Effect of coexisting salt on TEMPO-mediated oxidation of wood cellulose for preparation of nanocellulose

Cellulose

Volumn 24, Issue 9, 2017, Pages 4097-4101

  Inamochi, Toru ^a   Funahashi, Ryunosuke ^a   Nakamura, Yasutaka ^a   Saito, Tsuguyuki ^a   Isogai, Akira ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Carboxylate content; Coexisting salt; Nanofibrillation; Oxidation kinetics; TEMPO

Indexed keywords

CARBOXYLATION; CELLULOSE; NANOTECHNOLOGY; WOOD;

2 ,2 ,6 ,6-TETRAMETHYLPIPERIDINE-1-OXYL; CARBOXYLATE CONTENTS; NANO FIBRILLATIONS; OXIDATION KINETICS; OXIDATION SYSTEMS; OXIDIZED CELLULOSE; TEMPO; TEMPO-MEDIATED OXIDATION;

OXIDATION;

INORGANIC SALTS; OXIDATION;

EID: 85021959820     PISSN: 09690239     EISSN: 1572882X     Source Type: Journal    
DOI: 10.1007/s10570-017-1402-y     Document Type: Article

References (20)

1. Bragd PL, Besemer AC, van Bekkum H (2000) Bromide-free TEMPO-mediated oxidation of primary alcohol groups in starch and methyl α-d-glucopyranoside. Carbohydr Res 328:355–363
2. Bragd PL, Besemer AC, van Bekkum H (2001) TEMPO-derivatives as catalysts in the oxidation of primary alcohol groups in carbohydrates. J Mol Catal A 170:35–42
3. Bragd PL, Besemer AC, van Bekkum H (2002) Selective oxidation of carbohydrate by 4-AcNH-TEMPO/peracid systems. Carbohydr Polym 49:397–406
4. Chang PS, Park KO, Shin HK, Suh DS, Kim KO (2008) Physicochemical properties of partially oxidized corn starch from bromide-free TEMPO-mediated oxidation. Food Sci 73:C173–C178
5. Coseri S (2017) Cellulose: To depolymerize… or not to? Biotechnol Adv 35:251–266
6. de Nooy AEJ, Besemer AC, van Bekkum H (1995) Highly selective nitroxyl radical-mediated oxidation of primary alcohol groups in water-soluble glucans. Carbohydr Res 269:89–98
7. Isogai A, Kato Y (1998) Preparation of polyuronic acid from cellulose by TEMPO-mediated oxidation. Cellulose 5:153–164
8. Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3:71–85
9. Jiang B, Drouet E, Milas M, Rinaudo M (2000) Study on TEMPO-mediated selective oxidation of hyaluronan and the effects of salt on the reaction kinetics. Carbohydr Res 327:455–461
10. Lai C, Zhang S, Sheng L, Liao S, Xi T, Zhang Z (2013) TEMPO-mediated oxidation of bacterial cellulose in a bromide-free system. Cooloid Polym Sci 291:2985–2992
11. Pääkkönen T, Bertinetto C, Pönni R, Tummala GK, Nuopponen M, Vuorinen T (2015) Rate-limiting steps in bromide-free TEMPO-mediated oxidation of cellulose: quantification of the N-oxoammonium cation by iodometric titration and UV–vis spectroscopy. Appl Catal A 505:532–538
12. Saito T, Isogai A (2004) TEMPO-mediated oxidation of native cellulose. The effect of oxidation conditions on chemical and crystal structures of the water-insoluble fractions. Biomacromolecules 5:1983–1989
13. Saito T, Okita Y, Nge TT, Sugiyama J, Isogai A (2006a) TEMPO-mediated oxidation of native cellulose. Microscopic analysis of fibrous fractions in the oxidized products. Carbohydr Polym 65:435–440
14. Saito T, Nishiyama Y, Putaux JL, Vignon M, Isogai A (2006b) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7:1687–1691
15. Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromolecules 8:2485–2591
16. Shibata I, Isogai A (2003) Depolymerization of cellouronic acid during TEMPO-mediated oxidation. Cellulose 10:151–158
17. Shinoda R, Saito T, Okita Y, Isogai A (2012) Relationship between length and degree of polymerization of TEMPO-oxidized cellulose nanofibrils. Biomacromolecules 13:842–849
18. Takaichi S, Saito T, Tanaka R, Isogai A (2014) Improvement of nanodispersibility of oven-dried TEMPO-oxidized celluloses in water. Cellulose 21:4093–4103
19. Tamura N, Wada M, Isogai A (2009) TEMPO-mediated oxidation of (1 → 3)-β-d-glucans. Carbohydr Polym 77:300–305
20. Yui Y, Tanaka C, Isogai A (2014) Analysis of TEMPO-mediated oxidation of cotton cellulose fabrics through electron spin resonance technique. J Fiber Sci Technol 70:53–58