Integrated process for extracting vitamin E with high purity from the methylated oil deodorizer distillate

Separation and Purification Technology

Volumn 196, Issue , 2018, Pages 229-236

  Qin, Lei ^a   Zeng, Qian ^a   Zhang, Jingjing ^a   Cheng, Hongye ^a   Chen, Lifang ^a   Qi, Zhiwen ^a  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Deodorizer distillate; Ionic liquid; Reextraction; Solvent selection; Vitamin E

Indexed keywords

EXTRACTION; FATTY ACIDS; HEXANE; IONIC LIQUIDS; REUSABILITY; SOLVENTS;

DEODORIZER DISTILLATES; EXTRACTANTS; EXTRACTION PROCESS; FATTY ACID METHYL ESTER; PARTITION COEFFICIENT; RE-EXTRACTION; SOLVENT SELECTION; VITAMIN-E;

ORGANIC SOLVENTS;

EID: 85019600202     PISSN: 13835866     EISSN: 18733794     Source Type: Journal    
DOI: 10.1016/j.seppur.2017.05.031     Document Type: Article

References (34)

1. Ge, Y.Q., Yan, H., Hui, B.D., Ni, Y.Y., Wang, S.X., Cai, T.Y., Extraction of natural vitamin E from wheat germ by supercritical carbon dioxide. J. Agric. Food. Chem. 50 (2002), 685–689.
2. Ramamurthi, S., McCurdy, A., Enzymatic pretreatment of deodorizer distillate for concentration of sterols and tocopherols. J. Am. Oil Chem. Soc. 70 (1993), 287–295.
3. Posada, L.R., Shi, J., Kakuda, Y., Xue, S.J., Extraction of tocotrienols from palm fatty acid distillates using molecular distillation. Sep. Purif. Technol. 57 (2007), 220–229.
4. Liu, D., Shi, J., Posada, L.R., Kakuda, Y., Xue, S.J., Separating tocotrienols from palm oil by molecular distillation. Food Rev. Int. 24 (2008), 376–391.
5. Torres, C.F., Torrelo, G., Señorans, F.J., Reglero, G., A two steps enzymatic procedure to obtain sterol esters, tocopherols and fatty acid ethyl esters from soybean oil deodorizer distillate. Process Biochem. 42 (2007), 1335–1341.
6. Wang, H.T., Goto, M., Sasaki, M., Hirose, T., Separation of α-tocopherol and squalene by pressure swing adsorption in supercritical carbon dioxide. Ind. Eng. Chem. Res. 43 (2004), 2753–2758.
7. Chu, B.S., Baharin, B.S., Che Man, Y.B., Quek, S.Y., Separation of vitamin E from palm fatty acid distillate using silica: I equilibrium of batch adsorption. J. Food Eng. 62 (2004), 97–103.
8. A.G.M. Top, L.W. Leong, A.S. Ong, T. Kawada, H. Watanabe, N. Tsuchiya, Production of high concentration tocopherols and tocotrienols from palm-oil by-products, US. Patent. (1993) US 5190618.
9. Dang, Y.Y., Zhang, H., Xiu, Z.L., Microwave-assisted aqueous two-phase extraction of phenolics from grape (Vitis vinifera) seed. J. Chem. Technol. Biotechnol. 89 (2013), 1576–1581.
10. Zhang, J., Huang, C.P., Chen, B.H., Ren, P.J., Lei, Z.G., Extraction of aromatic hydrocarbons from aromatic/aliphatic mixtures using chloroaluminate room-temperature ionic liquids as extractants. Energy Fuel 21 (2007), 1724–1730.
11. Vicente, G., Paiva, A., Fornari, T., Najdanovic-Visak, V., Liquid–liquid equilibria for separation of tocopherol from olive oil using ethyl lactate. Chem. Eng. J. 172 (2011), 879–884.
12. Dos Santos Freitas, L., Jacques, R.A., Richter, M.F., da Silva, A.L., Caramão, E.B., Pressurized liquid extraction of vitamin E from Brazilian grape seed oil. J. Phys. Chem. A 1200 (2008), 80–83.
13. Plechkova, N.V., Seddon, K.R., Applications of ionic liquids in the chemical industry. Chem. Soc. Rev. 37 (2008), 123–150.
14. Lei, Z.G., Dai, C.N., Zhu, J.Q., Chen, B.H., Extractive distillation with ionic liquids: a review. AlChE J. 60 (2014), 3312–3329.
15. 2 and helium in an ionic liquid containing poly(amidoamine) dendrimer gen 0. Ind. Eng. Chem. Res. 52 (2013), 10484–10494.
16. Freire, M.G., Teles, A.R.R., Ferreira, R.A.S., Carlos, L.D., Lopes-da-Silva, J.A., Coutinho, J.A.P., Electrospun nanosized cellulose fibers using ionic liquids at room temperature. Green Chem. 13 (2011), 3173–3180.
17. Zhao, H., Xia, S.Q., Ma, P.S., Use of ionic liquids as ‘green’ solvents for extractions. J. Chem. Technol. Biotechnol. 80 (2005), 1089–1096.
18. Lyu, Z.X., Zhou, T., Chen, L.F., Ye, Y.M., Sundmacher, K., Qi, Z.W., Reprint of: Simulation based ionic liquid screening for benzene–cyclohexane extractive separation. Chem. Eng. Sci. 115 (2014), 186–194.
19. Song, Z., Zhou, T., Zhang, J.N., Cheng, H.Y., Chen, L.F., Qi, Z.W., Screening of ionic liquids for solvent-sensitive extraction –with deep desulfurization as an example. Chem. Eng. Sci. 129 (2015), 69–77.
20. Chen, F.L., Zhang, Q., Mo, K., Fei, S., Gu, H.Y., Yang, L., Optimization of ionic liquid-based homogenate extraction of orientin and vitexin from the flowers of trollius chinensis and its application on a pilot scale. Sep. Purif. Technol. 175 (2017), 147–157.
21. Ji, Y.M., Chen, J.Y., Lv, J.X., Li, Z.L., Xing, L.Y., Ding, S.Y., Extraction of keratin with ionic liquids from poultry feather. Sep. Purif. Technol. 132 (2014), 577–583.
22. Passos, H., Freire, M.G., Coutinho, J.A.P., Ionic liquid solutions as extractive solvents for value-added compounds from biomass. Green Chem. 16 (2014), 4786–4815.
23. Claudio, A.F.M., Ferreira, A.M., Freire, M.G., Coutinho, J.A.P., Enhanced extraction of caffeine from guarana seeds using aqueous solutions of ionic liquids. Green Chem. 15 (2013), 2002–2010.
24. Ren, G.W., Gong, X.W., Wang, B.L., Chen, Y.Y., Huang, J.Y., Affinity ionic liquids for the rapid liquid–liquid extraction purification of hexahistidine tagged proteins. Sep. Purif. Technol. 146 (2015), 114–120.
25. Olkiewicz, M., Plechkova, N.V., Fabregat, A., Stüber, F., Fortuny, A., Font, J., Bengoa, C., Efficient extraction of lipids from primary sewage sludge using ionic liquids for biodiesel production. Sep. Purif. Technol. 153 (2015), 118–125.
26. Achinivu, E.C., Howard, R.M., Li, G.Q., Gracz, H., Henderson, W.A., Lignin extraction from biomass with protic ionic liquids. Green Chem. 16 (2014), 1114–1119.
27. Ni, X.L., Xing, H.B., Yang, Q.W., Wang, J., Su, B.G., Bao, Z.B., Yang, Y.W., Ren, Q.L., Selective liquid–liquid extraction of natural phenolic compounds using amino acid ionic liquids: a case of α-tocopherol and methyl linoleate separation. Ind. Eng. Chem. Res. 51 (2012), 6480–6488.
28. Qin, L., Zhang, J.N., Cheng, H.Y., Chen, L.F., Qi, Z.W., Yuan, W.K., Selection of imidazolium-based ionic liquids for vitamin E extraction from deodorizer distillate. ACS Sustainable Chem. Eng. 4 (2016), 583–590.
29. Yang, Q.W., Xing, H.B., Cao, Y.F., Su, B.G., Yang, Y.W., Ren, Q.L., Selective separation of tocopherol homologues by liquid−liquid extraction using ionic liquids. Ind. Eng. Chem. Res. 48 (2008), 6417–6422.
30. L. Qin, J.S. Li, H.Y. Cheng, L.F. Chen, Z.W. Qi, W.K. Yuan, Association extraction for vitamin E recovery from deodorizer distillate by in situ formation of deep eutectic solvent, AIChE J. 10.1002/aic.15606.
31. Li, M., Pham, P.J., Pittman, C.U. Jr, Li, T., Selective solid-phase extraction of α-tocopherol by functionalized ionic liquid-modified mesoporous SBA-15 adsorbent. Anal. Sci. 24 (2008), 1245–1250.
32. Jiang, S.T., Shao, P., Pan, L.J., Zhao, Y.Y., Molecular distillation for recovering tocopherol and fatty acid methyl esters from rapeseed oil deodoriser distillate. Biosyst. Eng. 93 (2006), 383–391.
33. Wan, J.C., Zhang, W.N., Jiang, B., Guo, Y.H., Hu, C.R., Separation of individual tocopherols from soybean distillate by low pressure column chromatography. J. Am. Oil Chem. Soc. 85 (2008), 331–338.
34. Amaral, J.S., Casal, S., Oliveira, B.P.P., Seabra, R.M., Development and evaluation of a normal phase liquid chromatographic method for the determination of tocopherols and tocotrienols in walnuts. J. Liq. Chromatogr. Relat. Tech. 28 (2005), 785–795.