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Competition experiment employing a secondary RAE (5, 1 equiv), a primary RAE (SI-16, 1 equiv), and benzylacrylate (1 equiv) showed higher yields of the secondary radical adduct; see the Supporting Information for details. This result is corroborated by observations in nickel catalyzed Giese reactions using alkyl halides as radical precursors:
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CCDC 1510142 (18 b) and 1510143 (19 b) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre.
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