Cooperative Catalysis of Noncompatible Catalysts through Compartmentalization: Wacker Oxidation and Enzymatic Reduction in a One-Pot Process in Aqueous Media

Angewandte Chemie - International Edition

Volumn 54, Issue 15, 2015, Pages 4488-4492

  Sato, Hirofumi ^a,b   Hummel, Werner ^a   Gröger, Harald ^a  

^a BIELEFELD UNIVERSITY   (Germany)

^b OSAKA MUNICIPAL TECHNICAL RESEARCH INSTITUTE   (Japan)

Author keywords

chiral alcohols; enzyme catalysis; one pot synthesis; polydimethylsiloxane; Wacker oxidation

Indexed keywords

CATALYSIS; CATALYST DEACTIVATION; CATALYSTS; ENZYMES; HEAVY IONS; KETONES; POLYDIMETHYLSILOXANE; SILICONES; STYRENE; SYNTHESIS (CHEMICAL);

ASYMMETRIC HYDRATIONS; CHIRAL ALCOHOLS; COOPERATIVE CATALYSIS; ENZYMATIC REDUCTION; ENZYME CATALYSIS; ENZYME DEACTIVATION; ONE-POT SYNTHESIS; WACKER OXIDATION;

OXIDATION;

EID: 85027935948     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201409590     Document Type: Article

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46. We chose room temperature, a relatively low reaction temperature, to suppress the undesired effects that can be expected at elevated temperatures such as loss of styrene from the reaction mixture due to its evaporation as well as deactivation of the enzyme and the cofactor.
47. With respect to the recycling of other components, an attempt to recycle methanol was not made due to its low price and readily availability. In contrast, recycling of ADH and the cofactor is in principle an interesting option for future work although modified downstream-processing would be required for this purpose. In the current process based on extractive workup, enzyme and cofactor recycling would be tedious and might also lead to significant enzyme deactivation. In addition, for this process it has to be considered that the ADH can be produced efficiently and inexpensively by means of a recombinant strain, thus making multiple reuse of ADH not a task of highest priority.