Highly Active and Selective Zr/MCF Catalyst for Production of 1,3-Butadiene from Ethanol in a Dual Fixed Bed Reactor System

ACS Sustainable Chemistry and Engineering

Volumn 4, Issue 9, 2016, Pages 4887-4894

  Cheong, Jian Liang ^a   Shao, Yaling ^a   Tan, Sherman J R ^a   Li, Xiukai ^a   Zhang, Yugen ^a   Lee, Su Seong ^a  

^a INSTITUTE OF BIOENGINEERING AND NANOTECHNOLOGY   (Singapore)

Author keywords

1,3 Butadiene; Biomass conversion; Ethanol; Heterogeneous catalysis; Mesoporous materials

Indexed keywords

BIOCONVERSION; CATALYSIS; CATALYSTS; CHEMICAL REACTORS; DEHYDROGENATION; ETHANOL; ETHYLENE; SILICA;

1 ,3-BUTADIENE; BIOMASS CONVERSION; ETHANOL CONVERSION; FIXED BED REACTOR SYSTEM; HIGH CATALYTIC PERFORMANCE; MESOCELLULAR SILICEOUS FOAMS; OPTIMAL CONDITIONS; WEIGHT HOURLY SPACE VELOCITY;

MESOPOROUS MATERIALS;

EID: 84986309866     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/acssuschemeng.6b01193     Document Type: Article

References (40)

1. Gavrilescu, M., Biomass Potential for Sustainable Environment, Biorefinery Products and Energy. In Sustainable Energy in the Built Environment-Steps Towards nZEB, Visa, I., Ed.; Springer International Publishing: 2014; pp 169-194.
2. Angelici, C.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Chemocatalytic conversion of ethanol into butadiene and other bulk chemicals ChemSusChem 2013, 6, 1595-1614 10.1002/cssc.201300214
3. Posada, J. A.; Patel, A. D.; Roes, A.; Blok, K.; Faaij, A. P.; Patel, M. K. Potential of bioethanol as a chemical building block for biorefineries: preliminary sustainability assessment of 12 bioethanol-based products Bioresour. Technol. 2013, 135, 490-499 10.1016/j.biortech.2012.09.058
4. Sun, J.; Wang, Y. Recent Advances in Catalytic Conversion of Ethanol to Chemicals ACS Catal. 2014, 4, 1078-1090 10.1021/cs4011343
5. Bruijnincx, P. C. A.; Weckhuysen, B. M. Shale gas revolution: an opportunity for the production of biobased chemicals? Angew. Chem., Int. Ed. 2013, 52, 11980-11987 10.1002/anie.201305058
6. Toussaint, W.; Dunn, J.; Jachson, D. R. Production of butadiene from alcohol Ind. Eng. Chem. 1947, 39, 120-125 10.1021/ie50446a010
7. Kvisle, S.; Aguero, A.; Sneeden, R. P. A. Transformation of ethanol into 1, 3-butadiene over magnesium oxide/silica catalysts Appl. Catal. 1988, 43, 117-131 10.1016/S0166-9834(00)80905-7
8. Jones, M. D.; Keir, C. G.; Iulio, C. D.; Robertson, R. A. M.; Williams, C. V.; Apperley, D. C. Investigations into the conversion of ethanol into 1,3-butadiene Catal. Sci. Technol. 2011, 1, 267-272 10.1039/c0cy00081g
9. Stahly, E. E.; Jones, H. E.; Corson, B. B. Butadiene from ethanol Ind. Eng. Chem. 1948, 40, 2301-2303 10.1021/ie50468a017
10. Corson, B. B.; Stahly, E. E.; Jones, H. E.; Bishop, H. D. Butadiene from ethyl alcohol Ind. Eng. Chem. 1949, 41, 1012-1017 10.1021/ie50473a028
11. Corson, B. B.; Jones, H. E.; Welling, C. E.; Hinckley, J. A.; Stahly, E. E. Butadiene from ethyl alcohol Ind. Eng. Chem. 1950, 42, 359-373 10.1021/ie50482a039
12. Toussaint, W. J.; Dunn, J. T. Process for making diolefins. U.S. Patent 2421361, 1947.
13. Sushkevich, V. L.; Ivanova, I. I.; Ordomsky, V. V.; Taarning, E. Design of a Metal-Promoted Oxide Catalyst for the Selective Synthesis of Butadiene from Ethanol ChemSusChem 2014, 7 (9) 2527-2536 10.1002/cssc.201402346
14. z mixed metal oxides Catal. Today 2016, 259, 446-452 10.1016/j.cattod.2015.04.010
15. Quattlebaum, W. M.; Toussaint, W. J.; Dunn, J. T. Deoxygenation of Certain Aldehydes and Ketones: Preparation of Butadiene and Styrene J. Am. Chem. Soc. 1947, 69, 593 10.1021/ja01195a040
16. Bhattacharyya, S.; Avasthi, B. One-step catalytic conversion of ethanol to butadiene in a fluidized bed Ind. Eng. Chem. Process Des. Dev. 1963, 2, 45-51 10.1021/i260005a010
17. Niiyama, H.; Morii, S.; Echigoya, E. Butadiene formation from ethanol over silica-magnesia catalysts Bull. Chem. Soc. Jpn. 1972, 45 (3) 655-659 10.1246/bcsj.45.655
18. 2O for Synthesis of Buta-1,3-diene from Ethanol J. Chem. Soc., Chem. Commun. 1985, 1613-1614 10.1039/C39850001613
19. León, M.; Díaz, E.; Ordóñez, S. Ethanol catalytic condensation over Mg-Al mixed oxides derived from hydrotalcites Catal. Today 2011, 164, 436-442 10.1016/j.cattod.2010.10.003
20. Makshina, E. V.; Janssens, W.; Sels, B. F.; Jacobs, P. A. Catalytic study of the conversion of ethanol into 1,3-butadiene Catal. Today 2012, 198, 338-344 10.1016/j.cattod.2012.05.031
21. 2-MgO Catalysts ChemSusChem 2014, 7, 2505-2515 10.1002/cssc.201402361
22. Sushkevich, V. L.; Ivanova, I. I.; Taarning, E. Ethanol conversion into butadiene over Zr-containing molecular sieves doped with silver Green Chem. 2015, 17, 2552-2559 10.1039/C4GC02202E
23. Kim, T.-W.; Kim, J.-W.; Kim, S.-Y.; Chae, H.-J.; Kim, J.-R.; Jeong, S.-Y.; Kim, C.-U. Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported spherical silica catalysts for circulating fluidized bed Chem. Eng. J. 2015, 278 (2015) 217-223 10.1016/j.cej.2014.09.110
24. Chae, H.-J.; Kim, T.-W.; Moon, Y.-K.; Kim, H.-K.; Jeong, K.-E.; Kim, C.-U.; Jeong, S.-Y. Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported ordered mesoporous silica catalysts Appl. Catal., B 2014, 150-151, 596-604 10.1016/j.apcatb.2013.12.023
25. 2-MgO materials Catal. Sci. Technol. 2015, 5 (5) 2869-2879 10.1039/C5CY00200A
26. 2-MgO Catalysts for the Lebedev Ethanol-to-Butadiene Process ACS Catal. 2015, 5, 6005-6015 10.1021/acscatal.5b00755
27. Sekiguchi, Y.; Akiyama, S.; Urakawa, W.; Koyama, T.-R.; Miyaji, A.; Motokura, K.; Baba, T. One-step catalytic conversion of ethanol into 1,3-butadiene using zinc-containing talc Catal. Commun. 2015, 68, 20-24 10.1016/j.catcom.2015.04.023
28. 2 Catalysts for the Conversion of Ethanol into Butadiene ChemSusChem 2015, 8, 994-1008 10.1002/cssc.201402894
29. Makshina, E. V.; Dusselier, M.; Janssens, W.; Degrève, J.; Jacobs, P. a.; Sels, B. F. Review of old chemistry and new catalytic advances in the on-purpose synthesis of butadiene Chem. Soc. Rev. 2014, 43 (22) 7917-7953 10.1039/C4CS00105B
30. 2 catalysts for the transformation of bioethanol and acetaldehyde into 1,3-butadiene RSC Adv. 2015, 5, 103982-103988 10.1039/C5RA22623F
31. Burla, J.; Burla, J.; Fehnel, R.; Louie, P.; Terpeluk, P. Two-Step Production of 1,3-Butadiene from Ethanol; Senior Design Project, University of Pennsylvania, 2012.
32. Klein, A.; Keisers, K.; Palkovits, R. Formation of 1,3-butadiene from ethanol in a two-step process using modified zeolite-β catalysts Appl. Catal., A 2016, 514, 192-202 10.1016/j.apcata.2016.01.026
33. Larina, O. V.; Kyriienko, P. I.; Soloviev, S. O. Effect of Lanthanum in Zn-La(-Zr)-Si Oxide Compositions on their Activity in the Conversion of Ethanol into 1,3-Butadiene Theor. Exp. Chem. 2016, 52, 51-56 10.1007/s11237-016-9450-1
34. Han, Y.; Lee, S. S.; Ying, J. Y. Spherical Siliceous Mesocellular Foam Particles for High-Speed Size Exclusion Chromatography Chem. Mater. 2007, 19, 2292-2298 10.1021/cm063050x
35. Gervasini, A.; Manzoli, M.; Martra, G.; Ponti, A.; Ravasio, N.; Sordelli, L.; Zaccheria, F. Dependence of copper species on the nature of the support for dispersed CuO catalysts J. Phys. Chem. B 2006, 110, 7851-7861 10.1021/jp056604c
36. Chang, F.-W.; Yang, H.-C.; Roselin, L. S.; Kuo, W.-Y. Ethanol dehydrogenation over copper catalysts on rice husk ash prepared by ion exchange Appl. Catal., A 2006, 304, 30-39 10.1016/j.apcata.2006.02.017
37. Garg, S.; Soni, K.; Kumaran, G. M.; Bal, R.; Gora-Marek, K.; Gupta, J. K.; Sharma, L. D.; Dhar, G. M. Acidity and catalytic activities of sulfated zirconia inside SBA-15 Catal. Today 2009, 141, 125-129 10.1016/j.cattod.2008.03.021
38. Cassinelli, W. H.; Martins, L.; Magnani, M.; Pulcinelli, S. H.; Briois, V.; Santilli, C. V. Time-resolved XAS/MS/Raman monitoring of mutual copper self-reduction and ethanol dehydrogenation reactions RSC Adv. 2016, 6 (25) 20453-20457 10.1039/C5RA27403F
39. Sushkevich, V. L.; Palagin, D.; Ivanova, I. I. With Open Arms: Open Sites of ZrBEA Zeolite Facilitate Selective Synthesis of Butadiene from Ethanol ACS Catal. 2015, 5 (8) 4833-4836 10.1021/acscatal.5b01024
40. Coppens, M.-O.; Wang, G. Optimal Design of Hierarchically Structured Porous Catalysts. In Design of Heterogeneous Catalysts; Wiley-VCH Verlag GmbH & Co. KGaA: 2009; pp 25-58.