 815-827
6. Herrick, F. W.; Casebier, R. L.; Hamilton, J. K.; Sandberg, K. R. Microfibrillated Cellulose: Morphology and Accessibility J. Appl. Polym. Sci.: Appl. Polym. Symp. 1983, 37, 797-813
7. Pääkkö, M.; Ankerfors, M.; Kosonen, H.; Nykänen, A.; Ahola, S.; Österberg, M.; Ruokolainen, J.; Laine, J.; Larsson, P. T.; Ikkala, O.; Lindström, T. Enzymatic Hydrolysis Combined with Mechanical Shearing and High-Pressure Homogenization for Nanoscale Cellulose Fibrils and Strong Gels Biomacromolecules 2007, 8, 1934-1941 10.1021/bm061215p
8. Wågberg, L.; Decher, G.; Norgren, M.; Lindström, T.; Ankerfors, M.; Axnäs, K. The Build-Up of Polyelectrolyte Multilayers of Microfibrillated Cellulose and Cationic Polyelectrolytes Langmuir 2008, 24, 784-795 10.1021/la702481v
9. Saito, T.; Nishiyama, Y.; Putaux, J. L.; Vignon, M.; Isogai, A. Homogeneous Suspensions of Individualized Microfibrils from TEMPO-Catalyzed Oxidation of Native Cellulose Biomacromolecules 2006, 7, 1687-1691 10.1021/bm060154s
10. Kistler, S. Coherent Expanded Aerogels Rubber Chem. Technol. 1932, 5, 600-603 10.5254/1.3539386
11. Gesser, H.; Goswami, P. Aerogels and Related Porous Materials Chem. Rev. 1989, 89, 765-788 10.1021/cr00094a003
12. 2 Aerogels. 1. Electron Microscopy J. Phys. Chem. 1995, 99, 15945-15949 10.1021/j100043a037
13. Schaefer, D. W.; Keefer, K. D. Structure of Random Porous Materials: Silica Aerogel Phys. Rev. Lett. 1986, 56, 2199-2202 10.1103/PhysRevLett.56.2199
14. Pekala, R. Organic Aerogels from the Polycondensation of Resorcinol with Formaldehyde J. Mater. Sci. 1989, 24, 3221-3227 10.1007/BF01139044
15. Tan, C.; Fung, B.; Newman, J.; Vu, C. Organic Aerogels with Very High Impact Strength Adv. Mater. 2001, 13, 644-646 10.1002/1521-4095(200105)13:9<644::AID-ADMA644>3.0.CO;2-#
16. Gavillon, R.; Budtova, T. Aerocellulose: New Highly Porous Cellulose Prepared from Cellulose NaOH Aqueous Solutions Biomacromolecules 2008, 9, 269-277 10.1021/bm700972k
17. Svagan, A. J.; Samir, M. A.; Berglund, L. A. Biomimetic Foams of High Mechanical Performance Based on Nanostructured Cell Walls Reinforced by Native Cellulose Nanofibrils Adv. Mater. 2008, 20, 1263-1269 10.1002/adma.200701215
18. Fischer, F.; Rigacci, A.; Pirard, R.; Berthon-Fabry, S.; Achard, P. Cellulose-Based Aerogels Polymer 2006, 47, 7636-7645 10.1016/j.polymer.2006.09.004
19. Jin, H.; Nishiyama, Y.; Wada, M.; Kuga, S. Nanofibrillar Cellulose Aerogels Colloids Surf., A 2004, 240, 63-67 10.1016/j.colsurfa.2004.03.007
20. Pääkkö, M.; Vapaavuori, J.; Silvennoinen, R.; Kosonen, H.; Ankerfors, M.; Lindström, T.; Berglund, L. A.; Ikkala, O. Long and Entangled Native Cellulose I Nanofibers Allow Flexible Aerogels and Hierarchically Porous Templates for Functionalities Soft Matter 2008, 4, 2492-2499 10.1039/b810371b
21. Olsson, R. T.; Samir, M. A. S. A.; Salazar-Alvarez, G.; Belova, L.; Ström, V.; Berglund, L. A.; Ikkala, O.; Nogues, J.; Gedde, U. W. Making Flexible Magnetic Aerogels and Stiff Magnetic Nanopaper Using Cellulose Nanofibrils as Templates Nat. Nanotechnol. 2010, 5, 584-588 10.1038/nnano.2010.155
22. Wang, M.; Anoshkin, I. V.; Nasibulin, A. G.; Korhonen, J. T.; Seitsonen, J.; Pere, J.; Kauppinen, E. I.; Ras, R. H.; Ikkala, O. Modifying Native Nanocellulose Aerogels with Carbon Nanotubes for Mechanoresponsive Conductivity and Pressure Sensing Adv. Mater. 2013, 25, 2428-2432 10.1002/adma.201300256
23. Liu, A.; Walther, A.; Ikkala, O.; Belova, L.; Berglund, L. A. Clay Nanopaper with Tough Cellulose Nanofiber Matrix for Fire Retardancy and Gas Barrier Functions Biomacromolecules 2011, 12, 633-641 10.1021/bm101296z
24. Cervin, N. T.; Aulin, C.; Larsson, P. T.; Wågberg, L. Ultra Porous Nanocellulose Aerogels as Separation Medium for Mixtures of Oil/Water Liquids Cellulose 2012, 19, 401-410 10.1007/s10570-011-9629-5
25. Aulin, C.; Netrval, J.; Wågberg, L.; Lindström, T. Aerogels from Nanofibrillated Cellulose with Tunable Oleophobicity Soft Matter 2010, 6, 3298-3305 10.1039/c001939a
26. Hamedi, M.; Karabulut, E.; Marais, A.; Herland, A.; Nyström, G.; Wågberg, L. Nanocellulose Aerogels Functionalized by Rapid Layer-by-Layer Assembly for High Charge Storage and Beyond Angew. Chem., Int. Ed. 2013, 52, 12038-12042 10.1002/anie.201305137
27. Wu, Z. Y.; Li, C.; Liang, H. W.; Chen, J. F.; Yu, S. H. Ultralight, Flexible, and Fire-Resistant Carbon Nanofiber Aerogels from Bacterial Cellulose Angew. Chem. 2013, 125, 2997-3001 10.1002/ange.201209676
28. Shang, K.; Liao, W.; Wang, J.; Wang, Y. T.; Wang, Y. Z.; Schiraldi, D. A. Nonflammable Alginate Nanocomposite Aerogels Prepared by a Simple Freeze-Drying and Post-Cross-Linking Method ACS Appl. Mater. Interfaces 2016, 8, 643-650 10.1021/acsami.5b09768
29. Han, Y.; Zhang, X.; Wu, X.; Lu, C. Flame Retardant, Heat Insulating Cellulose Aerogels from Waste Cotton Fabrics by in situ Formation of Magnesium Hydroxide Nanoparticles in Cellulose Gel Nanostructures ACS Sustainable Chem. Eng. 2015, 3, 1853-1859 10.1021/acssuschemeng.5b00438
30. Iler, R. Multilayers of Colloidal Particles J. Colloid Interface Sci. 1966, 21, 569-594 10.1016/0095-8522(66)90018-3
31. Decher, G. Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites Science 1997, 277, 1232-1237 10.1126/science.277.5330.1232
32. Shimazaki, Y.; Mitsuishi, M.; Ito, S.; Yamamoto, M. Preparation of the Layer-by-Layer Deposited Ultrathin Film Based on the Charge-Transfer Interaction Langmuir 1997, 13, 1385-1387 10.1021/la9609579
33. Bergbreiter, D. E.; Tao, G.; Franchina, J. G.; Sussman, L. Polyvalent Hydrogen-Bonding Functionalization of Ultrathin Hyperbranched Films on Polyethylene and Gold Macromolecules 2001, 34, 3018-3023 10.1021/ma000873d
34. Sun, J.; Wu, T.; Liu, F.; Wang, Z.; Zhang, X.; Shen, J. Covalently Attached Multilayer Assemblies by Sequential Adsorption of Polycationic Diazo-Resins and Polyanionic Poly (acrylic acid) Langmuir 2000, 16, 4620-4624 10.1021/la991482z
35. Priolo, M. A.; Gamboa, D.; Holder, K. M.; Grunlan, J. C. Super Gas Barrier of Transparent Polymer-Clay Multilayer Ultrathin Films Nano Lett. 2010, 10, 4970-4974 10.1021/nl103047k
36. Li, Z.; Lee, D.; Sheng, X.; Cohen, R. E.; Rubner, M. F. Two-Level Antibacterial Coating with both Release-Killing and Contact-Killing Capabilities Langmuir 2006, 22, 9820-9823 10.1021/la0622166
37. Hiller, J. A.; Mendelsohn, J. D.; Rubner, M. F. Reversibly Erasable Nanoporous Anti-Reflection Coatings from Polyelectrolyte Multilayers Nat. Mater. 2002, 1, 59-63 10.1038/nmat719
38. Shim, B. S.; Tang, Z.; Morabito, M. P.; Agarwal, A.; Hong, H.; Kotov, N. A. Integration of Conductivity, Transparency, and Mechanical Strength into Highly Homogeneous Layer-by-Layer Composites of Single-Walled Carbon Nanotubes for Optoelectronics Chem. Mater. 2007, 19, 5467-5474 10.1021/cm070442a
39. Li, Y. C.; Schulz, J.; Grunlan, J. C. Polyelectrolyte/Nanosilicate Thin-Film Assemblies: Influence of pH on Growth, Mechanical Behavior, and Flammability ACS Appl. Mater. Interfaces 2009, 1, 2338-2347 10.1021/am900484q
40. Carosio, F.; Laufer, G.; Alongi, J.; Camino, G.; Grunlan, J. C. Layer-by-Layer Assembly of Silica-Based Flame Retardant Thin Film on PET Fabric Polym. Degrad. Stab. 2011, 96, 745-750 10.1016/j.polymdegradstab.2011.02.019
41. Apaydin, K.; Laachachi, A.; Ball, V.; Jimenez, M.; Bourbigot, S.; Toniazzo, V.; Ruch, D. Polyallylamine-Montmorillonite as Super Flame Retardant Coating Assemblies by Layer-by Layer Deposition on Polyamide Polym. Degrad. Stab. 2013, 98, 627-634 10.1016/j.polymdegradstab.2012.11.006
42. Kim, Y. S.; Davis, R.; Cain, A. A.; Grunlan, J. C. Development of Layer-by-Layer Assembled Carbon Nanofiber-Filled Coatings to Reduce Polyurethane Foam Flammability Polymer 2011, 52, 2847-2855 10.1016/j.polymer.2011.04.023
43. Laufer, G.; Kirkland, C.; Cain, A. A.; Grunlan, J. C. Clay-Chitosan Nanobrick Walls: Completely Renewable Gas Barrier and Flame-Retardant Nanocoatings ACS Appl. Mater. Interfaces 2012, 4, 1643-1649 10.1021/am2017915
44. Laufer, G.; Kirkland, C.; Morgan, A. B.; Grunlan, J. C. Intumescent Multilayer nanocoating, Made with Renewable Polyelectrolytes, for Flame-Retardant Cotton Biomacromolecules 2012, 13, 2843-2848 10.1021/bm300873b
45. Alongi, J.; Han, Z.; Bourbigot, S. Intumescence: Tradition versus Novelty. A Comprehensive Review Prog. Polym. Sci. 2015, 51, 28-73 10.1016/j.progpolymsci.2015.04.010
46. Sauerbrey, G. Verwendung von Schwingquarzen zur Wägung dünner Schichten und zur Mikrowägung Eur. Phys. J. A 1959, 155, 206-222 10.1007/BF01337937
47. Rodahl, M.; Höök, F.; Krozer, A.; Brzezinski, P.; Kasemo, B. Quartz Crystal Microbalance Setup for Frequency and Q-Factor Measurements in Gaseous and Liquid Environments Rev. Sci. Instrum. 1995, 66, 3924-3930 10.1063/1.1145396
48. Bingol, B.; Meyer, W. H.; Wegner, G. Acidity of Poly(vinylphosphonic acid) and a Comparison with Analogous Polyelectrolytes Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2007, 48, 144-145
49. Odijk, T. Polyelectrolytes Near the Rod Limit J. Polym. Sci., Polym. Phys. Ed. 1977, 15, 477-483 10.1002/pol.1977.180150307
50. Koklukaya, O.; Carosio, F.; Grunlan, J. C.; Wagberg, L. Flame-Retardant Paper from Wood Fibers Functionalized via Layer-by-Layer Assembly ACS Appl. Mater. Interfaces 2015, 7, 23750-23759 10.1021/acsami.5b08105
51. Soares, S.; Camino, G.; Levchik, S. Comparative Study of the Thermal Decomposition of Pure Cellulose and Pulp Paper Polym. Degrad. Stab. 1995, 49, 275-283 10.1016/0141-3910(95)87009-1
52. Price, D.; Horrocks, A.; Akalin, M.; Faroq, A. Influence of Flame Retardants on the Mechanism of Pyrolysis of Cotton (Cellulose) Fabrics in Air J. Anal. Appl. Pyrolysis 1997, 40-41, 511-524 10.1016/S0165-2370(97)00043-0
53. Ma, H.; Tong, L.; Xu, Z.; Fang, Z. Intumescent Flame Retardant-Montmorillonite Synergism in ABS Nanocomposites Appl. Clay Sci. 2008, 42, 238-245 10.1016/j.clay.2007.12.009
54. Wicklein, B.; Kocjan, A.; Salazar-Alvarez, G.; Carosio, F.; Camino, G.; Antonietti, M.; Bergström, L. Thermally Insulating and Fire-Retardant Lightweight Anisotropic Foams Based on Nanocellulose and Graphene Oxide Nat. Nanotechnol. 2015, 10, 277-283 10.1038/nnano.2014.248