Airborne measurements of bro and the sum of hobr and Br2 over the tropical west pacific from 1 to 15km during the convective transport of active species in the tropics (CONTRAST) experiment

Journal of Geophysical Research

Volumn 121, Issue 20, 2016, Pages 12,560-12,578

  Chen, Dexian ^a   Huey, L Gregory ^a   Tanner, David J ^a   Salawitch, Ross J ^b,c   Anderson, Daniel C ^b   Wales, Pamela A ^b   Pan, Laura L ^d   Atlas, Elliot L ^e   Hornbrook, Rebecca S ^d   Apel, Eric C ^d   Blake, Nicola J ^f   Campos, Teresa L ^d   Donets, Valeria ^e   Flocke, Frank M ^d   Hall, Samuel R ^d   Hanisco, Thomas F ^g   Hills, Alan J ^d   Honomichl, Shawn B ^d   Jensen, Jørgen B ^d   Kaser, Lisa ^d   Montzka, Denise D ^d   Nicely, Julie M ^b,g   Reeves, J Michael ^d   Riemer, Daniel D ^e   Schauffler, Sue M ^d   Ullmann, Kirk ^d   Weinheimer, Andrew J ^d   Wolfe, Glenn M ^g,h   more..

^a GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^b University of Maryland   (United States)

^c UNIVERSITY OF MARYLAND   (United States)

^d NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^e UNIVERSITY OF MIAMI   (United States)

^f UNIVERSITY OF CALIFORNIA   (United States)

^g NASA GODDARD SPACE FLIGHT CENTER   (United States)

^h UNIVERSITY OF MARYLAND BALTIMORE COUNTY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AIRBORNE SURVEY; ATMOSPHERIC CHEMISTRY; ATMOSPHERIC CONVECTION; BIOMASS BURNING; BROMINE COMPOUND; DETECTION METHOD; EXTRATROPICAL ENVIRONMENT; IONIZATION; STRATOSPHERE; TROPICAL ENVIRONMENT; TROPOPAUSE;

PACIFIC OCEAN; PACIFIC OCEAN (TROPICAL); PACIFIC OCEAN (WEST);

EID: 84995694144     PISSN: 01480227     EISSN: 21562202     Source Type: Journal    
DOI: 10.1002/2016JD025561     Document Type: Article

References (73)

1. Anderson, D. C., et al. (2016), A pervasive role for biomass burning in tropical high ozone/low water structures, Nat. Commun., 7, 10267, doi:10.1038/ncomms10267.
2. Arsene, C., A. Bougiatioti, M. Kanakidou, B. Bonsang, and N. Mihalopoulos (2007), Tropospheric OH and Cl levels deduced from non-methane hydrocarbon measurements in a marine site, Atmos. Chem. Phys., 7, 4661-4673.
3. Aschmann, J., B.-M. Sinnhuber, E. L. Atlas, and S. Schauffler (2009), Modeling the transport of very short-lived substance into the tropical upper troposphere and lower stratosphere, Atmos. Chem. Phys., 9, 9237-9247.
4. Ashfold, M. J., N. R. P. Harris, E. L. Atlas, A. J. Manning, and J. A. Pyle (2012), Transport of short-lived species into the tropical tropopause layer, Atmos. Chem. Phys., 12, 6309-6322, doi:10.5194/acp-12-6309-2012.
5. Bertram, T. H., and J. A. Thornton (2009), Toward a general parameterization of N2O5 reactivity on aqueous particles: The competing effects of particle liquid water, nitrate and chloride, Atmos. Chem. Phys., 9, 8351-8363.
6. Browne, E. C., et al. (2011), Global and regional effects of the photochemistry of CH3O2NO2: Evidence from ARCTAS, Atmos. Chem. Phys., 11, 4209-4219, doi:10.5194/acp-11-4209-2011.
7. Burkholder, J. B., S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine (2015), Chemical kinetics and photochemical data for use in atmospheric studies, Evaluation No. 18, JPL Publication 15-10, Jet Propul. Lab., Pasadena. [Available at http://jpldataeval.jpl.nasa.gov.]
8. Carpenter, L. J., S. Reimann, J. B. Burkholder, C. Clerbaux, B. D. Hall, R. Hossaini, J. C. Laube, and S. A. Yvon-Lewis (2014), Ozone-depleting substances (ODSs) and other gases of interest to the Montreal Protocol, in Scientific Assessment of Ozone Depletion: 2014, Global Ozone Res. and Monit. Proj.-Rep. 55, chap. 1, World Meteorol. Organ., Geneva, Switzerland.
9. Choi, S., et al. (2012), Analysis of satellite-derived Arctic tropospheric BrO columns in conjunction with aircraft measurements during ARCTAS and ARCPAC, Atmos. Chem. Phys., 12, 1255-1285, doi:10.5194/acp-12-1255-2012.
10. Crowley, J. N., M. Ammann, R. A. Cox, R. G. Hynes, M. E. Jenkin, A. Mellouki, M. J. Rossi, J. Troe, and T. J. Wallington (2010), Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V-Heterogeneous reactions on solid substrates, Atmos. Chem. Phys., 10, 9059-9223, doi:10.5194/acp-10-9059-2010.
11. Daniel, J. S., S. Solomon, R. W. Portmann, and R. R. Garcia (1999), Stratospheric ozone destruction: The importance of bromine relative to chlorine, J. Geophys. Res., 104, 23,871-23,880, doi:10.1029/1999JD900381.
12. Danilin, M. Y., N.-D. Sze, M. K. W. Ko, J. M. Rodriguez, and M. J. Prather (1996), Bromine-chlorine coupling in the Antarctic ozone hole, Geophys. Res. Lett., 23, 153-156, doi:10.1029/95GL03783.
13. Dibb, J. E., L. D. Ziemba, J. Luxford, and P. Beckman (2010), Bromide and other ions in the snow, firn air, and atmospheric boundary layer at Summit during GSHOX, Atmos. Chem. Phys., 10, 9931-9942.
14. Dorf, M., A. Butz, C. Camy-Peyret, M. P. Chipperfield, L. Kritten, and K. Pfeilsticker (2008), Bromine in the tropical troposphere and stratosphere as derived from balloon-borne BrO observations, Atmos. Chem. Phys., 8, 7265-7271.
15. Fernandez, R. P., R. J. Salawitch, D. E. Kinnison, J.-F. Lamarque, and A. Saiz-Lopez (2014), Bromine partitioning in the tropical tropopause layer:Implications for stratospheric injection, Atmos. Chem. Phys., 14, 13,391-13,410.
16. Fitzenberger, R., H. Bösch, C. Camy-Peyret, M. P. Chipperfield, H. Harder, U. Platt, B.-M. Sinnhuber, T. Wagner, and K. Pfeilsticker (2000), First profile measurements of tropospheric BrO, Geophys. Res. Lett., 27, 2921-2924, doi:10.1029/2000GL011531.
17. Frieler, K., M. Rex, R. J. Salawitch, T. Canty, M. Streibel, R. M. Stimpfle, K. Pfeilsticker, M. Dorf, D. K. Weisenstein, and S. Godin-Beekmann (2006), Toward a better quantitative understanding of polar stratospheric ozone loss, Geophys. Res. Lett., 33, L10812, doi:10.1029/ 2005GL025466.
18. Hebestreit, K., J. Stutz, D. Rosen, V. Matveiv, M. Peleg, M. Luria, and U. Platt (1999), DOAS measurements of tropospheric bromine oxide in mid-latitudes, Science, 283, 55-57.
19. Holzinger, R., C. Warneke, A. Hansel, A. Jordan, and W. Lindinger (1999), Biomass burning as a source of formaldehyde, acetaldehyde, methanol, acetone, acetonitrile, and hydrogen cyanide, Geophys. Res. Lett., 26, 1161-1164, doi:10.1029/1999GL900156.
20. Hönninger, G., H. Leser, O. Sebastián, and U. Platt (2004), Ground-based measurements of halogen oxides at the Hudson Bay by active long path DOAS and passive MAX-DOAS, Geophys. Res. Lett., 31, L04111, doi:10.1029/2003GL018982.
21. Hossaini, R., M. P. Chipperfield, B. M. Monge-Sanz, N. A. D. Richards, E. Atlas, and D. R. Blake (2010), Bromoform and dibromomethane in the tropics: A 3-D model study of chemistry and transport, Atmos. Chem. Phys., 10, 719-735.
22. Huey, L. G. (2007), Measurement of trace atmospheric species by chemical ionization mass spectrometry: Speciation of reactive nitrogen and future directions, Mass Spectrom. Rev., 26, 166-184.
23. Iraci, L. T., R. R. Michelsen, S. F. M. Ashbourn, T. A. Rammer, and D. M. Golden (2005), Uptake of hypobromous acid (HOBr) by aqueous sulfuric acid solutions: Low-temperature solubility and reaction, Atmos. Chem. Phys., 5, 1577-1587.
24. Jacob, D. J. (2000), Heterogeneous chemistry and tropospheric ozone, Atmos. Environ., 34, 2131-2159.
25. Kazantseva, N. N., A. Ernepesova, A. Khodjamamedov, O. A. Geldyev, and B. S. Krumgalz (2002), Spectrophotometric analysis of iodide oxidation by chlorine in highly mineralized solutions, Anal. Chim. Acta, 456, 105-119.
26. Kercher, J. P., T. P. Riedel, and J. A. Thornton (2009), Chlorine activation by N2O5: Simulation, in situ detection of ClNO2 and N2O5 by chemical ionization mass spectrometry, Atmos. Meas. Tech., 2, 193-204.
27. Kim, S., et al. (2007), Measurement of HO2NO2 in the free troposphere during the Intercontinental Chemical Transport Experiment-North America 2004, J. Geophys. Res., 112, D12S01, doi:10.1029/2006JD007676.
28. Ko, M. K. W., N.-D. Sze, C. J. Scott, and D. K. Wisenstein (1997), On the relation between stratospheric chlorine/bromine loading and short-lived tropospheric source gases, J. Geophys. Res., 102, 25,507-25,517, doi:10.1029/97JD02431.
29. Ko, M. K. W., et al. (2002), Very short-lived halogen and sulfur substances, in Scientific Assessment of Ozone Depletion: 2002, Global Ozone Res. and Monit. Proj. - Rep. 47, chap. 2, Geneva, Switzerland.
30. Kunz, A., P. Konopka, R. Müller, and L. L. Pan (2011), Dynamical tropopause based on isentropic potential vorticity gradients, J. Geophys. Res., 116, D01110, doi:10.1029/2010JD014343.
31. Lee, A. M., R. L. Jones, I. Kilbane-Dawe, and J. A. Pyle (2002), Diagnosing ozone loss in the extratropical lower stratosphere, J. Geophys. Res., 107(D11), 4110, doi:10.1029/2001JD000538.
32. Levine, J. G., P. Braesicke, N. R. P. Harris, N. H. Savage, and J. A. Pyle (2007), Pathways and timescales for troposphere-to-stratosphere transport via the tropical tropopause layer and their relevance for very short lived substances, J. Geophys. Res., 112, D04308, doi:10.1029/ 2005JD006940.
33. Liang, Q., E. Atlas, D. Blake, M. Dorf, K. Pfeilsticker, and S. Schauffler (2014), Convective transport of very short lived bromocarbons to the stratosphere, Atmos. Chem. Phys., 14, 5781-5792, doi:10.5194/acp-14-5781-2014.
34. Liao, J., et al. (2011a), A comparison of Arctic BrO measurements by chemical ionization mass spectrometry and long path-differential optical absorption spectroscopy, J. Geophys. Res., 116, D00R02, doi:10.1029/2010JD014788.
35. Liao, J., et al. (2011b), Observations of inorganic bromine (HOBr, BrO, and Br2) speciation at Barrow, Alaska, in spring 2009, J. Geophys. Res., 116, D00R02, doi:10.1029/2011JD016641.
36. Liao, J., et al. (2012), Characterization of soluble bromide measurements and a case study of BrO observations during ARCTAS, Atmos. Chem. Phys., 12, 1327-1338, doi:10.5194/acp-12-1327-2012.
37. Liao, J., et al. (2014), High levels of molecular chlorine in the Arctic atmosphere, Nat. Geosci., 7, 91-94, doi:10.1038/NGEO2046.
38. Mahajan, A. S., H. Oetjen, J. D. Lee, A. Saiz-Lopez, G. B. McFiggans, and J. M. C. Plane (2009), High bromine oxide concentrations in the semipolluted boundary layer, Atmos. Environ., 43(25), 3811-3818.
39. Montzka, S. A., et al. (2011), Ozone-depleting substances (ODSs) and related chemicals, in Scientific Assessment of Ozone Depletion: 2010, Global Ozone Res. and Monit. Proj.-Rep. 52, chap. 1, World Meteorol. Organ., Geneva, Switzerland.
40. Navarro, M. A., et al. (2015), Airborne measurements of organic bromine compounds in the Pacific tropical tropopause layer, Proc. Natl. Acad. Sci. U.S.A., 112(45), 13,789-13,793, doi:10.1073/pnas.1511463112.
41. Neuman, J. A., et al. (2006), Reactive nitrogen transport and photochemistry in urban plumes over the North Atlantic Ocean, J. Geophys. Res., 111, D23S54, doi:10.1029/2005JD007010.
42. Neuman, J. A., et al. (2010), Bromine measurements in ozone depleted air over the Arctic Ocean, Atmos. Chem. Phys., 10, 6503-6514, doi:10.5194/acp-10-6503-2010.
43. Orlando, J. J. (2003), Atmospheric chemistry of organic bromine and iodine compounds, in Organic Bromine and Iodine Compounds, Handbook of Environmental Chemistry, vol. 3, Part R, edited by A. H. Nelson, pp. 253-299, Springer, Berlin.
44. Pan, L. L., W. J. Randel, B. L. Gary, M. J. Mahoney, and E. J. Hintsa (2004), Definition and sharpness of the extratropical tropopause: A trace gas perspective, J. Geophys. Res., 109, D23103, doi:10.1029/2004JD004982.
45. Pan, L. L., et al. (2007), Chemical behavior of the tropopause observed during the Stratosphere-Troposphere Analyses of Regional Transport (START) experiment, J. Geophys. Res., 112, D18110, doi:10.1029/2007JD008645.
46. Pan, L. L., et al. (2016), The Convective Transport of Active Species in the Tropics (CONTRAST) experiment, Bull. Am. Meteorol. Soc., doi:10.1175/BAMS-D-14-00272.1, in press.
47. Parrella, J. P., et al. (2012), Tropospheric bromine chemistry: Implications for present and pre-industrial ozone and mercury, Atmos. Chem. Phys., 12, 6723-6740.
48. Pommier, M., C. A. McLinden, J. A. Neuman, and J. B. Nowak (2012), Biomass burning in Siberia as a source of BrO to the Arctic free troposphere, Atmos. Environ., 62, 416-423.
49. Rudolph, J., B. Ramacher, C. PlassDulmer, K. P. Muller, and R. Koppmann (1997), The indirect determination of chlorine atom concentration in the troposphere from changes in the patterns of non-methane hydrocarbons, Tellus, Ser. B, 49(5), 592-601, doi:10.1034/j.1600-0889.49. issue5.13.x.
50. Salawitch, R. J. (2006), Biogenic bromine, Nature, 439(19), 275-276.
51. Salawitch, R. J., et al. (1993), Chemical loss of ozone in the arctic polar vortex in the winter of 1991-1992, Science, 261, 1146-1149.
52. Salawitch, R. J., D. K. Weisenstein, L. J. Kovalenko, C. E. Sioris, P. O. Wennberg, K. Chance, M. K. W. Ko, and C. A. McLinden (2005), Sensitivity of ozone to bromine in the lower stratosphere, Geophys. Res. Lett., 32, L05811, doi:10.1029/2004GL021504.
53. Schofield, R., K. Kreher, B. J. Connor, P. V. Johnston, A. Thomas, D. Shooter, M. P. Chipperfield, C. D. Rodgers, and G. H. Mount (2004), Retrieved tropospheric and stratospheric BrO columns over Lauder, New Zealand, J. Geophys. Res., 109, D14304, doi:10.1029/2003JD004463.
54. Schwartz, S. E. (1986), Mass-transport considerations pertinent to aqueous-phase reactions of gases in liquid-water clouds, in Chemistry of Multiphase Atmospheric Systems, edited by W. Jaechske, pp. 415-471, Springer, Heidelberg.
55. Simpson, I. J., et al. (2011), Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN, Atmos. Chem. Phys., 11, 6445-6463, doi:10.5194/acp-11-6445-2011.
56. Sinnhuber, B.-M., and I. Folkins (2006), Estimating the contribution of bromoform to stratospheric bromine and its relation to dehydration in the tropical tropopause layer, Atmos. Chem. Phys., 6, 4755-4761.
57. Sinnhuber, B.-M., A. Rozanov, N. Sheode, O. T. Afe, A. Richter, M. Sinnhuber, F. Wittrock, and J. P. Burrows (2005), Global observations of stratospheric bromine monoxide from SCIAMACHY, Geophys. Res. Lett., 32, L20810, doi:10.1029/2005GL023839.
58. Sioris, C. E., et al. (2006), Latitudinal and vertical distribution of bromine monoxide in the lower stratosphere from Scanning Imaging Absorption Spectrometer for Atmospheric Chartography limb scattering measurements, J. Geophys. Res., 111, D14301, doi:10.1029/ 2005JD006479.
59. Sjostedt, S. J., et al. (2007), Observations of hydroxyl and the sum of peroxy radicals at Summit, Greenland during summer 2003, Atmos. Environ., 41, 5122-5137.
60. Slusher, D. L., L. G. Huey, D. J. Tanner, F. M. Flocke, and J. M. Roberts (2004), A thermal dissociation-chemical ionization mass spectrometry (TD-CIMS) technique for the simultaneous measurement of peroxyacyl nitrates and dinitrogen pentoxide, J. Geophys. Res., 109, D19315, doi:10.1029/2004JD004670.
61. Tegtmeier, S., K. Krüger, B. Quack, E. L. Atlas, I. Pisso, A. Stohl, and X. Yang (2012), Emission and transport of bromocarbons: From the West Pacific Ocean into the stratosphere, Atmos. Chem. Phys., 12, 10,633-10,648.
62. Theys, N., M. V. Roozendael, F. Hendrick, C. Fayt, C. Hermans, J.-L. Baray, F. Goutail, J.-P. Pommereau, and M. D. Mazière (2007), Retrieval of stratospheric and tropospheric BrO columns from multi-axis DOAS measurements at Réunion Island (21°S, 56°E), Atmos. Chem. Phys., 7, 4733-4749.
63. van Roozendael, M., et al. (2002), Intercomparison of BrO measurements from ERS-2 GOME, ground-based and balloon platforms, Adv. Space Res., 29, 1661-1666.
64. von Glasow, R., R. von Kuhlmann, M. G. Lawrence, U. Platt, and P. J. Crutzen (2004), Impact of reactive bromine chemistry in the troposphere, Atmos. Chem. Phys., 4, 2481-2497.
65. Wang, S., et al. (2015), Active and widespread halogen chemistry in the tropical and subtropical free troposphere, Proc. Natl. Acad. Sci. U.S.A., 112(30), 9281-9286, doi:10.1073/pnas.1505142112.
66. Warwick, N. J., A. Pyle, G. D. Carver, X. Yang, N. H. Savage, F. M. O’Connor, and R. A. Cox (2006), Global modeling of biogenic bromocarbons, J. Geophys. Res., 111, D24305, doi:10.1029/2006JD007264.
67. Wennberg, P. O., et al. (1994), Removal of stratospheric O3 by radicals: In situ measurements of OH, HO2, NO, NO2, ClO and BrO, Science, 266, 398-404.
68. Wolfe, G. M., and J. A. Thornton (2011), The Chemistry of Atmosphere-Forest Exchange (CAFE) Model-Part 1: Model description and characterization, Atmos. Chem. Phys., 11(1), 77-101, doi:10.5194/acp-11-77-2011.
69. World Meteorological Organization (WMO) (2011), Scientific Assessment of Ozone Depletion: 2010, Global Ozone Res. and Monit. Proj. - Rep. 52, 516 pp., World Meteorol. Organ., Geneva, Switzerland.
70. World Meteorological Organization (WMO) (2014), Scientific Assessment of Ozone Depletion: 2014, Global Ozone Res. and Monit. Proj.- Rep. 55, 416 pp., World Meteorol. Organ., Geneva, Switzerland.
71. Wu, C.-H., M. M. Birky, and L. G. Hepler (1963), Thermochemistry of some bromine and iodine species in aqueous solution, J. Phys. Chem., 67(6), 1202-1205, doi:10.1021/j100800a009.
72. Yang, X., R. A. Cox, N. J. Warwick, J. A. Pyle, G. D. Carver, F. M. O’Connor, and N. H. Savage (2005), Tropospheric bromine chemistry and its impacts on ozone: A model study, J. Geophys. Res., 110, D23311, doi:10.1029/2005JD006244.
73. Zheng, W., F. M. Flocke, G. S. Tyndall, A. Swanson, J. J. Orlando, J. M. Roberts, L. G. Huey, and D. J. Tanner (2011), Characterization of a thermal decomposition chemical ionization mass spectrometer for the measurement of peroxy acyl nitrates (PANs) in the atmosphere, Atmos. Chem. Phys., 11, 6529-6547, doi:10.5194/acp-11-6529-2011.